• Macromolecular Research
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• v.17 no.3
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• pp.149-155
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• 2009

The thermal decomposition behavior and degradation characteristics off our different thermotropic liquid crystalline polymers (TLCPs) were studied. The thermal decomposition behavior was determined by means of thermogravimetric analysis (TGA) at different heating rates in nitrogen and air. The order of the thermal stability was as follows: multi-aromatic polyester > hydroxybenzoic acid (HBA)/hydroxynaphthoic acid (HNA) copolyester > HNA/hydroxyl acetaniline (HAA)/terephthalic acid (TA) copolyester > HBA/Poly(ethylene terephthalate) (PET) copolyester. The activation energies of the thermal degradation were calculated by four multiple heating rate methods: Flynn-Wall, Friedman, Kissinger, and Kim-Park. The Flynn-Wall and Kim-Park methods were the most suitable methods to calculate the activation energy. Samples were exposed to an accelerated degradation test (ADT), under fixed conditions of heat ($63{\pm}3^{\circ}C$), humidity ($30{\pm}4%$) and Xenon arc radiation ($1.10\;W/m^2$), and the changes in surface morphology and color difference with time were determined. The TLCPs decomposed, discolored and cracked upon exposure to ultraviolet radiation.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2007.05a
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• pp.353-356
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• 2007

This paper presents the thermal and electrical characteristics of ZnO arrester blocks under the AC voltages. The leakage currents of ZnO arrester blocks were measured as a function of time. The temperature distributions of ZnO arrester blocks were observed by the forward looking infrared camera The degradation and thermal runaway of ZnO arrester blocks were closely related with the temperature limit of ZnO arrester blocks which decided heat generation and dissipation As a result, the degradation and thermal runaway of ZnO arrester blocks depend on the temperature and leakage current of ZnO arrester blocks.

• Nuclear Engineering and Technology
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• v.56 no.4
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• pp.1277-1283
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• 2024

This study presents a radiation-induced thermal conductivity degradation (TCD) model of zirconium as compared to the conventional UO2 TCD model. We derived the governing factors of the radiation-induced TCD model, such as maximum TCD value and temperature range of TCD. The maximum TCD value was derived by two methods, in which 1) experimental result of 32 % TCD was directly utilized as the maximum TCD value and 2) a theoretical approach based on dislocation was applied to derive the maximum TCD value. Further, the temperature range of TCD was determined to be 437-837 K by 1) experimental results of post-annealing of irradiation hardening as compared to 2) the rate theory and thermal equilibrium. Consequently, the radiation-induced TCD model of zirconium was derived to be $f_r=1-{\frac{0.32}{1+{\exp}\,\{(T-637)/45\}}}$. Because the thermal conductivity of zirconium is one of the factors determining the storage and transport system, this newly proposed model could improve the safety analysis of spent fuel storage systems.

• Korean Journal of Food Science and Technology
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• v.24 no.3
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• pp.236-239
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• 1992

Glucose was added into 2% MSG solution and studied for its effect on MSG degradation during heating at $100{\sim}120^{\circ}C$ and initial pH of 4 and 5. It was found that thermal degradation of MSG was significantly increased as the glucose concentration increased up to 20%. The values of thermal degradation constant calculated from linear relationship between log(% MSG) and heating time was linearly increased as the glucose concentration increased. The increased effect was more significant at pH5 than pH4.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.5
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• pp.1189-1196
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• 1988

Thermal entrance lengths of turbulent tube flow for viscoelastic polymer solutions are investigated experimentally in the recirculating flow system with tubes of inside diameters 8.5mm(L/D=710) and 10.3mm(L/D=1158), respectively. In the present system, the hydrodynamic and thermal boundary layers develop simultaneously from the beginning of the test section. To provide the boundary condition of constant heat flux at the wall, the test tubes are heated directly by electricity. The polymer solution used in the current study is 1000 wppm aqueous solution of polyacrylamide(Separan AP-273). The apparent viscosity of the polymer solutions circulating in the flow system are measured by the capillary tube viscometer at regular time intervals. Thermal entrance lengths vary due to the rate of degradation. The entrance lengths of degraded polymer solutions are about 500~600 times the diameter. However, the entrance lengths of fresh polymer solutions are greater than the lengths of the test tubes used in this study suggesting that thermal entrance lengths for viscoelastic polymer solutions are greater than 1100 tube times the diameters. Friction factor is almost insensitive to the degradation, but the heat transfer $j_{H}$-factor is affected seriously by degradation. Based on the present experimental data of fresh solutions a correlation for the heat transfer $j_{H}$-factor is presented.ted.

