• 제목/요약/키워드: thermal treatment.

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Distribution of Anatase Phase Depending on the Thermal Treatment Temperature of Tio2 Nanotubes and Its Effects on the Photocatalytic Efficiency (Tio2 나노튜브의 열처리 온도에 따른 Anatase 상의 분포와 그에 따른 광 촉매 효율)

  • Kim, Se-Im;Hwang, Ji-Hun;Lee, Seung-Wook;Kim, Rak-Kyoung;Son, Su-Min;Shaislamov, Ulugbek;Yang, Jun-Mo;Yang, Bee-Lyong
    • Journal of the Korean Ceramic Society
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    • v.45 no.6
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    • pp.331-335
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    • 2008
  • The purpose of this study is to characterize the photo-catalytic efficiency of $TiO_2$ nanotube with respect to the distribution of anatase phase which can be changed by the annealing temperature of $TiO_2$ nanotube. $TiO_2$ nanotube was fabricated by the anodization method in the 0.5 wt% HF electrolyte. And then the $TiO_2$ nanotube was annealed at temperatures ranging from $380^{\circ}C$ to $780^{\circ}C$ in dry oxygen ambient for 2 h. For the photo-catalytic water-splitting tests, the photocurrent density was measured as a function of applied potential with a potentiostat using a Ag/AgCl reference, Pt counter electrode, and 1 M KOH electrolyte under illumination of UV by a Xe arc lamp of 1 KW. According to the UV photo-catalytic water-splitting tests, the nanotube annealed at $560^{\circ}C$ was found to show the highest photocurrent density.

Control of Algal Blooms in Eutrophic Water Using Porous Dolomite Granules

  • Huh, Jae-Hoon;Choi, Young-Hoon;Lee, Shin Haeng;Cheong, Sun Hee;Ahn, Ji Whan
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.108-113
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    • 2017
  • The use of aluminum-based coagulants in water pretreatment is being carefully considered because aluminum exposure is a risk factor for the onset of Alzheimer's disease. Lightly burned-dolomite kiln dust (LB-DKD) was evaluated as an alternative coagulant because it contains high levels of the healthful minerals calcium and magnesium. An organic pore forming agent (OPFA) was incorporated to prepare porous granules after OPFA removal through a thermal decomposition process. A spray drying method was used to produce uniform and reproducible spherical granules with low density, since fine dolomite particles have irregular agglomeration behavior in the hydration reaction. The use of fine dolomite powder and different porosity granules led to a visible color change in raw algae (RA) containing water, from dark green to transparent colorlessness. Also, dolomite powders and granules exhibited a mean removal efficiency of 48.3% in total nitrogen (T-N), a gradual increase in the removal efficiency of total phosphorus (T-P) as granule porosity increased. We demonstrate that porous dolomite granules can improve the settling time and water quality in summer seasons for the emergent treatment of excessive algal blooms in eutrophic water.

Electrochemical Studies of Carbon Felt Electrode Modified Under Airless Conditions for Redox Flow Batteries

  • Noh, Tae Hyoung;Kim, Min Young;Kim, Da Hye;Yang, Seung Hoon;Lee, Jong Ho;Park, Hong Sik;Noh, Hee Sook;Lee, Moo Sung;Kim, Ho Sung
    • Journal of Electrochemical Science and Technology
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    • v.8 no.2
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    • pp.155-161
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    • 2017
  • Carbon felts were prepared under various thermal conditions to improve the electrochemical properties of vanadium redox flow batteries. The number of C-O and/or C-OH functional groups on the surface of the electrodes treated under airless conditions was much larger than that of the untreated and partially oxygen-treated electrodes. The carbon felt treated under airless conditions had the lowest surface area. The overall kinetic properties of the redox reaction were greatly improved for the carbon felt treated under airless conditions; i.e., the reversibility of the anodic and cathodic reactions associated with the $VO_2{^+}/VO^{2+}$ couple became more reversible. Single-cell tests indicated that the carbon felt exhibited an excellent discharge capacity of $3.1Ah{\cdot}g^{-1}$ at $40mA{\cdot}cm^{-2}$, and the corresponding Coulombic, voltage, and energy efficiencies were 89.5%, 91.8%, and 82.2%, respectively.

