• Title/Summary/Keyword: thermal $T_g$

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Preparation of Graphene Based PdOx and CuOx/MnOx Nanocomposites and Their Catalytic Applications in C-C Coupling and CH3SH Decomposition Reactions

  • Lee, Gyeong-Hun;Park, Jun-Beom
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.175.2-175.2
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    • 2014
  • Graphene (G) has been modified with palladium, copper, and manganese oxide nanoparticles (NPs), and their catalytic applications have been studied in C-C coupling reactions and methylmercaptan (CH3SH) decomposition reactions. In this research, graphite oxide (GO) sheets were exfoliated and oxidized from graphite powder and impregnated with metal precursors including Pd2+, Cu2+, and Mn2+. The thermal treatments of the metal impregnated GO in preferred gas environments produced Pd NPs on graphene (Pd/G), PdO NPs on GO (PdO/GO), and CuOx and MnOx NPs on graphene (CuOx/MnOx/G). In case of Pd/G and PdO/GO, the TEM images show that, although the mean size of the Pd NPs changed significantly before and after the C-C coupling reaction, that of the PdO NPs didn't, implying that the PdO/GO was superior to Pd/G in terms of the recyclability. Also, we demonstrate that the CuOx/MnOx/G exerts the excellent catalytic efficiency in CH3SH decomposition reaction comparing with conventional catalysts. The chemical and electronic structural changes were investigated using XRD and XPS.

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Growth kinetics and pattern formation of ice dendrites at small subcoolings (작은 과냉각 상태에서 ice dendrite의 결정 성장 특성)

  • 구기갑
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.197-208
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    • 1995
  • An experiment study of the dendrite growth of ice crystals growing in quiescent pure subcooled water was made at small subcoolings of 0.035 K < ${\Delta}T$ < 1.000 K. It was observed that the growth kinetics and morphology are functions of not only subcooling but also thermal convection. When the subcooling is less than 0.35K, it was found that effect of thermal convection on growth kinetics of ice dendrites becomes important. Quantitiative measurements of growth velocity, $V_{G}$, and tip radii of the edge and basal planes, $R_{1}$ and $R_{2}$, were made simultaneously as a function of subcooling.

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Survival and Thermal Inactivation of Coliform Bacteria after the Heat Treatment at 143°F (유우원(乳牛源) 대장균군세균(大腸菌群細菌)의 치사열(致死熱)에 관한 연구)

  • Chung, G.T.;Han, H.R.
    • Korean Journal of Veterinary Research
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    • v.11 no.2
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    • pp.137-140
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    • 1971
  • Survival and thermal inactivation after heat treatment at $143^{\circ}F$ were observed among 27 strains of coliform bacteria isolated from dairy cattle. The results obtained were as follows. 1. The obvious differences in heat-sensitivity were observed among the strains tested. 2. No strain was found resistant to the heat treatment of $143^{\circ}F$ for 30 minutes. 3. A marked effect of density of coliform bacteria on the survival after the heat treatment was observed. As the density of coliform bacteria was increased, the rate of survival was increased markedly regardless of the length of heat treatment.

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Thermal annealing for long-term stability of polymer light-emitting devices

  • Kim, Jin-Ook;Park, Jong-Hyn;Lee, Jae-Yoon;Lee, N.Y.;Chung, In-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.153-156
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    • 2003
  • Thermal annealing of a polymer light-emitting diode (PLED) is shown to result in a remarkable improvement in the long-term stability of the device. The best half-life is obtained at an annealing temperature above the $T_g$ of emitting polymer. It is shown that the annealing of the emitting polymer layer results in a more than an order of magnitude increase in the half-life in spite of a decrease in the efficiency of the device as the annealing temperature increases.$^1$

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A Study on the Thermal Circuit of Underground Tunnel Installed Power Cables (전력구 부설에 대한 지중 전력 케이블의 허용전류 계산 열 회로에 관한 연구)

  • Jeong, S.H.;Kim, D.K.;Choi, S.B.;Bae, J.H.;Ha, T.H.;Lee, H.G.;Gwag, B.M.;Yoon, H.H.;Kang, J.W.
    • Proceedings of the KIEE Conference
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    • 2000.11a
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    • pp.159-161
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    • 2000
  • This paper examines the thermal circuit of underground tunnels installed power cables. It can be appreciated to understand the mechanism of heat transfer and to calculate the current carrying capacity of power cables in tunnel.

