• Title/Summary/Keyword: thermally stable layer

Search Result 49, Processing Time 0.038 seconds

Correlation between Ferromagnetic State and Thermally Stable Layer of Fe on the W(001) Surface

  • Sin, Min-Jeong;Park, Byeong-Gyu;Hwang, Chan-Yong;Lee, Han-Gil
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2014.02a
    • /
    • pp.173.1-173.1
    • /
    • 2014
  • The variations of electronic and magnetic properties of ultrathin Fe overlayers on a W(001) surface as a function of Fe film thickness (1.0~4.0 ML) has been investigated using x-ray magnetic circular dichroism (XMCD) in conjunction with ultraviolet photoelectron spectroscopy (UPS) and low energy electron diffraction (LEED). We found that the ferromagnetic property of Fe film started to build up over 2.0 ML, as we confirmed the spin and angular moment contribution to the magnetic moment using XMCD experiments. We will systematically demonstrate that the occurrence of ferromagnetic property of Fe film on a W(001) surface is closely correlated to a themally stable layer of Fe film on a W(001) surface.

  • PDF

In-situ Thermally Curable Hyper-branched 10H-butylphenothiazine

  • Jo, Mi-Young;Lim, Youn-Hee;Ahn, Byung-Hyun;Lee, Gun-Dae;Kim, Joo-Hyun
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.2
    • /
    • pp.492-498
    • /
    • 2012
  • A hyper branched 10-butylphenothiazine with in-situ thermally curable methacrylate (1,3,5-tris-[$\{$10-Butyl-3-(4-(2-methyl-acryloyloxy)-phenyl)-7-yl-10H-phenothiazine$\}$]-benzene, (tris-PTMA)) was synthesized successfully. From the TGA thermogram of tris-PTMA was thermally stable up to $336^{\circ}C$. In the first heating scan of DSC thermogram, tris-PTMA showed glass transition temperature (Tg) at $140^{\circ}C$ and broad endothermic process in the region of $144-179^{\circ}C$, which is thermally curing temperature. In the second heating process, $T_g$ exhibited at $158.7^{\circ}C$ and endothermic process was not observed. Thermally cured tris-PTMA showed no big change in the UV-visible spectrum after washing with organic solvent such as methylene chloride, chloroform, toluene, indicating that thermally cured film was very good solvent resistance. Thermally cured tris-PTMA was electrochemically stable and the HOMO energy level of tris-PTMA was -5.54 eV. The maximum luminance efficiency of double layer structured polymer light-emitting diode based on in-situ thermally cured tris-PTMA was 0.685 cd/A at 16.0 V, which was higher than that of the device without thermally cured tris-PTMA (0.348 cd/A at 15.0 V).

Turbulent Dispersion Behavior of a Jet Issued into Thermally Stratified Cross Flows(I) (열적으로 성층화된 횡단류에 분출된 제트의 난류확산 거동(I))

  • Kim, Kyung Chun;Kim, Sang Ki
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.23 no.2
    • /
    • pp.218-225
    • /
    • 1999
  • Flow visualization study has been conducted to simulate the turbulent dispersion behavior of a crossflow jet physically under the conditions of various thermal stratification in a wind tunnel. A smoke jet with the constant ratio of the jet to freestream velocity is injected normally to the cross flow of the thermally stratified wind tunnel(TSWT) for flow visualization. The typical natures of the smoke dispersion under different thermal stratifications such as neutral, weakly stable, strongly stable, weakly unstable, strongly unstable and inversion layer are successfully reproduced in the TSWT. The Instantaneous velocity and temperature fluctuations are measured by using a cold and hot-wire combination probe. The time averaged dispersion behaviors, the centerline trajectories, the spreading angles and the virtual origins of the cross jet are deduced from the edge detected images with respect to the stability parameter. All the general characteristics of the turbulent dispersion behavior reveal that the definitely different dispersion mechanisms are inherent in both stable and unstable conditions. It is conjectured that the turbulent statistics obtained in the various stability conditions quantitatively demonstrate the vertical scalar flux plays a key role in the turbulent dispersion behavior.

Strained Ge Light Emitter with Ge on Dual Insulators for Improved Thermal Conduction and Optical Insulation

  • Kim, Youngmin;Petykiewicz, Jan;Gupta, Shashank;Vuckovic, Jelena;Saraswat, Krishna C.;Nam, Donguk
    • IEIE Transactions on Smart Processing and Computing
    • /
    • v.4 no.5
    • /
    • pp.318-323
    • /
    • 2015
  • We present a new way to create a thermally stable, highly strained germanium (Ge) optical resonator using a novel Ge-on-dual-insulators substrate. Instead of using a conventional way to undercut the oxide layer of a Ge-on-single-insulator substrate for inducing tensile strain in germanium, we use thin aluminum oxide as a sacrificial layer. By eliminating the air gap underneath the active germanium layer, we achieve an optically insulating, thermally conductive, and highly strained Ge resonator structure that is critical for a practical germanium laser. Using Raman spectroscopy and photoluminescence experiments, we prove that the novel geometry of our Ge resonator structure provides a significant improvement in thermal stability while maintaining good optical confinement.

