• 제목/요약/키워드: thermal NO

검색결과 2,439건 처리시간 0.029초

직접 가열식 열탈착 공정을 이용한 유류오염토양의 정화 (Remediation of Petroleum-Contaminated Soil by a Directly-Heated Thermal Desorption Process)

  • 민형식;양인호;정상조;김한승
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제14권5호
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    • pp.62-70
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    • 2009
  • 본 연구에서는 lab-scale의 열탈착 장치를 설계 및 제작하고 실제 유류오염 토양을 대상으로 다양한 운전조건에 따른 오염토양정화성능을 비교하였다. 대상 토양은 군부대로 사용되던 부지 내 유류저장소 부근 고농도 오염토로 선정하였고, 10 L 용적의 원통형 batch 형태의 직접 가열식 열탈착기를 사용하여 초기 TPH 농도 4476 ppm의 고농도 오염 토양시료를 다양한 운전조건에서 열탈착하여 처리효율 분석을 수행하였다. 열중량 분석을 통해 열탈착 실험에서 대상 오염물질을 제거하기 위한 토양 시료의 평균 가열온도는 $200-300^{\circ}C$가 적합한 것으로 확인하였다. Batch 형식의 운전을 통한 처리효율 분석 결과 토양 내 오염물질을 90% 이상 제거하기 위해서는 약 $200^{\circ}C$에서는 10분, 약 $300^{\circ}C$에서는 5분 이상의 처리 시간이 요구되었다. 함수율이 높고 덩어리진 토양일수록 처리효율, 특히 고분자 오염물질의 처리효율이 크게 감소함을 보였다. 따라서 풍건을 통하여 오염토양 내 수분을 저하시킨 후 분쇄 처리하여 열탈착기에 주입하는 것이 효과적이라 판단된다. 또한 처리 전 토양과 처리 후 토양의 물리화학적 특성 비교한 결과 고온에 의해 증발된 수분함량을 제외하고 나머지 특성들은 거의 변화가 없어 실제 복원현장에서 오염토양을 열탈착 공정을 이용하여 오염물질을 제거한 후 추가적인 후처리 과정 없이 처리토양을 원래 위치에 복원하는 것이 가능함을 확인하였다. 본 연구결과는 현장운전에서 오염물질의 제거 효율을 극대화하기위한 인자 결정 및 검증을 위한 기초자료로 활용될 수 있을 것으로 사료된다.

산화제 입구 속도에 따른 0.2MW 순산소 연소기의 NO 배출 특성 (Effects of Oxidizer Inlet Velocity on NO Emission characteristics of 0.2MW Oxy-Fuel Combustor)

  • 김호근;이상민;안국영;김용모
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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    • pp.63-68
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    • 2006
  • Effects of oxidizer inlet velocity on NO emission characteristics of 0.2MW oxy-fuel combustor have been experimentally investigated. The NO formation process in the oxy-fuel combustion is extremely sensitive even for the small fraction of nitrogen in oxidizer. By increasing the oxidizer velocity, flame length is reduced due to the enhanced turbulent mixing. The increased oxidizer velocity also results in the decreased flame temperature through the elevated entrainment rate of the recirculated product and the corresponding NO emission is drastically decreased. Experimental results clearly indicate that the entrained product gases play a crucial role to decrease the temperature at the flame zone and the post flame zone where the thermal NO is mainly formed.

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Complete Freund Adjuvant에 의한 피부염증에서 통각과민현상의 기전 (Mechanism of Hyperalgesia Following Cutaneous Inflammation by Complete Freund Adjuvant)

