• 제목/요약/키워드: thermal NO

검색결과 2,439건 처리시간 0.027초

전기방사법과 이원화 열처리 공정을 통한 은 나노섬유의 합성 및 투명전극으로의 응용 (Synthesis of Silver Nanofibers Via an Electrospinning Process and Two-Step Sequential Thermal Treatment and Their Application to Transparent Conductive Electrodes)

  • 이영인;좌용호
    • 한국재료학회지
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    • 제22권10호
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    • pp.562-568
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    • 2012
  • Metal nanowires can be coated on various substrates to create transparent conducting films that can potentially replace the dominant transparent conductor, indium tin oxide, in displays, solar cells, organic light-emitting diodes, and electrochromic windows. One issue with these metal nanowire based transparent conductive films is that the resistance between the nanowires is still high because of their low aspect ratio. Here, we demonstrate high-performance transparent conductive films with silver nanofiber networks synthesized by a low-cost and scalable electrospinning process followed by two-step sequential thermal treatments. First, the PVP/$AgNO_3$ precursor nanofibers, which have an average diameter of 208 nm and are several thousands of micrometers in length, were synthesized by the electrospinning process. The thermal behavior and the phase and morphology evolution in the thermal treatment processes were systematically investigated to determine the thermal treatment atmosphere and temperature. PVP/$AgNO_3$ nanofibers were transformed stepwise into PVP/Ag and Ag nanofibers by two-step sequential thermal treatments (i.e., $150^{\circ}C$ in $H_2$ for 0.5 h and $300^{\circ}C$ in Ar for 3 h); however, the fibrous shape was perfectly maintained. The silver nanofibers have ultrahigh aspect ratios of up to 10000 and a small average diameter of 142 nm; they also have fused crossing points with ultra-low junction resistances, which result in high transmittance at low sheet resistance.

노멕스 허니콤 구조 직물을 적용한 소방관용 특수방화복 개발 및 이의 보호 쾌적 성능평가 (Development of Firefighters' Personal Protective Clothing with Nomex Honeycomb Fabric and its Protective and Comfort Evaluation)

  • 정재연;구본준;김도형;권민재;강성욱;최정윤;이주영
    • 한국의류산업학회지
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    • 제21권5호
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    • pp.606-617
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    • 2019
  • The present study newly developed a firefighters' protective jacket and pants using a Nomex honeycomb structured layer (HPC) in cases of being exposed to flashover or flameover. This study evaluated the protective and comfort functions of an HPC compared to the current KFI firefighters' protective clothing (FPC). The results are as follows. First, thermal protective performance (TPP) of fabric layers was 2.75 times greater for HPC than FPC at $125kW/m^2$. Second, the predicted second and third degree burn areas were smaller for HPC than FPC when using a flame manikin. Third, thermal insulation using a thermal manikin was 0.2 clo greater for HPC than FPC. Fourth, there were no marked differences in maximal performance, mobility, and microclimate temperature/humidity between FPC and HPC through human wear trials. The thermal insulation of HPC was higher than that of FPC; however, any negative effect of HPC thermal insulation on the comfort functions for firefighters was not found. In conclusion, the newly-developed HPC provided more protection in reducing burn injuries from $125kW/m^2$, while no negative impact on maximal performance, mobility and thermal comfort functions of firefighters, which is appropriate for quick-evasive tactics at the flashover, flameover or back draft fires.

Horizontal Firing Boiler의 열유동 해석 (Numerical Analysis on Flow and Heat Transfer of Horizontal Firing Boiler)

  • 김광추;박만흥;김종길;최청렬;강대웅;김창녕
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.973-978
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    • 2001
  • Numerical Analysis for liquid fuel combustion of horizontal firing boiler is performed. The mixture-fraction/PDF equilibrium chemistry model is used to predict the combustion of the vaporized fuel. P1 model for radiation effect is used. Superheater, reheater and economizer is modeled using porous with heat sink. Flow and temperature field is investigated, and distribution of thermal $NO_{x}$ and CO is investigated. Computation as the change of excess air and swirling is performed to investigate the change of thermal $NO_{x}$.

