• Title/Summary/Keyword: thermal ionization

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Influence of Combustion Flame on Flashover Characteristics Due to Fire Occurrence (화재발생시 직류 플래시오버특성에 미치는 연소화염의 영향)

  • 하장호;김인식;정우영
    • Fire Science and Engineering
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    • v.17 no.2
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    • pp.25-34
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    • 2003
  • In this paper, characteristics of the DC flashover voltage in the horizontal air gap of sphere-sphere/needle-needle electrode system were investigated when the combustion flame of paraffin oil was present between the two electrodes. The reduction characteristic of DC flashover voltage was discussed with the thermal ionization process, the relative air density and the deflection phenomena in the shape of flames that caused by the corona wind and Coulomb's force. As the results of an experimental investigation, It was found that the reduction characteristics of DC flashover voltages with flames were affected strongly by the flame deflection and the change of relative air density. It was also found that the thermal ionization phenomena were not important in the range of combustion flame temperature.

A Correction Method for the Peak Tailing Backgrounds for Accurate Isotope Ratio Measurements of Uranium in Ultra Trace Levels using Thermal Ionization Mass Spectrometry

  • Park, Jong-Ho;Choi, In-Hee;Park, Su-Jin;Lee, Myung-Ho;Song, Kyu-Seok
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4327-4331
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    • 2011
  • A new method in thermal ionization mass spectrometry (TIMS) was developed to correct peak tailing backgrounds in the isotope ratio measurements of uranium in ultra trace levels for higher accuracy. Two different uranium standard reference materials (U005 and U030) were used to construct databases of signal intensities at mass 234 u and mass 236 u, which correspond to the two uranium minor isotopes, and signal intensity of $^{238}U$. Correlations between peak tailing backgrounds and $^{238}U$ were obtained by least-squares regression on calculated backgrounds at mass 234 u and mass 236 u with respect to the signal intensity of $^{238}U$ followed by separation of the peak tails of the two major isotopes of uranium ($^{235}U$ and $^{238}U$), which enables us to obtain a master equation for peak tailing background correction on all kinds of samples. Verification of the correction method was carried out using U010 and IRMM-040a.

Effect of a Magnetic Field on Thermal Conductivity of Partially Ionized Gases

  • Yun, Hong-Sik
    • Journal of The Korean Astronomical Society
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    • v.9 no.1
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    • pp.1-6
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    • 1976
  • The translational and reactive parts of thermal conductivity of a partially ionized solar magneto-plasma gas have been calculated based on Yun and Wyller's formulation (1972) along with Devoto's theory(1968). The computed results are presented as functions of temperature and pressure for given magnetic field strengths. The results of the calculations show that for most photospheric conditions the magnetic field does not play any important role in characterizing thermal properties of the ionized gas. However, when the gas pressure is low(e.g., P<10 dynes/$cm^2)$) the field becomes extremely effective even if its strength is quite small (e.g., B<0.1 gauss). The reactive part of the thermal transport is found to be very important when the gas is undertaking active ionization.

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Analysis of soil discharge characteristics in sand with water content (수분 함유량에 따른 모래의 지중방전 특성 분석)

  • Lee, Bok-Hee;kim, Hoe-Gu;Park, Geon-Hun;Lee, Kyu-Sun;Ahn, Chang-Hwan
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.05a
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    • pp.436-439
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    • 2008
  • It has been known that the value of soil resistance drops when a high impulse curennt is injected into a grounding electrode. In this paper, impulse generator is used to investigate the dry soil and wet soil characteristics in cylinderical test cell. The impulse resistances and breakdown characteristics were discussed based on its voltage and current traces. As a result, sand resistances are decreased with increasing the applied currents. It was thought that a decrease in resistance of dry sand with increasing current is due to both thermal and ionization processes. On the other hand, in case there is no water presence in the soil, the reduction in resistance as the currents are of dry sand increased is mainly due to the ionization process.

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Combustion Characteristics of Ionized Fuels for Battery System Safety (배터리 시스템 안전을 위한 이온화 연료의 연소 특성)