Study of Effect of PZT Thin Film Prepared in Different Post-Annealing Temperature Using SIMS (이차이온질량분석기를 이용한 PZT 박막의 후열처리 온도에 따른 특성에 관한 연구)

  • Shenteng, Shenteng;Lee, Tae-Yong;Lee, Kyung-Chun;Hur, Won-Young;Shin, Hyun-Chang;Kim, Hyun-Duk;Song, Joon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.5
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    • pp.392-397
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    • 2011
  • The effect of various post-annealing temperature to sputtered Pb(Zr,Ti)$O_3$ (PZT) thin films was investigated. The crystallization process, surface morphology and the electrical characteristics strongly depends on the rapid thermal annealing (RTA). In radio frequency (RF) sputtering methods, there were many papers mostly forcing on the crystal forming and the surface variations with different elements distribution (Pb, Ti, Zr, O) on the surface of the PZT layer. In this experiment, the post-annealing treatment promoted the Pb volatilization in PZT thin film and affected the Ti diffused throughout the Pt layer into the PZT layer. Second ion mass spectroscopy (SIMS) analysis was employed to show that the Pb element in the PZT layer was decreased at the same time the Ti element mass was slight decreased than Pb with increasing RTA temperature. That result prove the content of Pb affect the PZT thin film property.

Spherical UO3 Gel Preparation Using the External Gelation Method (External Gelation 방법을 이용한 구형 UO3 Gel 입자 제조)

  • Jeong, KyungChai;Kim, YeonKu;Oh, SeungChul;Cho, Moon-Sung;Lee, YoungWoo;Chang, JongWha
    • Journal of the Korean Ceramic Society
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    • v.42 no.11 s.282
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    • pp.729-736
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    • 2005
  • HTGR (High Temperature Gas-cooled Reactor) is spotlighted to next generation nuclear power plant for producing the clean hydrogen gas and the electricity. In this study, the spherical $UO_3$ gel particles were prepared by the external gelation process, and the characteristics of these particles were analyzed the particle shape, composition of precipitate, and thermal decomposition characteristics with the Streoscope, FT-IR, and X-ray diffractometer. Raw material of the ADUN (Acid Deficient Uranyl Nitrate) solution, which has [$NO_3$]/[U] mole ratio = 1.75, was obtained from dissolution of the $U_{3}O_{8}$ powder with concentrated $HNO_3$, and its concentration is 3.5 M-U/l. The broth solution is prepared with the ADUN, urea, PVA, and THFA solution. The droplets of the broth solution was made through a nozzle system. From this study, we obtained the following results; 1) an externel chemical gelation process is a suitable method in the spherical $UO_3$ particle production, 2) the particle shape are changed by an urea mixing time, THFA volume, and the viscosity of the broth solution, 3) the amorphous $UO_3$ particles obtained from these experiments was converted to $U_{3}O_{8}$ and then $UO_2$ by heat treatment in hydrogen atmosphere at $600^{\circ}C$.

Structural, Magnetic, and Magnetoresistance Properties of Co-evaporated Ag-Co Nano-granular Alloy Films (동시 진공증착한 Ag-Co 미세입상 합금박막의 구조, 자기 및 자기저항 특성)

  • 이수열;이성래
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.48-53
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    • 1995
  • The structure, magnetic properties and magnetoresistance phenorrena of Ag-Co nano-granular alloy films prepared by a thermal co-evaporation were studied. Supersaturated fee Ag-Co solid solution and fee Co clusters coexisted in the as-deposited state. As Co content increases from 20 to 55 at.% Co, the grain size of the Ag matrix decreases from 147 to $67{\AA}$, and the Co solubility in the Ag matrix increases from 2.5 to 6.7%. Ag-Co alloy films having composition below 25 at.% Co showed mainly superparamagnetic behavior and above that composition, they showed both paramagnetic and ferromagnetic l::ehavior in the as-deposited state. The maximum magnetoresistance of 19% at R. T. and 10 kOe was obtained in the as-deposited 30 at.% Co alloy film. Heat treatment did not improve the MR ratio tecause most of the Co was already precipitated in the as-deposited state.

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Coercivity Enhancement of Sintered Nd-Fe-B Magnets by Grain Boundary Diffusion with DyH3 Nanoparticles

  • Liu, W.Q.;Chang, C.;Yue, M.;Yang, J.S.;Zhang, D.T.;Liu, Y.Q.;Zhang, J.X.;Yi, X.F.;Chen, J.W.
    • Journal of Magnetics
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    • v.18 no.4
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    • pp.400-404
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    • 2013
  • Grain boundary diffusion technique with $DyH_3$ nanoparticles was applied to fabricate Dy-less sintered Nd-Fe-B permanent magnets with high coercivity. The magnetic properties and microstructure of magnets were systematically studied. The coercivity and remanence of grain boundary diffusion magnet were improved by 60% and reduced by 7% compared with those of the original magnet, respectively. Meanwhile, both the remanence temperature coefficient (${\alpha}$) and the coercivity temperature coefficient (${\beta}$) of the magnets were improved after diffusion treatment. Investigation shows that Dy is preferentially enriched as (Nd, Dy)$_2Fe_{14}B$ phase in the surface region of the $Nd_2Fe_{14}B$ matrix grains indicated by the remarkable enhancement of the magneto-crystalline anisotropy field of the magnet. As a result, the magnet diffused with a small amount of Dy nanoparticles possesses enhanced coercivity without remarkably sacrificing its magnetization.