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영상처리 기술을 이용한 연소상태 진단 (Flame Diagnosis using Image Processing Technique)

  • 이태영;김성환;이상룡
    • 한국정밀공학회지
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    • 제16권7호
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    • pp.196-202
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    • 1999
  • Recent trend changes a criterion for evaluation of burner that environmental problem is raised as global issue. For efficient driving problem, the higher thermal efficiency and the lower oxygen in exhaust gas, burner is evaluated the better. For environmental problem, burner must satisfy $NO_{X}$ limit and CO limit. Consequently, 'good burner' means on whose thermal efficiency is high under the constraint of $NO_{X}$ and CO consistency. To make existing burner satisfy recent criterion, it is highly recommended to develop feedback control scheme whose output is the consistency of $NO_{X}$ and CO. This paper describes development of real time flame diagnosis technique that evaluate and diagnose combustion state such as consistency of components in exhaust gas, stability of flame in quantitative sense. This study focuses on wave length of luminescence from chemical reaction measurement of the luminescence via optical measuring apparatus and derive correlation with consistency of components in exhaust gas by image processing technique.

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$CH_{4}$ 제트 화염의 NOx 배출 특성에 관한 수치 및 실험적 연구 (Numerical and Experimental Investigation on NOx Emission Characteristics of $CH_4$ Jet Flame)

  • 박정배;김종현;이창언
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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    • pp.67-76
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    • 2000
  • Experimental and numerical investigation on NOx emission characteristics with equivalence ratios, fuel flow rates and nozzle diameters were studied in CH4 Jet flames. Emission indices of NOx were measured by chemiluminescent method with carbon converter. Numerical analyses were carried out with GRl-2.11 mechanism that includes C2-chemistry and all of NO reaction mechanisims. The roles of thermal NO and prompt NO mechanism on each flame's NOx emission index were investigated. The results of this study show that the numerical results represent well the trends of ElNOx experimentally observed. The numerical analyses clarified the trends of EINOx with equivalence ratios, fuel flow rates and nozzle diameters.

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열교환기 관사이의 거리변화에 대한 열효율 특성 (Characteristics of Thermal Efficiency with Changing Distances Between Tubes for Heat Exchanger)

  • 김종민;이재박;이승로;이창언;금성민
    • 에너지공학
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    • 제19권3호
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    • pp.177-181
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    • 2010
  • 열교환기는 용도에 따라 여러가지 형태가 존재하지만 중요한 것은 열교환기의 성능을 향상시킴으로서 열교환기의 크기를 소형화하는 것이라 할 수 있다. 그러나 보일러처럼 열교환기가 버너 앞에 위치할 경우 열교환기의 효율도 중요하지만 환경오염물질의 배출특성도 고려되어야 한다. 따라서 본 연구에서는 비예혼합화염보다 화염길이가 짧고 당량비 조절을 통해 $NO_x$ 및 CO 배출을 제어할 수 있는 예혼합방식의 버너 앞에 원형관 열교환기를 설치한 후 열교환기 관사이의 거리 및 당량비를 변화시킬 때 $NO_x$와 CO의 배출특성과 열교환기의 열효율을 실험적으로 구하였다.

고강도 저열팽창 인바합금에 있어서 CO 첨가의 영향 (Effects of Co Addition in High Strength and Low Thermal Expansion Invar Alloy)

  • 김봉서;조영암;유경재;권해웅;이희웅;김병걸
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1901-1903
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    • 1999
  • To investigate invar alloy as a core material for increased capacity over-head transmission line which have high strength and low thermal expansion coefficient, hardness and thermal expansion coefficient of Fe-Ni-Co alloy have been studied. It is necessary that invar alloy have low thermal expansion coefficient and high strength for increased capacity over-head transmission line. In this paper. we tried to find out the effect of Ni and Co which has ferromagnetic properties and high saturation magnetization. It was found that Ni decrease thermal expansion coefficient and hardness, Co decrease thermal expansion coefficient but increase hardness in Fe-xNi-Co system. In Fe-(29-x)Ni-Co system, the material has no low thermal expansion properties substituting Co instead of Ni in concentration range of $1\sim7$%Co.

