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http://dx.doi.org/10.9713/kcer.2018.56.1.112

Study on Equillibrium, Kinetic, Thermodynamic Parameters for Adsorption of Brilliant Green by Zeolite  

Lee, Jong Jib (Division of chemical Engineering, Kongju National University)
Publication Information
Korean Chemical Engineering Research / v.56, no.1, 2018 , pp. 112-118 More about this Journal
Abstract
Adsorption equilibrium, kinetic and thermodynamic parameters of a brilliant green from aqueous solutions at various initial dye concentration (10~30 mg/L), contact time (1~24 h) and temperature (298~318 K) on zeolite were studied in a batch mode operation. The equilibrium adsorption values were analyzed by Langmuir, Freundlich and Dubinin-Radushkevich model. The results indicate that Langmuir and Freundlich model provides the best correlation of the experimental data. Base on the estimated values of Langmuir dimensionless separation factor ($R_L=0.041{\sim}0.057$) and Freundlich constant (1/n=0.30~0.47), this process could be employed as effective treatment method. calculated values of adsorption energy by Dubinin-Radushkevich model were 1.564~1.857 kJ/mol corresponding to physical adsorption. The adsorption kinetics of brilliant green were best described by the pseudo second-order rate model and followed by intraparticle diffusion model. Thermodynamic parameters such as activation energy, free energy, enthalpy and entropy were calculated to estimate nature of adsorption. negative Gibbs free energy (-10.3~-11.4 kJ/mol), positive enthalpy change (49.48 kJ/mol) and Arrehenius activation energy (27.05 kJ/mol) indicates that the adsorption is spontaneous, endothermic and physical adsorption process, respectively.
Keywords
Brilliant green; Dye adsorption; Adsorption kinetic; Adsorption; Dye;
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Times Cited By KSCI : 3  (Citation Analysis)
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