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증기조건 향상에 따른 증기터빈 기술동향

  • Na, Un-Hak
    • 열병합발전
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    • s.36
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    • pp.16-21
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    • 2003
  • For many years, T/G Supplier has constructed a number of thermal power plants and researched to improve the performance and the reliability of steam turbine, which are achieved by advances in design and materials technology. In recent, interest is renewed in advance steam condition as means of improving economy of thermal power plant and reducing environmental pollution. Improvements in the maximum power have been driven by the development of advanced rotor and bucket material and longer last stage bucket. Improvements in efficiency have been brought through advance in mechanical efficiency and thermodynamic efficiency. This paper describes a number of new steam path design features introduced to the steam turbine product. And also this paper describes new design technologies' development, new technologies' trend and technologies' development for ultra-super critical steam turbine.

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Steam Turbine Technology for Advanced Steam Condition (증기조건 향상에 따른 증기터빈 기술 동향)

  • Nah, U.H.;Cho, S.I.;Shin, H.;Kim, Y.S.;Yang, S.H.
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.2174-2179
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    • 2003
  • For many years, T/G Supplier has constructed a number of thermal power plants and researched to improve the performance and the reliability of steam turbine, which are achieved by advances in design and materials technology. In recent, interest is renewed in advanced steam condition as means of improving economy of thermal power plant and reducing environmental pollution. Improvements in the maximum power have been driven by the development of advanced rotor and bucket material and longer last stage bucket. Improvements in efficiency have been brought through advances in mechanical efficiency and thermodynamic efficiency. This paper describes a number of new steam path design features introduced to the steam turbine product. And also this paper describes new design technologies' development, new technologies' trend and technologies' development for ultra-super critical steam turbine.

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Fouling Analyses of Heat Exchangers for PSR (주기적안전성평가를 위한 원전 열교환기 Fouling 평가)

  • Hwang, K.M.;Jin, T.E.;Han, S.G.;Kim, B.S.
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1467-1472
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    • 2003
  • Fouling of heat exchangers is generated by water-borne deposits, commonly known as foulants including particulate matter from the air, migrated corrosion produces; silt, clays, and sand suspended in water; organic contaminants; and boron based deposits in plants. This fouling is known to interfere with normal flow characteristics and reduce thermal efficiencies of heat exchangers. This paper focuses on fouling analyses for six heat exchangers of two primary systems in two nuclear power plants; the regenerative heat exchangers of the chemical and volume control system and the component cooling water heat exchangers of the component cooling water system. To analyze the fouling for heat exchangers, fouling factor was introduced based on the ASME O&M codes and TEMA standards. Based on the results of the fouling analyses, the present thermal performances and fouling levels for the six heat exchangers were predicted.

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Fabrication and application of high-aspect-ratio microchannels using laser-induced etching (레이저유도 에칭을 이용한 고세장비 마이크로채널 가공 및 응용)

  • Oh Kwang-H.;Lee M.K.;Kim S.G.;Lim H.T.;Jeong S.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.659-660
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    • 2006
  • High-aspect-ratio(max. 12.5) microchannels with excellent surface quality and good shape uniformity have been realized utilizing laser-induced etching technique. Etch width and depth variations depend largely upon process variables such as laser power and etchant concentration. Etchant concentration in association with viscosity also influence on the cross-sectional profile of the channels. The optimum process conditions for the fabrication of high-aspect-ratio microchannels applicable to micro thermal devices are demonstrated.

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Correlation between leakage current and temperature Rise for artificially aged insulators (인위적 열화 애자에 대한 누설전류와 온도와의 관계)

  • Kim, J.T.;Kim, J.H.;Koo, J.Y.;Yoon, J.H.;Ham, G.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.186-188
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    • 2001
  • In this study, the correlation between leakage currents and temperature rise was investigated for the more accurate diagnosis of bad insulator by use of the infrared camera. For the purpose, leakage currents and thermal images were measured for the artificially aged insulators using salt fog. From the results, it is concluded as follows ; in case of artificially aged insulators, the leakage. current was decreased with the duration of voltage application and was largely affected by humidity, which seems due to ionic conduction. Also, the correlation between temperature rise and leakage current was appeared to be quite linear, although it showed below linearity at large leakage current.

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