Optimization of ZnO:Al properties for $CuInSe_2$ superstrate thin film solar cell

  • Lee, Eun-U;Park, Sun-Yong;Lee, Sang-Hwan;Kim, U-Nam;Jeong, U-Jin;Jeon, Chan-Uk
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2010.05a
    • /
    • pp.36.1-36.1
    • /
    • 2010
  • While the substrate-type solar cells with Cu(In,Ga)Se2 absorbers yield conversion efficiencies of up 20%[1], the highest published efficiency of Cu(In,Ga)Se2 superstrate solar cell is only 12.8% [2]. The commerciallized Cu(In,Ga)Se2 solar cells are made in the substrate configuration having the stacking sequence of substrate (soda lime glass)/back contact (molybdenum)/absorber layer (Cu(In,Ga)Se2)/buffer layer (cadmium sulfide)/window layer (transparent conductive oxide)/anti reflection layer (MgF2) /grid contact. Thus, it is not possible to illuminate the substrate-type cell through the glass substrate. Rather, it is necessary to illuminate from the opposite side which requires an elaborate transparent encapsulation. In contrast to that, the configuration of superstrate solar cell allows the illumination through the glass substrate. This saves the expensive transparent encapsulation. Usually, the high quality Cu(In,Ga)Se2 absorber requires a high deposition temperature over 550C. Therefore, the front contact should be thermally stable in the temperature range to realize a successful superstrate-type solar cell. In this study, it was tried to make a decent superstrate-type solar cell with the thermally stable ZnO:Al layer obtained by adjusting its deposition parameters in magnetron sputtering process. The effect of deposition condition of the layer on the cell performance will be discussed together with hall measurement results and current-voltage characteristics of the cells.

  • PDF

Patterning of liquid crystal alignment layers using selective dewetting process in a thermoplastic polymer film

  • Kim, Hak-Rin;Shin, Min-Soo;Lee, You-Jin;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2006.08a
    • /
    • pp.1719-1722
    • /
    • 2006
  • We proposed a soft-lithographic method for aligning a liquid crystal (LC) in patterned azimuthal orientations. It is demonstrated that a thermoplastic polystyrene layer is patterned from a thermally stable polyimide layer via pressure-assisted capillary force lithography, which provides multidirectional LC alignment condition simply followed by a unidirectional rubbing process.

  • PDF

Towards Thermally Stable Tandem Organic Solar Cells

  • Yang, Feng;Wang, Sihan;Kim, Ji-Hwan;Kim, Yong-Sang
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.410.2-410.2
    • /
    • 2016
  • Tandem structure is promising in organic solar cells because of its double open-circuit voltage (VOC) and efficient photon energy conversion. In a typical tandem device, the two single sub-cells are stacked and connected by an interconnecting layer. The fabrication of two sub-cells are usually carried out in a glovebox filled with nitrogen or argon gas, which makes it expensive and laborious. We report a glovebox-free fabricated inverted tandem organic solar cells wherein the tandem structure comprises sandwiched interconnecting layer based on p-doped hole-transporting, metal, and electron-transporting materials. Complete fabrication process of the tandem device was performed outside the glove box. The tandem solar cells based on poly(3-hexylthiophene) (P3HT) and (6,6)-phenyl C61-butyric acid methyl ester (PCBM) can realize a high VOC, which sums up of the two sub-cells. The tandem device structure was ITO/ZnO/P3HT:PCBM/PEDOT:PSS/MoO3/Au/Al/ZnO-d/P3HT:PCBM/PEDOT:PSS/Ag. The separate sub-cells were morphologically and thermally stable up to 160 oC. The high stability of the active layer benefits in the fabrication processes of tandem device. The performance of tandem organic solar cells comes from the sub-cells with an 50 nm thick active layer of P3HT:PCBM, achieving an average power conversion efficiency (PCE) of 2.9% (n=12) with short-circuit current density (JSC) = 4.26 mA/cm2, VOC = 1.10 V, and fill factor (FF) = 0.62. Based on these findings, we propose a new method to improve the performance and stability of tandem organic solar cells.

  • PDF

Printability of Thermally and Chemically Stable Silica-Titanium Dioxide Composite Coating Layer (실리카-이산화티탄 복합 코팅층의 열적, 화학적 안정성 및 인쇄적성 평가)

  • Kim, Hye Jin;Han, Kyu Sung;Hwang, Kwang Taek;Nahm, Sahn;Kim, Jin Ho
    • Korean Journal of Materials Research
    • /
    • v.29 no.10
    • /
    • pp.631-638
    • /
    • 2019
  • As automation systems become more common, there is growing interest in functional labeling systems using organic and inorganic hybrid materials. Especially, the demand for thermally and chemically stable labeling paper that can be used in a high temperature environment above $300^{\circ}C$ and a strong acid and base atmosphere is increasing. In this study, a composite coating solution for the development of labeling paper with excellent thermal and chemical stability is prepared by mixing a silica inorganic binder and titanium dioxide. The silica inorganic binder is synthesized using a sol-gel process and mixed with titanium dioxide to improve whiteness at high-temperature. Adhesion between the polyimide substrate and the coating layer is secured and the surface properties of the coating layer, including the thermal and chemical stability, are investigated in detail. The effects of the coating solution dispersion on the surface properties of the coating layer are also analyzed. Finally, it is confirmed that the developed functional labeling paper showed excellent printability.

MgO Thin Film Characterization in a Vacuum In-line Sealing Process for High-efficiency PDP (고효율 PDP를 위한 진공 인라인 실장에서의 MgO 보호막 영향분석)

  • Kwon, Sang-Jik;Jang, Chan-Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.18 no.11
    • /
    • pp.1019-1023
    • /
    • 2005
  • We have examined the electrical and optical characteristics of the plasma display panel produced by vacuum in-line sealing technology. In the MgO layer deposited at room temperature, after sealing at the panel temperature of $430^{\circ}C$, the luminous efficiency decreased compared with that of the panel before sealing. Moreover, firing and sustain voltage of the sealed panel increased compared with that of the panel before sealing. This was resulted from that the MgO protective layer was cracked by the softening of the dielectric layer during the sealing process. In order to avoid the MgO crack during the vacuum in-line sealing, thermally stable MgO layer or lower temperature sealing is required.