A Study of Iteration Method for 2-Dimensional 2-Group Diffusion Problems (2차원 2군 확산 문제의 반복법에 대한 고찰)

  • Jong Hwa Chang;Kil Yoo Kim;Chang Hyun Chung
    • Nuclear Engineering and Technology
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    • v.15 no.1
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    • pp.33-40
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    • 1983
  • It is shown that the Shanks sequence $E_{k}$-transformation and the conventional extrapolation method are theoretically related. The $E_1$$^2$-transformation method is then applied for the multigroup diffusion problems. The diffusion code, CITATION, is modified for this study and the computing time is compared for each iteration tactics. The Equipose method, in which only sing1e inner iteration for each energy group is carried for an outer iteration, has been known as the fastest iteration method. However, in the case of 3-group problems, the proposed method, in which the number of inner iteration for the fast and thermal group is 2 and 1 respectively, gives better convergency than the Equipose method by about 12%. The double extrapolation method results in faster computing time than the single extrapolation method without computing storage problem. It is, however, to note that this method is verified only for a two-group treatment.t.

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The Change of Superficial and Deep Heats in Ultrasound Application by Coupling Media (초음파 적용시 전파매질에 따른 표면열과 심부열의 변화)

  • Lee, Young-Hi;Kim, Jin-Sang
    • The Journal of Korean Physical Therapy
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    • v.12 no.2
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    • pp.57-67
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    • 2000
  • The purpose of this study was carried out in five rabbits of 3kg to investigate the change of superficial and deep heats in ultrasound application by coupling media. Temperature measured with thermistor needle at skin. subcutaneous, muscle in before coupling media application, after coupling media application. 2minutes. 5minutes, 7minutes, 10minutes. Coupling media was used gel, glycerin, distilled water. The data was analyzed using spss/pc+and t-test The results were as fallow : 1. With skin. gel was significant temperature change in 2minutes(p<.05). glycerin was significant temperature change in 2minutes(p<.05), 5minutes(p<.05), 7minutes(p<.01), 10minutes(p<.01). distilled water was significant temperature change in post coupling media(p<.05), 2minutes(p<.01). 5minutes(p<.05). 7minutes(p<.01). 10minutes(p<.01). With subcutaneous. gel was no temperature change. glycerin was significant temperature change in 2minutes(p<.05), 5minutes(p<.05), 10minutes(p<.01). distilled water was no temperature change. With muscle. gel was no temperature change. glycerin was significant temperature change in 2minutes(p<.05). 5minutes(p<.05). 7minutes(p<.05). 10minutes( p<.05). distilled water was significant temperature change in 10minutes(p<.05). 2. Superficial heats of skin and subcutaneous was higher temperature change than Deep heats of muscle. 3. Gel. glycerin. distilled Water required minimum treatment 10minutes fur thermal effect. 4. Gel was low temperature change superficial and deep heats. and glycerin was high temperature change superficial and deep heats. This results show that gel is high transmissiveness in the coupling media and glycerin is low transmissiveness in the coupling media.

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The appearance change and heat·moisture transfer properties of knitted fabric by yarn shrinkage (원사의 수축에 따른 다공성 편성물의 형태변화와 열·수분 전달특성)

  • Sang, Jeong-Seon;Park, Juhyun;Lee, Mee-Sik;Oh, Kyung Wha
    • The Research Journal of the Costume Culture
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    • v.25 no.6
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    • pp.880-892
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    • 2017
  • In this study, the appearance change and the heat moisture transfer properties of knitted fabric by yarn shrinkage were examined to obtain useful data on the development of thermo-sensitive functional materials. Eleven types of knitted fabric were knitted using highly bulky acrylic-blended yarn. After shrinking the specimens using dry heat treatment, the appearance change and thickness were measured. An HEC simulator was adopted for measuring the heat moisture transfer properties of specimens by yarn shrinkage. When holes were arranged vertically in the mesh structure, the specimens with 2,500 and 5,000 holes showed high percent change of hole area, appearance, and thickness. When holes were diagonally arranged in the mesh structure, the percent change of hole area in the specimen with 1,250 holes was larger than the one with 2,500 holes. However, the dimensional stability of the specimen with 2,500 holes was better because of its smaller appearance and thickness change. In the tuck structure, the percent change of hole area in the specimen with 625 and 416 holes was relatively large compared with the appearance and thickness change. Furthermore, the hole size in the tuck structure was smaller than that in the mesh structure but the percent change of hole area was larger. Therefore, it was proved that the tuck structure is more suitable than the mesh structure for developing thermo-sensitive functional materials. Heat moisture transfer property test verified that the change of hole area by yarn shrinkage enabled obtaining the thermal effect due to the distinct temperature difference in the inner layer.