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.3
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• pp.111-118
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• 1998

The intrinsic degradation behavior of $(V_{0.53}Ti_{0.47})_{0.925}Fe_{0.075}$ alloy with BCC structure and the two plateau regions (the low and high plateau region) has been investigate during the temperature-induced hydrogen absorption-desorption cycling (thermal cycling). After 400 thermal cycles between room temperature and $600^{\circ}C$ under 10atm $H_2$, the total reversible hydrogen absorption capacity decreased by about 40%. From thermal desorption analysis it was found that the degradation behavior at each plateau region was different. In addition, XRD analysis showed that the crystal structure of the sample in de-hydrided state was changed from BCC to BCT after degradation, and that of the sample in hydrided state it was maintained as FCC although peaks were broadened after degradation. From the result of static isothermal hydrogenation treatment it were found that crystal structure change from BCC to BCT was caused by the thermal energy. TEM analysis showed that the peak broadening was due to the formation of an amorphous phase in FCC matrix.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.10
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• pp.883-892
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• 2009

We evaluated the degradation properties of various alkanolamine absorbents (MEA, AMP, DEA, and MDEA) having different chemical structures for $CO_2$ capture. The degradation of $CO_2$ absorbent in general was known to be caused by oxygen which is in flue gas and by heat source, respectively. To analyze the effect of $CO_2$ and $O_2$ on degree of degradation, we conducted a variety of experiments at $30^{\circ}C$ and $60^{\circ}C$ (oxidative degradation) and $130^{\circ}C$ and $150^{\circ}C$ (thermal degradation), respectively. DEA showed the worst property for oxidative degradation in the presence of oxygen among the alkanolamine absorbents. In the case of thermal degradation, the degradation of absorbent was occurred for most of absorbents at $150^{\circ}C$. Among these absorbents, MEA and DEA gave the worst results. As a result, AMP which is a primary amine and having a steric hindrance showed the best result through the degradation test. But, the degradation of absorbent proceeded easily in the case of DEA which is a secondary amine and having 2 OH groups in terminal position. Consequently, we have evaluated the degree of degradation of various absorbents having different chemical structures to give the basic data for the development of alkanolamine absorbent.

• Composites Research
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• v.16 no.6
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• pp.33-40
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• 2003

The initial thermal degradation of polymer matrix composite is not observed easily. At the beginning of thermal degradation of polymer matrix composites, phase transformation such as chain scission, oxidation occur, and then micro delamination is produced in matrix and interface between matrix and fiber before blistering. Initial heat damage deteriorate mechanical properties of composites. We presented the detection method of the initial heat damage of composites conveniently using ultrasonic technique. Absorption coefficient and material velocity was measured with thermal degradation and degree of cure. The more thermal degradation was progressed, the more absorption coefficient was increased. When the cure temperature is more high, the absorption coefficient of cured composite is increased and material velocity is decreased. We concluded that cure temperature is more high, the defects such as void is increased and molecular structure cured at high temperature has cross-linking structure which is more absorb the ultrasonic waves.

• Journal of the Korean Wood Science and Technology
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• v.26 no.3
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• pp.9-15
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• 1998

The strength and stiffness of structures would be weakened by thermal degradation of wood members which are exposed to a variety of heat including a fire. For this reason, thermal degraded wood members can't pertinently support the load. However, it is easy to repair or rehabilitate wood structures. So, the degraded wood members which can't support the load can be replaced with new members. For the sake of this advantage, there is a need for nondestructive evaluation(NDE) technique, which is very effective to assess wood members in service. In this paper, it was considered whether the stress wave method is adequate to estimate static bending MOE of thermal degraded wood. As the result, the relationship between static bending MOE and MOEsw in elevated temperature was found out significant. Therefore, the application of stress wave method for estimating static bending MOE of thermal degraded zzwood would be possible. However, it is thought that further research for the effects of exposure temperature, time, and thermal degradation on the relationship between static bending MOEb and MOEsw would be needed.

• Analytical Science and Technology
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• v.6 no.2
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• pp.231-238
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• 1993

The thermal behavior of binder in multi-layer actuator has an effect on the properties of actuator. Binder burn-out process and thermal degradation mechanism of PNN-PZT/Acrylic binder were analyzed by FTIR, DSC, TGA. Binder was burnt out by two step. In oxygen atomsphere, thermal degradation was activated and final residue was minimized to 5%.