  • 정용;임중우;정승수;김윤숙;윤덕미;남택상;백광세
    • The Korean Journal of Pain
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    • 제13권2호
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    • pp.164-174
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    • 2000
  • Background: After an injury to tissue such as the skin, hyperalgesia develops. Hyperalgesia is characterized by an increase in the magnitude of pain evoked by noxious stimuli. It has been postulated that in the mechanism of hyperalgesia (especially secondary hyperalgesia) and allodynia, a sensitization of central nervous system such as spinal dorsal horn may contribute to development of hyperalgesia. However, the precise mechanism is still unclear. In the present study, we investigated the roles of N-methyl-D-aspartate (NMDA) receptor and nitric oxide (NO) system in the mechanism of hyperalgesia, and their relations with c-fos expression Methods: Inflammation was induced by injection of complete Freund adjuvant (CFA) into unilateral hindpaw of Sprague-Dawley rat. Behavioral studies measuring paw withdrawal responses by von Frey filaments and paw withdrawal latencies by radiant heat stimuli and stainings of nicotinamide adenine dinucleotide phosphate (NADPH)-diaphorase and c-fos immunoreactivity were performed. The effects of MK-801, an NMDA receptor blocker and $N^\omega$-nitro-L-arginine (L-NNA), a nitric oxide synthase (NOS) inhibitor were evaluated. Results: 1) Injection of CFA induced mechanical allodynia, mechanical hyperalgesia and thermal hyperalgesia. And it increased the number of NADPH-diaphorase positive neurons and c-fos expression neurons. 2) MK-801 inhibited mechanical hyperalgesia and thermal hyperalgesia induced by CFA and reduced the number of NADPH-diaphorase positive neurons and c-fos expression neurons. 3) L-NNA inhibited the thermal hyperalgesia and reduced the number of NADPH-diaphorase positive neurons, but did not affect the number of c-fos expression neurons. Conclusions: These results suggest that in the mechanism of mechanical hyperalgesia, NMDA receptor but not NO-system is involved and in the case of thermal hyperalgesia both NMDA receptor and NO system are involved. NO system did not affect the expression of c-fos, but c-fos expression and NOS activity were dependent on the activity of NMDA receptor.

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Synthesis of Silver Nanocrystallites by a New Thermal Decomposition Method and Their Characterization

  • Lee, Don-Keun;Kang, Young-Soo
    • ETRI Journal
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    • 제26권3호
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    • pp.252-256
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    • 2004
  • We formed silver nanocrystallites by the thermal decomposition of a $Ag^{+1}$-oleate complex, which was prepared by a reaction with $AgNO_{3}$ and sodium oleate in a water solution. The resulting monodispersed silver nanocrystallites were produced by controlling the temperature (290$^{\circ}$C). Transmission electron microscopic (TEM) images of the particles showed a 2-dimensional assembly of the particles with a diameter of $9.5{\pm}0.7nm$, demonstrating the uniformity of these nanocrystallites. An energy-dispersive X-ray (EDX) spectrum and X-ray diffraction (XRD) peaks of the nanocrystallites showed the highly crystalline nature of the silver structure. We analyzed the decomposition of the $Ag^{+1}$-oleate complex using a Thermo Gravimetric Analyzer (TGA) and observed the crystallization process using XRD.

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Analysis of a Geometrically Asymmetric Trapezoidal Fin with Variable Fin Base Thickness and Height

  • Kang, Hyung-Suk
    • International Journal of Air-Conditioning and Refrigeration
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    • 제16권3호
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    • pp.83-88
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    • 2008
  • A geometrically asymmetric trapezoidal fin is analyzed using the one-dimensional analytic method. Heat loss and thermal resistance are represented as a function of the fin base thickness, base height, fm shape factor, inside fluid convection characteristic number, convection characteristic numbers ratio, fm length and ambient convection characteristic number. The relationship between the fin base height and the shape factor for equal amounts of heat loss is presented. One of the results shows that the variations of the fm base thickness and the inside fluid convection characteristic number give no effect on the thermal resistance.

다목적 그린하우스의 동절기 실내온열환경 특성에 관한 실측 연구 (A Study on the Thermal Environment in the Multipurpose Greenhouse in Winter)

  • 김순주;나수연
    • 한국태양에너지학회 논문집
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    • 제27권3호
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    • pp.15-21
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    • 2007
  • The purpose of this study is to provide the basic data for passive control and energy conservation strategies of multipurpose greenhouse. Passive design strategies which are appropriate to Jeju environmental circumstance were applied in the multipurpose greenhouse. The field measurement were conducted to examine relationship of micro climate and indoor thermal environment in the multipurpose greenhouse. The result of this study can be summarized as follow ; (1) The indoor temperature was ranged from 5 to $21^{\circ}C$ without a heating system, when the exterior temperature was -1 to $19^{\circ}C$. (2) The multi-purpose greenhouse requires almost no heating energy in winter, when it is used as a greenhouse, an exhibition hall or a cafeteria.

