• Title/Summary/Keyword: thermal dispersion

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Titania-assisted dispersion of carboxylated single-walled carbon nanotubes in ZnO sol for transparent conducting films with high thermal stability ($TiO_2$ 도입에 따른 ZnO 졸에서의 단일벽 탄소나노튜브의 분산안정성 및 그 투명전도성 필름의 고온 안정성)

  • Kim, Bo-Gyeong;Han, Joong-Tark;Jeong, Hee-Jin;Jeong, Seung-Yol;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.277-277
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    • 2010
  • We present facile chemical route stabilizing dispersion of carboxylated single-Walled carbon nanotubes (SWCNTs) in ZnOsol prepared by using diethanolamine as a stabilizer. The dispersion was stabilized via capping of carboxyl groups on the SWCNT surface by a titania layer. We also demonstrated that the conductivity of the films prepared P3/$TiO_2$/ZnO as enhanced by therml treatment, and the thermal stbility of the film improved hybridization with ZnO sol pristine P3, P3/$SiO_2$ and P3/$TiO_2$ hybrid films.

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The rheological behavior of collagen dispersion/poly(vinyl alcohol) blends

  • Lai, Guoli;Du, Zongliang;Li, Guoying
    • Korea-Australia Rheology Journal
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    • v.19 no.2
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    • pp.81-88
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    • 2007
  • Blends of collagen dispersion (COL) with poly(vinyl alcohol) (PVA) in different weight ratios were investigated by oscillatory rheometry, Fourier transform-infrared spectroscopy and scanning electron microscopy. It was found that even with 80% of PVA, the COL/PVA blends behaved more like collagen dispersion than pure PVA solution in the dynamic thermal and frequency processing, for instance, a dominant elastic appearance (G'>G"), a similar shear thinning behavior and the thermal denaturation below $40^{\circ}C$. However, influence on the blend behaviour by PVA was noticeable, for instance, an increase of dynamic denaturation temperature, the decreasing intensity of amide I, II and III bands as well as the diminishing irregular pores on the surface of blends. The interaction between collagen and PVA could be observed, especially at the regions with low content or high content of PVA.

Preparation and Characterization of Polyimide/Carbon-Nanotube Composites

  • Kim, Bong-Sup;Bae, Sang-Hoon;Park, Young-Hwan;Kim, Ji-Heung
    • Macromolecular Research
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    • v.15 no.4
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    • pp.357-362
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    • 2007
  • Polyimide/carbon nanotube (CNT) composite films, for potential use in high performance microelectronics and aerospace applications, were prepared by mixing a polyisoimide (PII) solution and a CNT suspension in NMP, followed by casting, evaporation and thermal imidization. The CNTs were modified by a nitric acid treatment to improve the thermal and electrical properties, as well as to provide good dispersion of the CNTs in a polymer matrix. The formation of functional groups on the modified CNT was confirmed by Raman spectroscopy. Scanning electron microscopy revealed the modified CNTs to be well dispersed in the polyimide matrix, with a uniform diameter of ca. 50 nm. The thermal stability of the films containing the CNTs was improved due to the enhanced interfacial interaction and good dispersion between the polyimide matrix and modified CNTs. In addition, the thermal expansion coefficient of the composites films was slightly decreased, but the dielectric constants increased linearly with increasing CNT content.

Stabilization and Thermal Properties of Carbon Nanotubes/Cu Nanocomposites Prepared by Molecular-Level Mixing

  • Hong, Youn-Jeong;Jung, Chung-Hun;Kim, Hye-Jin;Lee, Kyu-Mann
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1378-1381
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    • 2006
  • The CNTs are the most extensively studied material which are characterized by the complete property of matter, structure, and the large thermal conductivity (Thermal conductivity of $CNTs\;{\sim}>2000W/mK$ vs. Thermal conductivity of Aluminum ${\sim}\;>204W/mK$). Thus, they are successfully applied to the various fields. However, due to the strong agglomeration caused by the van der waal's force, their applications are limited. In the present study, a new method for CNTs dispersion was developed by using the mechanical dispersion, acid treatment, and then Cu was coated. This process produces CNTs/Cu nanocomposite powders, whereby the CNTs are homogeneously located within the Cu powders. The thermal properties of the CNTs/Cu nanocomposite were investigated.

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Effect of surface treatment of graphene nanoplatelets for improvement of thermal and electrical properties of epoxy composites

  • Kim, Minjae;Kim, Yeongseon;Baeck, Sung Hyeon;Shim, Sang Eun
    • Carbon letters
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    • v.16 no.1
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    • pp.34-40
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    • 2015
  • In this study, in order to improve the thermal and electrical properties of epoxy/graphene nanoplatelets (GNPs), surface modifications of GNPs are conducted using silane coupling agents. Three silane coupling agents, i.e. 2-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane (ETMOS), 3-glycidoxypropyltriethoxysilane (GPTS), and 3-glycidoxypropyltrimethoxysilane (GPTMS), were used. Among theses, GPTMS exhibits the best modification performance for fabricating GNP-incorporated epoxy composites. The effect of the silanization is evaluated using transmission electron microscopy (TEM), scanning electron microscopy, thermogravimetric analysis, and energy dispersive X-ray spectroscopy. The electrical and thermal conductivities are characterized. The epoxy/silanized GNPs exhibits higher thermal and electrical properties than the epoxy/raw GNPs due to the improved dispersion state of the GNPs in the epoxy matrix. The TEM microphotographs and Turbiscan data demonstrate that the silane molecules grafted onto the GNP surface improve the GNP dispersion in the epoxy.

