• Journal of Electrochemical Science and Technology
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• v.2 no.1
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• pp.20-25
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• 2011

This work focuses on the behavior of the overpotential increase due to a utilization rise in a molten carbonate fuel cell. The behavior is generally explained by Nernst loss, which is a kind of voltage loss due to the thermodynamic potential gradients in a polarization state due to the concentration distribution of reactant species through the gas flow direction. The evaluation of Nernst loss is carried out with a traditional experimental method of constant gas utilization (CU). On the other hand, overpotential due to the gas-phase mass-transport resistance at the anode and cathode shows dependence on the utilization, which can be measured using the inert gas step addition (ISA) method. Since the Nernst loss is assumed to be due to the thermodynamic reasons, the voltage loss can be calculated by the Nernst equation, referred to as a simple calculation (SC) in this work. The three values of voltage loss due to CU, ISA, and SC are compared, showing that these values rise with increases in the utilization within acceptable deviations. When we consider that the anode and cathode reactions are significantly affected by the gas-phase mass transfer, the behavior strongly implies that the voltage loss is attributable not to thermodynamic reasons, namely Nernst loss, but to the kinetic reason of mass-transfer resistance in the gas phase.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.1
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• pp.91-97
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• 2013

Recently a novel cycle named organic flash cycle (OFC) has been proposed which has improved potential for power generation from low-temperature heat sources. This study carries out thermodynamic performance analysis of OFC using various working fluids for recovery of low-grade heat sources in the form of sensible energy. Special attention is focused on the optimum flash temperature at which the exergy efficiency has the maximum value. Under the optimal conditions with respect to the flash temperature, the thermodynamic performances of important system variables including mass flow ratio, separation ratio, heat addition, specific volume flow rate at turbine exit, and exergy efficiency are thoroughly investigated. Results show that the exergy efficiency has a peak value with respect to the flash temperature and the optimum working fluid which shows the best exergy efficiency varies with the operating conditions.

• Journal of Ceramic Processing Research
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• v.19 no.6
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• pp.519-524
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• 2018

Carbon/carbon composites (C/C) have been widely studied in the aerospace field because of their excellent thermal shock resistance and specific strength at high temperature. However, they have the problems that is easily oxidized and deteriorated under atmospheric environment. In order to overcome these shortcomings, the CVD coating of ultra-high-temperature ceramics to C/C has become an important technical issue. In this study, thermodynamic calculations were performed to TaC CVD coating on C/C by FactSage 6.2 program. The Ta-C phase diagrams were constructed with the results of thermodynamic calculations in the Ta-C-H-Cl system. Based on the Ta-C phase diagram, the experimental conditions were designed to confirm the deposition of various phases such as TaC single phase, TaC + C and $TaC+Ta_2C$ by varying the composition of Ta/C ratio. The deposited films were found to be in good agreement with the predicted phases.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.7
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• pp.966-979
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• 1998

Thermodynamic and dynamic analysis has been conducted to investigate performance variations induced by substitution of alternative refrigerants, HFC134a or HC600a for CFC12 in hermetic reciprocating compressors. For the thermodynamic analysis, mass and energy conservation laws are applied to the cylinder volume and Helmholtz resonator modeling method is adopted to describe gas pulsations at suction and discharge system. The modeling of the dynamics of the compressor mechanism has been performed with lumped mass method to analyse the bearing loads and friction losses at each bearing. To verify the correctness of this analysis, results of the performance simulation have been compared to those of calorimetric measurrements of compressor operating with CFC12. Analysis of the various losses, noise and reliability as well as performance has been conducted to present the design guideline for the compressor development with alternative refrigerants. It is found that compressors with alternative refrigerants, HFC 134a or HC600a give better COPs than those with CFC12 under the same operating conditions and especially, compressors with HC600a show better reliability and noise characteristics also.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.15 no.2
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• pp.413-418
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• 2011

The thermodynamic properties of steam table are obtained by measurement or approximate calculation under appropriate assumptions. Therefore they are supposed to have basic measurement errors. And thermodynamic properties should be modeled through function approximation for using in numerical analysis. In order to make noised thermodynamic properties corresponding to measurement errors, random numbers are generated, adjusted to appropriate magnitudes and added to original thermodynamic properties. Both neural networks and quadratic spline interpolation method are introduced for function approximation of these modified thermodynamic properties in the saturated water based on pressure and temperature. In analysis spline interpolation method gives much less relative errors than neural networks at both ends of data. Excluding the both ends of data, the relative errors of neural networks is generally within ${\pm}0.2%$ and those of spline interpolation method within ${\pm}0.5$~1.5%. This means that the neural networks give smaller relative errors compared with quadratic spline interpolation method within range of use. From this fact it was confirmed that the neural networks trace the original values better than the quadratic interpolation method and neural networks are more appropriate method in modelling the saturated steam table.