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주강계 저열팽창 주조합금의 열팽창 계수와 경도에 미치는 Mo, V 첨가의 영향 (Effects of Mo, V addition on Linear Thermal Expansion Coefficient and Hardness of Low Thermal Expansion Cast Steel)

  • 김영한;윤의박;문병문;홍영명
    • 한국주조공학회지
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    • 제18권5호
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    • pp.467-473
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    • 1998
  • For enhancing the mechanical properties of LTE (low thermal expansion) cast steel, systematic researches have been carried out. The effects of alloying elements such as vanadium, molybdenum and carbon on the hardness and linear thermal expansion coefficient were investigated. In the range of $0.5{\sim}2.3\;wt%$ carbon, addition of 1.73 wt% carbon caused hardness increase due to the formation of eutectic carbide having high hardness but over the range of 1.73 wt% carbon, hardness was decreased. Thermal expansion coefficient increases with carbon contents. In the LTE cast steel containing 0.6 wt% carbon, hardness increased up to 1.96 wt% vanadium addition. But over the range of 1.96 wt% vanadium hardness was decreased by coarse eutectic carbide. Thermal expansion coefficient of LTE cast steel containing 0.6 wt%carbon moderately increased with increasing vanadium contents. There was no significant variation of hardness and thermal expansion coefficient according to molybdenum content in LTE cast steel.

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광섬유를 이용한 레이저섬광의 균일분포 증진효과에 따른 열확산계수 측정에 관한 고찰 (A Study on Thermal Diffusivity Measurement by Improvement of Laser Flash Uniformity Using an Optical Fiber)

  • 이원식;배신철
    • 대한기계학회논문집B
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    • 제22권8호
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    • pp.1073-1082
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    • 1998
  • When thermal diffusivity is measured by laser flash method, the thermal diffusivity call be calculated front the assumption of the uniformly heated whole surface of the specimen. It has been known that the approximate 5% error is made by the non-uniform energy distribution on the specimen surface of laser pulse heat source. In this study, to obtain the highly-uniformed laser beam, which has both the low non-uniform heating error from non-uniform laser beam and the energy loss, research was carried out on no transmitting loss by optical fiber and high repetitions. In addition, heating error and thermal diffusivity were measured as the measuring positions were varied and compared with the results using the uniform and the non-uniform laser beams. In addition, dole to using the uniformalized laser beam, the whole surface of the specimen was heated uniformly and as a result, it was the thought that this was very effective to reduce the variations of the errors of the thermal diffusivity as the measuring positions were varied. It can be obtained that when the thermal diffusivity of POCO-AXM-5Q1 of SRM in NBS was measured with both the uniform and the non-uniform laser beams, the dispersion error of the former was from 2 to 2.5%, which was more improved than that of the latter.

적외선 램프를 이용하여 소결한 구리 나노잉크의 전기적 특성 평가에 관한 연구 (Electrical Property Evaluation of Printed Copper Nano-Ink Annealed with Infrared-Lamp Rapid Thermal Process)

  • 한현숙;김창규;양승진;김윤현
    • 한국재료학회지
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    • 제26권4호
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    • pp.216-221
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    • 2016
  • A sintering process for copper based films using a rapid thermal process with infrared lamps is proposed to improve the electrical properties. Compared with films produced by conventional thermal sintering, the microstructure of the copper based films contained fewer internal and interfacial pores and larger grains after the rapid thermal process. This high-density microstructure is due to the high heating rate, which causes the abrupt decomposition of the organic shell at higher temperatures than is the case for the low heating rate; the high heating rate also induces densification of the copper based films. In order to confirm the effect of the rapid thermal process on copper nanoink, copper based films were prepared under varying of conditions such as the sintering temperature, time, and heating rate. As a result, the resistivity of the copper based films showed no significant changes at high temperature ($300^{\circ}C$) according to the sintering conditions. On the other hand, at low temperatures, the resistivity of the copper based films depended on the heating rate of the rapid thermal process.