Preparation and Heat Transfer Properties of Nanoparticle-in-Transformer Oil Dispersions as Advanced Energy-efficient Coolants (고효율 냉각용 나노분말/절연유 분산액의 제조 및 열전달특성)

  • Choi, Cheol;Oh, Je-Myung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.81-82
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    • 2006
  • The purposes of the present study are to produce a high thermal efficient of oil-based nanofluids which can be used as ultra-high voltage transformer oil, and to investigate their thermal and physical properties under static and dynamic conditions. Three kinds of nanofluids are prepared by dispersing $Al_2O_3$ or AlN nanoparticles in transformer oil. The thermal conductivities of the nanoparticles-oil mixtures increase with temperature, particle volume concentration and thermal conductivity of solid particle itself. It was quite important to eliminate $H_2O$ as byproducts of esterification and excess oleic acid which did not form stable chemical bonds with powder surface to get high dispersion stability.

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Enhancing Thermal Conductivity in Epoxy Composites with Functionalized Boron Nitride Nanosheets

  • Yang Soo Kim;Ik-Tae Im;Jong Seok Kim
    • Korean Journal of Materials Research
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    • v.33 no.12
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    • pp.503-510
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    • 2023
  • This comprehensive study delves into the intricate process of exfoliating and functionalizing boron nitride nanosheets (BNNSs) extracted from hexagonal boron nitride (h-BN), and meticulously explores their potential application within epoxy composites. The extensive research methodology encompasses a sequence of treatments involving hydrothermal and sonication processes aimed at augmenting the dispersion of BNNSs in solvents. Leveraging advanced analytical techniques such as Raman spectroscopy, X-ray diffraction, and FTIR spectroscopy, the study rigorously analyzes a spectrum of changes in the BNNS's properties, including layer count variations, interlayer interactions, crystal structure modifications, and the introduction of functional groups. The research also rigorously evaluates the impact of integrating BNNSs, specifically glycidyl methacrylate (GMA)-functionalized BNNSs, on the thermal conductivity of epoxy composites. The conclusive findings exhibit notable enhancements in thermal properties, predominantly attributed to the enhanced dispersion of fillers and enhanced interactions within the epoxy matrix. This pioneering work illuminates the wide potential of functionalized BNNSs for significantly enhancing the thermal conductivity of epoxy composites, paving the way for advanced materials engineering and practical applications.

USE OF A CENTRIFUGAL ATOMIZATION PROCESS IN THE DEVELOPMENT OF RESEARCH REACTOR FUEL

  • Kim, Chang-Kyu;Park, Jong-Man;Ryu, Ho-Jin
    • Nuclear Engineering and Technology
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    • v.39 no.5
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    • pp.617-626
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    • 2007
  • A centrifugal atomization process for uranium fuel was developed in order to fabricate high uranium density dispersion fuel for advanced research reactors. Spherical powders of $U_3Si$ and U-Mo were successfully fabricated and dispersed in aluminum matrices. Thermal and mechanical properties of dispersion fuel meat were characterized. Irradiation tests at the research reactor HANARO confirm the excellent performance of high uranium density dispersion fuel.

An Effect of Heat Input on Thermal Storage for Horizontal Thermal Storage Tank with Heat pipe (열 파이프용 수평 축열조에서의 열 입력이 축열에 미치는 영향)

  • 최우석;박이동;김철주;황영규
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1995.05a
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    • pp.69-76
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    • 1995
  • The horizontal thermal storage tank with heat pipe which is suitable for the sensible heat storage system is able to store a hot water from the heat source such as heating pad efficiently and to supply a hot water to load rapidly. Therefore Arrangement of heating pad affects thermal flow and thermal storage efficiency. So, if effective arrangement is decided for condition of constant number of heating pad, the more rapid thermal flow effect and higher thermal storage efficiency is obtainable by active heat transfer. In this experiments, number of heating pad is ranged from three, five and nine, and when number of heating pad is constant, arrangement are two types of concentration-type and dispersion-type. As a result, for the case of concentration-type of heating pad, strong entrainment take place in horizontal thermal storage tank with heat pipe by active heat transfer and in the constant number of heating pad, the concentration-type has the higher efficiency with about 5∼6% than the dispersion-type. Therefore, when heating pad is equipted to horizontal thermal storage tank with heat pipe, concentration-type of heating pad is an efficient design in constant number. of heating pad.

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Synthesis and Characterization of Glold Nanofluid Prepared by the Solution Plasma Processing (용액 플라즈마 공정을 이용하여 제조된 금 나노유체의 특성평가)

  • Heo, Yong-Kang;Lee, Sang-Yul
    • Journal of Powder Materials
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    • v.17 no.4
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    • pp.342-346
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    • 2010
  • In the present work, water-based gold nanofluids were synthesized by the solution plasma processing (SPP). The size distribution and the shape of gold nanoparticles in the nanofluids were investigated using high resolution transmission electron microscopy (HR-TEM). The dispersion stability of gold nanofluids was characterized using zeta potential, as well. The thermal properties of gold nanofluids were measured by utilizing lambda measurement device. Nanofluids containing nanoparticles with $64.0{\pm}42.1\;nm{\sim}18.10{\pm}5.0\;nm$ in diameter were successfully synthesized. As diameter of nanoparticles decreased, dispersion stability of nanofluids increased and the enhanced ratio of thermal conductivity increased. The nanofluid with nanoparticles of $18.10\;{\pm}\;5.0\;nm$ in diameter showed approximately 3% improvement in thermal conductivity measurement and this could be due to the enhanced Brownian movement.