• Title/Summary/Keyword: thermal anisotropy

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The mechanical and thermodynamic properties of α-Na3(U0.84(2),Na0.16(2))O4: A combined first-principles calculations and quasi-harmonic Debye model study

  • Chen, Haichuan
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.611-617
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    • 2021
  • The mechanical properties of α-Na3(U0.84(2),Na0.16(2))O4 have been researched using the first-principles calculations combined with the quasi-harmonic Debye model. The obtained lattice parameters agree well with the published experimental data. The results of elastic constants indicate that α-Na3(U0.84(2),Na0.16(2))O4 is mechanically stable. The polycrystalline moduli are predicted. The results show that the α-Na3(U0.84(2),Na0.16(2))O4 exhibits brittleness and possesses obvious elastic anisotropy. The hardness shows that it can be considered a "soft material". Furthermore, the Debye temperature θD and the minimum thermal conductivity kmin are also discussed, respectively. Finally, the thermal expansion coefficient α, isobaric heat capacity CP and isochoric heat capacity CV are evaluated through the quasi-harmonic Debye model.

Analysis of the thermal instability of laminated composite plates

  • H. Mataich;A. El Amrani;B. El Amrani
    • Coupled systems mechanics
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    • v.13 no.2
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    • pp.95-113
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    • 2024
  • In this paper, we will analyse the thermo-elastic behavior of the plate element of a structure arranged in a climatically aggressive environment (extreme temperature), we use a refined four-variable thick plate theory to take the shear effect into consideration, the proposed theory less computationally expensive and more accurate so that it incorporates the shear effect into the formulation. The plate is assumed to be simply supported on its four edges, so exact (closed-form) solutions are found according to the Navier expansion, and the governing stability equations and associated boundary conditions of the problem are obtained via the virtual works principle. The plate studied ismade of laminated composite materials, so a parametric study is needed to see the effect of different types of parameters and coupling on the critical temperature value causing thermo-elastic instability of the plate and also on the natural frequency of free vibration, as well as for other parameters such as anisotropy, slenderness and aspect ratio of the plate and finally the lamination angle. Numerical results are obtained for specially orthotropic and antisymmetrical plates and are compared with those obtained by othertheoriesin the literature to validate the analysis approach used.

Synthesis of carbon nanosheets using RF thermal plasma (유도 열플라즈마를 이용한 카본나노시트 합성)

  • Lee, Seung-Yong;Ko, Sang-Min;Koo, Sang-Man;Hwang, Kwang-Taek;Han, Kyu-Sung;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.5
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    • pp.207-212
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    • 2014
  • An ultrathin sheet-like carbon nanostructure provides an important model of a two-dimensional graphite structure with strong anisotropy in physical properties. As an easy and cheap route for mass production, RF thermal plasma synthesis of freestanding carbon nanosheet from $CH_4$ (Methane) and $C_3H_8$ (Propane) is presented. Using vapor synthesis process with RF inductively thermal plasma, carbon nanosheets were obtained without catalysts and substrates. The synthesized carbon nanosheets were characterized using transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) analysis. The carbon nanosheets synthesized using methane and propane generally showed 5~6 and 15~16 layers with a wrinkled morphology and size of approximately 100 nm.

The effect of the system factors on the shape of the S/L interface in GaAs single crystal grown by VGF method (VGF법을 사용한 GaAs 단결정 성장시 계의 구성요소가 고액계면의 형상에 미치는 영향)

  • Seung-Ho Hahn;Hyung-Tae Chung;Young-Kyu Kim;Jong-Kyu Yoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.1
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    • pp.33-41
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    • 1994
  • It is well known that the position and the shape of the S/L interface affect the qualities of the single crystal in the growth process. Thus the information of the temperature profile in the growth system is very important. In this study, we developed the program to predict the temperature profile from the setting values of the heating blocks in VGF(vertical gradient freezing) single crystal growth system. With this program, we studied the effects of the materials and the sizes of support rod, the materials of the crucible on the S/L interface shape. The larger radius and/or smaller thermal diffusivity support rod was, the flatter the S/L interface was. When the thermal conductivity of crucible was isotropic, the S/L interface was more concave downward to the solid phase in proportional to the increase of thermal diffusivity of the crucible. By the comparison of the S/L interface shape between PBN crucible and quartz crucible for the same condition, the effect of anisotropy of thermal conductivity of crucible showed different trends with respect to the position of the S/L interface.

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Effects of UV Irradiation and Thermal Treatment of Photo-Degradable Polyimide Layer on LC Alignment (광분해성 고분자를 이용한 액정배향에서의 광조사 및 열처리 효과)

  • Lee, Jang-Ju;Lee, Won-Ho;Shin, Yong-Il;Paek, Sang-Hyon
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.145-148
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    • 2012
  • The effects of the linearly polarized UV (LPUV) irradiation and thermal treatment of a photo-degradable polyimide (CBDA-ODA) alignment layer (AL) on its AL properties, liquid crystal (LC) alignment, and LCD characteristics have been investigated. The best quality of LC photo-alignment have been induced by the LPUV-irradiation with much (about 5~10 times) less dosage than that generating the maximum anisotropy of the AL. A thermal treatment of the LPUV-irradiated AL has effectively removed the undesirable, low-M.W. fragments of the AL generated during the photo-decomposition and increased the stability of the AL, which has resulted in improvement of the LC alignment and the LCD property.

