• Journal of Powder Materials
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• v.25 no.3
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• pp.208-212
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• 2018

In this paper, a new $Co_{10}Fe_{10}Mn_{35}Ni_{35}Zn_{10}$ high entropy alloy (HEA) is identified as a strong candidate for the single face-centered cubic (FCC) structure screened using the upgraded TCFE2000 thermodynamic CALPHAD database. The $Co_{10}Fe_{10}Mn_{35}Ni_{35}Zn_{10}$ HEA is fabricated using the mechanical (MA) procedure and pressure-less sintering method. The $Co_{10}Fe_{10}Mn_{35}Ni_{35}Zn_{10}$ HEA, which consists of elements with a large difference in melting point and atomic size, is successfully fabricated using powder metallurgy techniques. The MA behavior, microstructure, and mechanical properties of the $Co_{10}Fe_{10}Mn_{35}Ni_{35}Zn_{10}$ HEA are systematically studied to understand the MA behavior and develop advanced techniques for fabricating HEA products. After MA, a single FCC phase is found. After sintering at $900^{\circ}C$, the microstructure has an FCC single phase with an average grain size of $18{\mu}m$. Finally, the $Co_{10}Fe_{10}Mn_{35}Ni_{35}Zn_{10}$ HEA has a compressive yield strength of 302 MPa.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.10
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• pp.93-101
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• 2004

A method to calculate stability limits is investigated to predict the characteristics of high-frequency combustion instability in liquid-propellant rocket engine. It is based on the theory of linear stability analysis proposed in previous works and useful to predict combustion stability at the beginning stage of engine development. The system of equations governing reactive flow in combustor has the simplified and linearized forms. The overall equation expressing stability limits is adopted. The procedures to evaluate quantitatively each term included in the equation are proposed. The thermo-chemical properties and flow variables required in the evaluation can be obtained from calculation of thermodynamic equilibrium, CFD results, and experimental test data. Based on the existent data, stability limits are calculated with actual rocket engine (KSR-III rocket engine). The present calculations show the reasonable stability limits in a quantitative manner and the stability characteristics of the engine are discussed. The prediction from linear stability analysis could be serve as the first approximation to the true prediction.

• Journal of the Korean Chemical Society
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• v.42 no.5
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• pp.519-525
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• 1998

The critical micelle concentration $(CMC^{\ast})$ and the counterion binding constant (B) in a micellar state of the mixed surfactant systems of dodecylpyridinium chloride (DPC) with dodecyltrimethylammonium bromide (DTAB), tetradecyltrimethylammonium bromide (TTAB), and cetyldimethylethylammonium bromide (CDEAB) were determined at $25^{\circ}C$ as a function of ${\alpha}_1$ (the overall molc fraction of DPC) by the use of electric conductivity method. Various thermodynamic parameters $(X_{i},\;{\gamma}_{I},\;C_{i},\;a^{M}_{i}, \beta,\;{\Delta}H_{mix}, \;and\; {\Delta}G^{o}_{m})$ for the micellization of DPC/DTAB, DPC/TTAB, and DPC/CDEAB mixtures were calculated and analyzed for each system by means of the equations derived from the pseudophase separation model. The results show that the DPC/DTAB mixed system has the greatest deviation and the DPC/CDEAB mixed system has the smallest deviation from the ideal mixed micellar model.

• The KSFM Journal of Fluid Machinery
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• v.19 no.3
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• pp.14-18
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• 2016

The power generation system using cold energy, which evolves in a large amount during the vaporization process of the liquefied natural gas, was designed in favor of the Rankine cycle with a mixed refrigerant as the working fluid. In this study it is intended to identify the allowable limits of the working fluid composition in respect of equipment safety in the Rankine cycle-type power generation system driven by the cold energy. The thermodynamic properties of the working fluid, which is a hydrocarbon mixture, were calculated with the Peng-Robinson model. In the steady state simulation of the power generation system by using a commercial tool Aspen HYSYS, the feed conditions of LNG Test Bed Train No.1 along with some necessary assumptions were incorporated. The results indicated that deterioration of the mechanical performance of the equipment as well as its safety would be brought about if contents of $C_2H_6$ and $C_3H_8$ in the mixture become, respectively, too high or too low.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.12
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• pp.1167-1173
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• 2013

This study aimed to calculate the CFFs (critical flow functions) of a sonic nozzle bank with a 12-nozzle package within 1 s. Toward this end, the Helmholtz free energy of natural gas was formulated by using the AGA8-dc equation of state in a form without integral terms, and thereafter, thermodynamic properties such as the enthalpy, entropy, speed of sound, and heat capacity, which are used in CFF calculation, were derived in analytical form. As a result, the calculation time of CFFs was improved from 6.7 s in a previous study to 0.6 s per 12-nozzle package and kept almost constant regardless of the number of components in natural gas. Furthermore, it was confirmed that the calculated CFF values were in agreement with the results of a CFF international comparison test carried out under ISO management in 1998-1999.

• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.149-154
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• 1998

The characteristics of drag reduction and rheological behaviors were investigated using cationic surfactants, whose microstructures are known to change when concentration of the surfactant exceeds CMC. The firstly formed spherical micelles change to rodlike or disklike micelles because of packing between surfactants micells, and of thermodynamic perference. The drag reduction becomes significant when the concentration increases over this micellar transient point. Drag reductions were measured as a function of concentration, and rheological characteristics of the surfactant were further investigated to understand the correlation between their rheological properties and drag reduction. Micelles show the non-Newtonian behavior, and shear thickening behaviors were observed due to the structural development. In addition, structural developments were determined by adding the counter-ion in case of DOBON-G.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.8
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• pp.118-128
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• 2004

Exhaust plume effects on longitudinal aerodynamics of missile were investigated by wind tunnel tests using a solid plume simulator and CFD analyses with both the solid plume and air jet plumes. Approximate plume boundary prediction technique was used to produce the outer shape of the solid plumer and chamber conditions and nozzle shapes of the air jet plumes were determined through plume modeling technique to compensate the difference in thermodynamic properties between air and real plume. From comparisons among turbulence models in case of external flow interaction with the air jet plume, Spalart-Allmaras model turned out to give accurate result and to be less grid-dependent. Effects induced by the plume were evaluated through the computations with Spalart-Allmaras turbulence model and the air jet plume to account for various ratios of chamber and ambient pressure and Reynolds number under the flight test condition.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.263-263
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• 2013

This work examines the dynamic properties of ice surfaces in vacuum for the temperature range of 140~180 K, which extends over the onset temperatures for ice sublimation and the phase transition from amorphous to crystallization ice. In particular, the study focuses on the transport processes of excess protons and chloride ions in ice and their segregative behavior to the ice surface. These phenomena were studied by conducting experiments with a relatively thick (~100 BL) ice film constructed with a bottom $H_2O$ layer and an upper $D_2O$ layer, with excess hydronium and chloride ions trapped at the $H_2O$/$D_2O$ interface as they were generated by the ionization of hydrogen chloride. The migration of protons, chloride ions, and water molecules to the ice film surface and their H/D exchange reactions were measured as a function of temperature using the methods of low energy sputtering (LES) and Cs+ reactive ion scattering (RIS). Temperature programmed desorption (TPD) experiments monitored the desorption of water and hydrogen chloride from the surface. Our observations indicated that both hydronium and chloride ions migrated from the interfacial layer to segregate to the surface at high temperature. Hydrogen chloride gas desorbs via recombination reaction of hydronium and chloride ions floating on the surface. Surface segregation of these species is driven by thermodynamic potential gradient present near the ice surface, whereas in the bulk, their transport is facilitated by thermal diffusion process. The finding suggests that chlorine activation reactions of hydrogen chloride for polar stratospheric ice particles occur at the surface of ice within a depth of at most a few molecular layers, rather than in the bulk phase.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.6
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• pp.2888-2897
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• 2011

The performance of a geothermal heat pump system using carbon dioxide was investigated by the steady-state cycle simulation program developed in this study. A parametric study was carried out in order to investigate the effect of various operating conditions on the performance of the basic cycle without an IHX(internal heat exchanger). The simulation program consists of several Fortran subroutines for simulating indoor and outdoor heat exchangers, compressors, and expansion valves and Visual Basic subroutines for the graphic user interface(GUI) consisted with pre-processor for input data and post-processor for the output data. Refprop V6.01 was used for estimating the thermodynamic properties and equilibrium behaviors of carbon dioxide. The simulation results were validated by comparing experimental data through a series of case studies. The cycle simulation program developed in this work would seem to be a useful tool in optimizing and establishing economical and efficient operating conditions in the $CO_2$ geothermal heat pump system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.2
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• pp.449-454
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• 2010

In this paper, flow characteristics of R600a in an adiabatic capillary tube were investigated employing the homogeneous flow model. The model is based on fundamental equations of mass, energy and momentum which are solved simultaneously. Two friction factors(Churchill) and viscosity(McAdams) are comparatively used to investigate the flow characteristics. Thermodynamic and transport properties of R600a are calculated employing EES property code. Flow characteristics analysis of R600a in an adiabatic capillary tube is presented to offer the basic design data for the operating parameters. The operating parameters considered in this study include condensation temperature, evaporation temperature, subcooling degree and inner diameter tube of the adiabatic capillary tube. The main results were summarized as follows: condensation and evaporation temperature, inlet subcooling degree and inner diameter tube of an adiabatic capillary tube using R600a have an effect on length of an adiabatic capillary tube. The length of an adiabatic capillary tube using R600a is expressed to the correlation shown in Eq. (15).