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http://dx.doi.org/10.6111/JKCGCT.2014.24.5.207

Synthesis of carbon nanosheets using RF thermal plasma  

Lee, Seung-Yong (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Ko, Sang-Min (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Koo, Sang-Man (Department of Chemical Engineering, Hanyang University)
Hwang, Kwang-Taek (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Han, Kyu-Sung (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Kim, Jin-Ho (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
Abstract
An ultrathin sheet-like carbon nanostructure provides an important model of a two-dimensional graphite structure with strong anisotropy in physical properties. As an easy and cheap route for mass production, RF thermal plasma synthesis of freestanding carbon nanosheet from $CH_4$ (Methane) and $C_3H_8$ (Propane) is presented. Using vapor synthesis process with RF inductively thermal plasma, carbon nanosheets were obtained without catalysts and substrates. The synthesized carbon nanosheets were characterized using transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) analysis. The carbon nanosheets synthesized using methane and propane generally showed 5~6 and 15~16 layers with a wrinkled morphology and size of approximately 100 nm.
Keywords
Carbon nanosheet; RF thermal plasma; Vapor synthesis; Methane; Propane;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 A.C. Ferrari, "Ranman spectroscopy of graphene and graphite: disorder, electron-phonon coupling, doping and nonadiabatic effects", Solid State Commun. 143 (2007) 47.   DOI   ScienceOn
2 A. Peigney, Ch. Laurent, E. Flahaut, R.R. Bacsa and A. Rousset, "Specific surface area of carbon nanotubes and bundles of carbon nanotubes", Carbon 39 (2001) 507.   DOI   ScienceOn
3 G. Eda, G. Fanchini and C. Manish, "Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material", Nat. Nanotechnol. 3 (2008) 270.   DOI   ScienceOn
4 Z. Wei, D. Wang, S. Kim and S.Y. Kim, "Nanoscale tunable reduction of graphene oxide for graphene electronics", Science 328 (2010) 1373.   DOI   ScienceOn
5 D.A. Dikin, S. Stankovich and E.J. Zimney, "Preparation and characterization of graphene oxide paper", Nature 448 (2007) 457.   DOI   ScienceOn
6 H.G. Oh, H.G. Nam, D.H. Kim, M.H. Kim, K.H. Jhee and K.S. Song, "Neuroblastoma cells grown on fluorine or oxygen treated graphene sheets", Mater Lett. 131 (2014) 328.   DOI
7 K.X. Sheng, Y.X. XU, C. LI and G.Q. Shi, "High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide", Carbon 26 (2011) 9.
8 M.M. Hossain, O.K. Parkb and J.R. Hahn, "High yield and high concentration few-layer graphene sheets using solvent exfoliation of graphite with pre-thermal treatment in a sealed bath", Mater Lett. 123 (2014) 90.   DOI
9 K.S. Kim, Y. Zhao, H. Jang and S.Y. Lee, "Large-scale pattern growth of graphene films for dtretchable transparent electrodes", Nature 457 (2009) 706.   DOI   ScienceOn
10 L.R. Tong and R.G. Reddy, "Synthesis of titanium carbide nano-powders by thermal plasma", Scr. Mater. 52 (2005) 1253.   DOI   ScienceOn
11 B. Aktekin, G. Cakmak and T. Ozturk, "Induction thermal plasma synthesis of $Mg_2Ni$ nanoparticles", Int. J. Hydrogen Energy 39 (2014) 9859.   DOI
12 K.I. Kim, S.C. Choi and K.S. Han, "Synthesis of high purity aluminum nitride nanopowder by RF induction thermal plasma", J. Korean Cryst. Growth Cryst. Technol. 24 (2014) 1.   과학기술학회마을   DOI
13 A.B. Bourlinos, T.A. Steriotis, R. Zboril, V. Georgakilas and A. Stubos, "Direct synthesis of carbon nano sheets by the solid-state pyrolysis of betaine", Mater Sci. 44 (2009) 1407.   DOI
14 M.M. Hossain, J.R. Hahn and B.C. Ku, "Synthesis of highly dispersed and conductive raphene sheets by exfoliation of preheated graphite in a sealed bath and its applications to polyimide nanocomposites", Bull. Korean Chem. Soc. 35 (2014) 2049.   DOI
15 H.P. Klug and L.E. Alexander, "X-ray diffraction procedures for polycrystalline and morphous materials", 2nd ed. (Wiley, New York, 1974) p. 992.
16 J. Hackley, D. Ali, J. DiPasquale and J. Demaree, "Graphitic carbon growth on Si (111) using solid source molecular beam epitaxy", Appl. Phys. Lett. 95 (2009) 3.
17 C. Casiraghi, A. Hartschuh, H. Qian, S. Piscanec, C. Georgi, A. Fasoli, K.S. Novoselov, D.M. Basko and A.C. Ferrari, "Raman spectroscopy of graphene edges", Nano Lett. 9 (2009) 1441.
18 V. Singh and D. Joung, "Graphene based materials : past, present and future", Pro in Materials Sci. 56 (2011) 1178.   DOI   ScienceOn
19 N.G. Prikhodko, M. Auyelkhankyzy, B.T. Lesbayev and Z.A. Mansurov, "The effect of pressure on the synthe-sis of graphene layers in the flame", Materials Sci. and Chemical Eng. 2 (2014) 13.   DOI
20 R.J. Sereshta and M. Jahanshahi, "Synthesize and characterization of graphene nanosheets with high surface area and nano-porous structure", Appl. Surface Sci. 276 (2013) 672.   DOI   ScienceOn
21 J.L. White and P.M Sheaffer, "Pitch-based processing of carbon-carbon composites", Carbon 27 (1989) 697.   DOI
22 J. Kadla, S. Kubo, R. Venditti, R. Gilbert, A. Compere and W. Griffith, "Lignin-based carbon fibers for composite fiber applications", Carbon 40 (2002) 2913.   DOI   ScienceOn
23 V. Sridhar, J.H. Jeon and I.K. Oh, "Synthesis of graphene nano-sheets using eco-friendly chemicals and microwave radiation", Carbon 48 (2010) 2953.   DOI