• 공학논문집
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• 제6권2호
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• pp.85-98
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• 2004

The adsorption equilibrium data for the binary gas mixture system from the pure gas adsorption data of carbon dioxide and ethylene on ZSM-5 prepared were predicted. The binary gas mixture adsorption data have been examined against predicted values by two models-the vacancy solution model(VSM) and the statistical thermodynamic model(STM), using parameters obtained from the single component isotherm. The binary gas mixture data for the carbon dioxide-ethylene system were obtained for cation exchanged forms of ZSM-5 for the gas phase carbon dioxide mole fraction of 0.752 at $37^{\circ}C$ and 1 atm. The experimental adsorption phase diagrams were obtained for carbon dioxide-ethylene on sodium form ZSM-5 synthesized. The single component adsorption isotherms for carbon dioxide and ethylene were also obtained for this zeolite. The single component data were used to obtain parameters derived in two models. These parameters were, in turn, used to predict the binary mixture isotherms for this zeolite. Both the vacancy solution and the statistical thermodynamic models give satisfactory predictions of adsorption phase diagrams for the binary gas mixtures of carbon dioxide and ethylene on sodium exchanged ZSM-5. Also the correlation between the experimental data and the predicted values is generally in good agreement. The system appears to show ideal behavior with a relatively constant separation factor. The slight increase in adsorption capacity with an increase in ionic radius is due, in part, to the higher polarizability associated with larger cations.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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• pp.103-108
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• 2011

초임계환경에서 작동하는 케로신/액체산소 동축와류형 분사기의 혼합특성을 수치적으로 연구하였다. 케로신 물성치를 계산하기 위하여 써로게이트 모델이 적용되었다. 난류모델은 LES를 기반으로 하였고, 초임계영역의 상태량을 계산하기위해 SRK 상태방정식, 점성계수와 열전도도에 대하여 Chung이 제안한 고압상태 혼합물에 대한 방정식, 확산계수에 대하여 Fuller 이론에 Takahashi가 제안한 고압상태의 특징을 고려한 식을 적용하였다. 연소실 압력변화에 따른 분사기와 연소실에서의 열역학적 물성치와 혼합특성을 관찰하였다. 또한 분사기의 압력섭동 스펙트럼밀도를 분석하였다.

• 대한금속재료학회지
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• 제47권5호
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• pp.304-310
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• 2009

Recently, manganese nodule has been focused on alternative resources because of its high grade of noble metallic elements such as Co, Ni, and Cu etc. From the viewpoint of an optimization the operating variables for energy efficiency of smelting reduction process, thermodynamic model for smelting reduction process of Manganese nodule was developed by using energy and material balance concept. This model provided that specific consumption of pure oxygen and coke was strongly depended on post combustion ratio (PCR) and heat transfer efficiency (HTE). The dressing and dehydrating process of low grade manganese can be proposed an essential process to minimize the specific energy consumption with decreasing slag volume. The effect of electricity coal base smelting reduction process was also discussed from the energy optimizing point of view.

• International Journal of Naval Architecture and Ocean Engineering
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• 제13권1호
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• pp.659-673
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• 2021

This study aims to investigate the impact of the High Pressure Selective Catalytic Reduction system (SCR-HP) on a large marine two-stroke engine performance parameters by employing thermodynamic modelling. A coupled model of the zero-dimensional type is extended to incorporate the modelling of the SCR-HP components and the Control Bypass Valve (CBV) block. This model is employed to simulate several scenarios representing the engine operation at both healthy and degraded conditions considering the compressor fouling and the SCR reactor clogging. The derived results are analysed to quantify the impact of the SCR-HP on the investigated engine performance. The SCR system pressure drop and the cylinder bypass valve flow cause an increase of the engine Specific Fuel Oil Consumption (SFOC) in the range 0.3-2.77 g/kWh. The thermal inertia of the SCR-HP is mainly attributed to the SCR reactor, which causes a delayed turbocharger response. These effects are more pronounced at low engine loads. This study supports the better understanding of the operating characteristics of marine two-stroke diesel engines equipped with the SCR-HP and quantification of the impact of the components degradation on the engine performance.