• BMB Reports
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• v.37 no.6
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• pp.657-662
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• 2004

Oligoribonucleotides containing 8-oxo-7,8-dihydroguanosine (8-oxoG) and 8-oxo-7,8-dihydro-2'-O-methylguanosine (8-oxoG-Me) were synthesized. The base pairing properties of 8-oxoG and 8-oxoG-Me in oligoribonucleotide in cDNA synthesis by reverse transcriptases were studied. dCMP was preferentially incorporated into the site opposite 8-oxoG or 8-oxoG-Me than into other dNMPs. TMP and dCMP were inserted preferentially into sites opposite 8-oxoG or 8-oxoG by reverse transcriptases. HIV-RT did not incorporate TMP, but RAV2-RT incorporated 50% more TMP than dCMP into the site opposite 8-oxoG. In the site opposite 8-oxoG-Me TMP was substantially incorporated by HIV-RT or RAV2-RT. Thermodynamic analysis of the DNA. RNA heteroduplex containing 8-oxoG revealed that 8-oxoG and 8-oxoG-Me formed base pairs with cytidine and thymidine with similar stability. The thermodynamic parameter (${\Delta}G^{\circ}$) demonstrated that the formation of duplexes between 8-oxoG or 8-oxoG-Me and cytidine or thymidine is more thermodynamically favorable than with adenosine and guanosine. However, differences in the melting temperature and ${\Delta}G^{\circ}$'s of 8-oxoG/dC and 8-oxoG/T were much smaller than between G/dC and G/T. CD spectra showed that DNA . RNA containing 8-oxoG or 8-oxoG-Me duplexes showed similarities between the A-type RNA and B-type DNA conformations.

• Steel and Composite Structures
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• v.41 no.6
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• pp.873-886
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• 2021

In this paper, an analytical solution for thermodynamic response of functionally graded (FG) sandwich plates resting on variable elastic foundation is performed by using a quasi 3D shear deformation plate theory. The displacement field used in the present study contains undetermined integral terms and involves only four unknown functions with including stretching effect. The FG sandwich plate is considered to be subject to a time harmonic sinusoidal temperature field across its thickness with any combined boundary conditions. Equations of motion are derived from Hamilton's principle. The numerical results are compared with the existing results of quasi-3D shear deformation theories and an excellent agreement is observed. Several numerical examples for fundamental frequency, deflection, stress and variable elastic foundation parameter's analysis of FG sandwich plates are presented and discussed considering different material gradients, layer thickness ratios, thickness-to-length ratios and boundary conditions. The results of the present study reveal that the nature of the elastic foundation, the boundary conditions and the thermodynamic loading affect the response of the FG plate especially in the case of a thick plate.

• Aerospace Engineering and Technology
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• v.4 no.1
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• pp.18-24
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• 2005

Wet compression means the injection of water droplets into the compressor of gas turbines. This method decreases the compression work and increases the turbine output by decreasing the compressor exit temperature through the evaporation of water droplets inside the compressor. This paper provides thermodynamic and aerodynamic analysis on wet compression in a centrifugal compressor for a microturbine. The meanline performance analysis of centrifugal compressor is coupled with the thermodynamic equation of wet compression to get the meanline performance of wet compression. The most influencing parameter in the analysis is the evaporative rate of water droplets. It is found that the impeller exit flow temperature and compression work decreases as the evaporative rate increases. And the exit flow angle decreases as the evaporative rate increases.

• Transactions of the Korean hydrogen and new energy society
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• v.5 no.2
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• pp.91-98
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• 1994

In this study hydrogen gas and oxygen gas are used to make a pollution-free engine which is a closed system with the components such as a combustor, two turbines, a radiator and a compressor. One of the two turbines produces main power, and the other is used to drive a compressor to compress unburned gases and to return them to the combustor. Some of the water from the radiator is pumped to cool down the internal wall of the combustor and to be used as a working fluid which expands from liquid state to vapor state to get more expansion work. The possibility of operating the whole system is checked by the thermodynamic analysis to make the closed engine system. The calculations in the thermal analysis are based on the Brayton cycle and the Rankine cycle. The closed system in this study shows similar efficiency as usual internal combustion engines, but it produces water only without air pollution such as $NO_x$ and soot.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.4
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• pp.484-496
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• 1996

This paper presents an anlaysis on the thermodynamic performance of ice storage system. The primary interest in this work is the exergetic efficiency of the system. The ice storage system considered here is the capsule type system with the waste plastic bottle being used as a capsule. To examine the characteristics of irreversibility production and exergetic efficiency in detail the ice storage system to be analyzed has been separated from the refrigerator in this analysis. The analysis is based on the lumped model with 3 uniform temperatures. The results indicate that 3 dimensionless parameters can describe the exergetic efficiency of the system, from which the characteristics of irreversibilities and the ranges of these parameters to ensure the reasonable performance of the system can be found. Experiments also have been performed to demonstrate the feasibility of such a system. This analysis only shows the performance of ice storage side, with the refrigeration side excluded. However, the results can be interpreted as a total performance if the refrigerator coupled with the ice storage system operatres reversibly.