온도 성층축열조 가시화 및 실증분석에 관한 고찰 (Effect on Stratification due to Diffuser Shape in a Thermal Storage Tank)

  • 이영수;이상남;김종률
    • 설비공학논문집
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    • 제17권11호
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    • pp.990-997
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    • 2005
  • The stratified effect was investigated with three different types of diffuser shape in a thermal storage tank with variation of diffuser diameter, velocity, Froude number etc. Its effect was estimated by the degree of stratification. No matter of diffuser diameter and shape, the degree of stratification was the best as the Froude number gets closer to 1. In the case of a curved diffuser, when its diameter is a quarter of tank diameter and ejection velocity in a diffuser is approximately 0.2 m/s, the Froude number was almost 1. In the case of a flatted diffuser, when ejection velocity was 0.05 m/s, the Froude number was 1.5. Both cases which Froude number were nearer 1, showed the good degree of stratification.

RESULTS OF THERMAL CREEP TEST ON HIGHLY IRRADIATED ZIRLO

  • Quecedo, M.;Lloret, M.;Conde, J.M.;Alejano, C.;Gago, J.A.;Fernandez, F.J.
    • Nuclear Engineering and Technology
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    • 제41권2호
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    • pp.179-186
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    • 2009
  • This paper presents a thermal creep test under internal pressure and post-test characterization performed on high burnup (68 MWd/kgU) ZIRLO. This research has been done by the CSN, ENRESA, and ENUSA in order to investigate the behavior of advanced cladding materials in contemporary PWRs at higher burnup under dry cask storage conditions. Also, to investigate the hydride reorientation, the cool-down of the samples after the test has been done in a coordinated manner with the internal pressure. The creep results obtained are consistent with the expected behavior from reference CWSR material, Zr-4. During the test, the material retained significant ductility: one specimen leaked during the test at an engineering strain of the tube section of 17%; remarkably, the crack closed due to de-pressurization. Although significant hydride reorientation occurred during the cool-down under pressure, no specimen failed during the cool-down.

Wave propagation in a generalized thermo elastic plate embedded in elastic medium

  • Ponnusamy, P.;Selvamani, R.
    • Interaction and multiscale mechanics
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    • 제5권1호
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    • pp.13-26
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    • 2012
  • In this paper, the wave propagation in a generalized thermo elastic plate embedded in an elastic medium (Winkler model) is studied based on the Lord-Schulman (LS) and Green-Lindsay (GL) generalized two dimensional theory of thermo elasticity. Two displacement potential functions are introduced to uncouple the equations of motion. The frequency equations that include the interaction between the plate and foundation are obtained by the traction free boundary conditions using the Bessel function solutions. The numerical calculations are carried out for the material Zinc and the computed non-dimensional frequency and attenuation coefficient are plotted as the dispersion curves for the plate with thermally insulated and isothermal boundaries. The wave characteristics are found to be more stable and realistic in the presence of thermal relaxation times and the foundation parameter. A comparison of the results for the case with no thermal effects shows well agreement with those by the membrane theory.

멤브레인형 LNGC의 열계산에 기초한 안전운항기술에 관한 연구 (A Study on the Safe Maneuvering Technology Based on the Thermal Calculation of Membrane Type LNG Carrier)

  • 김창복;김경근;오철
    • Journal of Advanced Marine Engineering and Technology
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    • 제32권8호
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    • pp.1192-1200
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    • 2008
  • This paper is concerned with the thermal design of the $138,000m^3$ class membrane type LNGC. To predict the temperature distribution, BOG and BOR, 3-dimensional numerical calculation was carried-out for the quarter of No.3 LNG tank. These sequence analyses were performed under the standard conditions of IMO ship design condition, USCG ship design condition and the Korean flag LNGC's route condition according to the 6-voyage modes. As the results, temperature behavior, heat flux, total penetrating heat, BOG and BOR were obtained, and those were compared with the maneuvering results considering the real temperature variation of air and sea water temperature at noon time. For securing the safety of LNGC during the ballast voyage, optimum control patterns of pressure and temperature in LNG tank is suggested in this paper.