Electroactive Polymer Composites as a Tactile Sensor for Biomedical Applications

  • Kim GeunHyung
    • Macromolecular Research
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    • v.12 no.6
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    • pp.564-572
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    • 2004
  • Modem applications could benefit from multifunctional materials having anisotropic optical, electrical, thermal, or mechanical properties, especially when coupled with locally controlled distribution of the directional response. Such materials are difficult to engineer by conventional methods, but the electric field-aided technology presented herein is able to locally tailor electroactive composites. Applying an electric field to a polymer in its liquid state allows the orientation of chain- or fiber-like inclusions or phases from what was originally an isotropic material. Such composites can be formed from liquid solutions, melts, or mixtures of pre-polymers and cross-linking agents. Upon curing, a 'created composite' results; it consists of these 'pseudofibers' embedded in a matrix. One can also create oriented composites from embedded spheres, flakes, or fiber-like shapes in a liquid plastic. Orientation of the externally applied electric field defines the orientation of the field-aided self-assembled composites. The strength and duration of exposure of the electric field control the degree of anisotropy created. Results of electromechanical testing of these modified materials, which are relevant to sensing and actuation applications, are presented. The materials' micro/nanostructures were analyzed using microscopy and X-ray diffraction techniques.

A High-Resolution Heterodyne Interferometer using Beat Frequency between Two-Axial Modes of a HeNe Laser (2-종 모드 레이저를 이용한 고분해능 헤터로다인 간섭계)

  • 김민석;김승우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.214-219
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    • 1997
  • We propose a new scheme of high-resolution heterodyne interferometer that employs the two-axial mode He-Ne laser with an inter-mode beat frequency of 600-1000 MHz. An electronic RF-heterodyne circuit lowers the beat frequency down to 5 MHz, so that the phase change of the interferometer output is precisely measured with a displacement resolution of 0.1 nanometer without significant loss of dynamic bandwidth. A thermal control scheme is adopted to stabilize the cavity length with aims to suppress frequency drifts caused by the phenomena of frequency pulling and polarization anisotropy of the two-axial mode laser to a stability level of 2 parts in $10^9$. The two-axial mode HeNe laser yields a high output power of 2.0 mW, whlch allows us to perform multiple measurements of up to 10 machine axes simultaneously.

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Thermally Induced Vibration Analysis of Flexible Spacecraft Appendages (위성체 유연구조물의 진동 해석)

  • Yoon, Il-Soung;Kim, Gu-Sun;Song, Oh-Seop
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1216-1221
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    • 2000
  • Thermally induced vibration response of composite thin walled beams is investigated. The thin-walled beam model incorporates a number of nonclassical effects of transverse shear, primary and secondary warping, 'rotary inertia' and anisotropy of constituent materials. Thermally induced vibration response characteristics of a composite thin walled beam exhibiting the circumferentially uniform system(CUS) configuration are exploited in connection with the structural coupling resulting from directional properties of fiber reinforced composite materials and from ply stacking sequence. A coupled thermal structure analysis that includes the effects of structural deformations on heating and temperature gradient is investigated.

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The Damage Evaluation for the Application of Acoustic Emission in a Drilling Procedure of the CFRP Composite Materials (CFRP의 드릴작업시 AE적용에 의한 손상평가)

  • 최병국;윤유성
    • Journal of the Korean Society of Safety
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    • v.16 no.4
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    • pp.47-51
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    • 2001
  • The carbon fiber reinforced plastics(CFRP) have been widely used in aircraft and spacecraft structures as well as sports goods because it has high specific strength, high specific stiffness and low coefficient of thermal expansion. Machining of CFRP poses problems not frequently seen for metals due to the nonhomogeneity, anisotropy, and abrasive characteristics of CFRP. Delamination is a common problem faced while drilling holes in CFRP using conventional drilling. Therefore, AE characteristics related to drilling damage process of unidirectional and [0/90/]s crossply laminate composite was studied. Also drilling damage like the delamination was observed by video camera in real time monitoring technique. From the results, we basically found the relationships between the delamination from drilling and AE characteristics for CFRP composites.

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A study on cleaning process of RIE damaged silicon (반응성 이온 식각에 의해 손상된 실리콘의 세정에 관한 연구)

  • 이은구;이재갑;김재정
    • Electrical & Electronic Materials
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    • v.7 no.4
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    • pp.294-299
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    • 1994
  • CHF$_{3}$/CH$_{4}$Ar 플라즈마에 의해 형성된 산화막 식각 잔류물의 화학구조와 이 잔류물의 제거를 위한 세정방법을 x-ray photoelectron spectroscopy를 이용하여 조사하였다. 잔류무르이 구조는 CF$_{x}$-polymer와 Si-C, Si-O 결합으로 이루어진 SiO$_{y}$ C$_{z}$ 이었다. CF$_{4}$O$_{2}$ 플라즈마에 의한 silicon light etch는 산화막 식각 잔류물인 SiO$_{y}$ C$_{z}$ 층과 손상된 실리콘 표면을 제거하엿으며 NH$_{4}$OH-H$_{2}$O$_{2}$과 HF용액으로 완전히 제거되는 CF$_{x}$-polymer/SiO$_{x}$층을 남겼다. 100.angs.정도의 silicon light etch는 minority carrier life time과 thermal wave signal값을 초기 웨이퍼 수준까지 회복시켰으며 접합누설 전류도 거의 습식 식각 공정수준까지 감소시켰다.

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