• 오토저널
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• 제3권3호
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• pp.49-57
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• 1981

A cycle simulation of 4 cycle spark ignition engine using methanol-water blend as a fuel has been developed for study of prediction of power, specific fuel consumption, mean effective pressure and thermal efficiency. One-dimensional flow model for intake process and thermodynamic model for combustion process were selected. After, performance test was made with conventional engine which was modified in consideration of fuel properties. And computational results by simulation have been compared with experimental results. As the agreement between computational and experimental results was good, prediction of engine performance by was possible.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1988년도 추계학술대회 논문집 학회본부
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• pp.220-223
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• 1988

A the dependent model for wail-stabilized local thermodynamic equilibrium (LTE) arcs has been used to examine the high-pressure sodium vapor arc. Arc properties including temperature, electrical conductivity, and optically thick and optically thin radiation fluxes were calculated as functions of radius and time.

• 한국해양공학회지
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• 제10권2호
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• pp.136-145
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• 1996

The theory is based on two thermodynamic equations for the air mass in the air column and bydrodynamic equation for the relation between the response of the air in the water column and the incident wave. The numerical model is experimented in a two dimensional water tank and the caisson model with sloped front wall is tested in the large towing tank.

• Bulletin of the Korean Chemical Society
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• 제2권1호
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• pp.17-24
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• 1981

Thermodynamic properties such as sublimation pressures, enthalpies and entropies of sublimation, enthalpies and entropies of solid krypton and xenon are calculated from $0{\circ}K$ to the triple point, using the vacancies-in-solid model. The Mie-Lennard-Jones 12,6 potential in uniform potential field is used. The results are compared with the calorimetric and sublimation pressure values, and are in a good agreement with the available calorimetric and sublimation pressure values.

• Korean Chemical Engineering Research
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• 제56권1호
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• pp.112-118
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• 2018

제올라이트에 대한 수용액으로부터 brilliant green의 흡착 평형과 동역학 및 열역학 파라미터들을 다양한 초기농도(10-30 mg/L), 접촉시간(1-24 h) 및 흡착온도(298-318 K)를 변수로 하여 회분식 실험을 통하여 연구하였다. 흡착평형 값들은 Langmuir, Freundlich 및 Dubinin-Radushkevich 식으로 해석하였다. 그 결과는 Langmuir 식과 Freundlich 식에 잘 맞았으며, 평가된 Langmuir 무차원 분리계수 값($R_L=0.041{\sim}0.057$)와 Freundlich 상수값(1/n=0.30~0.47)은 제올라이트에 의한 brilliant green의 흡착이 효과적인 공정이 될 수 있음을 나타냈다. Dubinin-Radushkevich 식에 의해 평가된 흡착 에너지값(1.564~1.857 kJ/mol)은 물리흡착에 해당하였다. Brilliant green의 흡착 동력학은 유사이차반응속도식에 잘 맞았으며, 입자내 확산식에 잘 따랐다. 흡착 특성을 평가하기 위하여 주로 활성화에너지, Gibbs 자유에너지, 엔탈피 및 엔트로피와 같은 열역학 파라미터가 계산되었다. Gibbs 자유에너지-10.3~-11.4 kJ/mol), 엔탈피(49.48 kJ/mol) 및 활성화에너지(27.05 kJ/mol)는 흡착이 자발적이고, 흡열 및 물리흡착 공정임을 나타냈다.

• 대기
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• 제27권2호
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• pp.133-150
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• 2017

This study evaluates CMIP5 model performance on rainy season evolution in the East Asian summer monsoon. Historical (1986~2005) simulation is analyzed using ensemble mean of CMIP5 19 models. Simulated rainfall amount is underestimated than the observed and onset and termination of rainy season are earlier in the simulation. Compared with evolution timing, duration of the rainy season is uncertain with large model spread. This area-averaged analysis results mix relative differences among the models. All model show similarity in the underestimated rainfall, but there are quite large difference in dynamic and thermodynamic processes. The model difference is shown in horizontal distribution analysis. BEST and WORST group is selected based on skill score. BEST shows better performance in northward movement of the rain band, summer monsoon domain. Especially, meridional gradient of equivalent potential temperature and low-level circulation for evolving frontal system is quite well captured in BEST. According to RCP8.5, CMIP5 projects earlier onset, delayed termination and longer duration of the rainy season with increasing rainfall amount at the end of 21st century. BEST and WORST shows similar projection for the rainy season evolution timing, meanwhile there are large discrepancy in thermodynamic structure. BEST and WORST in future projection are different in moisture flux, vertical structure of equivalent potential temperature and the subsequent unstable changes in the conditional instability.