  • Ko, Hyeok Ju;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.33 no.1
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    • pp.22-27
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    • 2018
  • Many electronic devices are powered by various rechargeable batteries such as lithium-ion recently, and occasionally the batteries undergo thermal runaway and cause fire, explosion, and other hazards. If a battery fire should occur in an electronic device of vehicle and aircraft cabin, it is important to quickly extinguish the fire and cool the batteries to minimize safety risks. Attempts to minimize these risks have been carried out by many researchers but the results have been still unsatisfied. Because most rechargeable batteries are operated on the ion state during charge and discharge of electricity and the combustion of ion state has big difference with normal combustion. Here we focused on the effect of ions including an electron during combustion process. The effects of an ionized fuel on the flame stability and the combustion products were experimentally investigated in the propane jet diffusion flames. The burner used in this experiment consisted of 7.5 mm diameter tube for fuel and the propane was ionized with th ionizer (SUNJE, SPN-11). The results show that toe overall flame stability and shape such as flame length has no significant difference even in the higher ion concentration. However the fuel ionization affects to the pollutant emissions such as NOx and soot. NOx and CO emissions measured in post flame region decreased by fuel ionization, especially high fuel velocity, i.e. high ion density. TGA analysis and morphology of soot by TEM indicates that the fuel ionization makes soot to be matured.

Characterization of Thermal Degradation of Polytrimethylene Terephthalate by MALDI-TOF Mass Spectrometry

  • Jang, Sung-Woo;Yang, Eun-Kyung;Jin, Sung-Il;Cho, Young-Dal;Choe, Eun-Kyung;Park, Chan-Ryang
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.833-838
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    • 2012
  • The thermal degradation products of polytrimethylene terephthalate (PTT) obtained by heating the sample in the temperature range of $250-360^{\circ}C$ under non-oxidative conditions was characterized using MALDI-TOF (matrix assisted laser desorption/ionization) mass spectrometry. The structures of the degradation products were determined and the relative compositions were estimated. The MALDI-TOF mass spectra of the thermally degraded PTT sample showed three main series of oligomer products with different end groups, which were carboxyl/carboxyl, carboxyl/allyl, and allyl/allyl. In contrast to the thermal degradation of polyethylene terephthalate (PET), the oligomers containing terephthalic anhydrides were not detected, whereas the formation of oligomers containing the unsaturated allyl ester group was confirmed by mass assignment. From these results, it was concluded that the thermal degradation of PTT proceeds exclusively through the ${\beta}$-CH hydrogen transfer mechanism, which is in accordance with the proposed reaction mechanism for the thermal degradation of polybutylene terephthalate (PBT).

Formation of star clusters by cloud-cloud collision

  • Han, Daniel;Kimm, Taysun
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.68.3-68.3
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    • 2019
  • We present the preliminary results on the formation of star clusters by cloud-cloud collision. For this purpose, we perform sub-parsec scale, radiation-hydrodynamic simulations of giant molecular clouds using a sink particle algorithm. The simulations include photo-ionization, direct radiation pressure, and non-thermal radiation pressure from infrared and Lyman alpha photons. We confirm that radiation feedback from massive stars suppresses accretion onto sink particles. We examine the collision-induced star formation and discuss the possibility on the formation of a globular cluster.

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Improvement of Luminance Properties of Blue OLEO using $SnDP(HPB)_2$ (Sn-complexes를 이용한 OLED의 발광 특성 향상에 관한 연구)

  • Kim, Dong-Eun;Choi, Gyu-Chae;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.121-122
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    • 2008
  • Blue emitting materials have been explored by various researchers. However, blue-emitting materials with high luminous efficiency, good color purity, and thermal stability are still much desired. In this study, we synthesized a new blue luminescent material, $SnDP(HPB)_2$ which is low molecular compound and thermal stability. The PL spectrum of $SnDP(HPB)_2$ was observed blue at the wavelength of 447nm. The ionization potential(IP) and the electron affinity(EA) of $SnDP(HPB)_2$ was measured to be 6.7 eV and 3.0 eV, respectively. The fundamental structure of the OLED was ITO/NPB/$SnDP(HPB)_2/Alq_3$/LiF/Al. As a Result, we obtained to enhance the performance of blue OLED.

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A New Technology for Strengthening Surface of Forging Die

  • Xin Lu;Zhongde Liu
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10b
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    • pp.189-192
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    • 2003
  • The Electro-thermal Explosion Coating (EEC) technique is a new surface treatment technology emerged in recent years. It uses an electrical discharge (with very high voltage from 5 to 30 kV or more) to produce a pulse current with large density inside the material to be deposited, the metal wire undergo the heating, melting, vaporization, ionization and explosion processes in a very short time (from tens ns to several hundreds ${\mu}s$), and the melted droplets shoot at the substrate with a very high velocity (3000 - 4500 m/s), so that the coating materials can be deposited on the surface of the substrate. Coatings with nano-size grains or ultra- fine grains can be formed because of rapid solidification (cooling rate up to $10^6-10^9\;k/s$). Surface of the substrate (about $1-5{\mu}m$ in depth) can be melted rapidly and coatings with very high bonding strength can be obtained.

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