• Title/Summary/Keyword: thermal $T_g$

Search Result 478, Processing Time 0.024 seconds

Effect of Transition Metal on the Thermal Stability and Mechanical Property of Fe-based Amorphous Alloys (Fe기 비정질합금의 열적안정성 및 기계적 성질에 미치는 천이금속의 영향)

  • Gook, Jin Seon;Yoon, Dong Joo
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.14 no.6
    • /
    • pp.345-349
    • /
    • 2001
  • This study has investigated the effect of thermal stability and mechanical property of $Fe_{80-X}P_{10}C_6B_4M_X$(X=2, 4, 6, M=transition metal) amorphous alloys fabricated by the melt-spun process. The glass transition temperature($T_g$), crystallization temperature($T_x$) and hardness increase with decreasing electron concentration (e/a) from about 7.38 to 7.18. The decrease of e/a implies the increase in the attractive bonding state between the M elements and other constituent element. The decrease in a/e leads to the enhancement of the attractive bonding state among the constituent elements which is favorable for the increase in $T_g$, $T_x$ and hardness.

  • PDF

Synthesis and Properties of Novel T-type Nonlinear Optical Polyurethane Containing Tricyanovinylthienyl Group with Enhanced Thermal Stability of Dipole Alignment

  • Cho, You-Jin;Kim, Mi-Sung;Lee, Ju-Yeon
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.2
    • /
    • pp.424-430
    • /
    • 2011
  • A novel T-type polyurethane 7 containing 1-(2,5-dioxyphenyl)-2-(5-(1,2,2-tricyanovinyl)-2-thienyl)ethenes as NLO chromophores, which constitute part of the polymer backbone, was prepared. Polyurethane 7 is soluble in common organic solvents such as DMF and DMSO. It shows a thermal stability up to $270^{\circ}C$ from TGA thermogram with $T_g$ value obtained from DSC thermogram near $155^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer film at 1560 nm fundamental wavelength is $3.56{\times}10^{-9}$ esu. Polymer 7 exhibits a thermal stability even at $5^{\circ}C$ higher than $T_g$, and no significant SHG decay is observed below $160^{\circ}C$, which is acceptable for nonlinear optical device applications.

A Study on the Thermal Properties of Epoxy/Micro-Nano Alumina Composites, as Mixture of Surface Modified Nano Alumina (표면개질된 나노알루미나를 혼합한, 에폭시/마이크로-나노알루미나 콤포지트의 열적특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.65 no.9
    • /
    • pp.1504-1510
    • /
    • 2016
  • The aim of this study is to improve properties both glass transition temperature($T_g$) and coefficient of thermal expansion(CTE) using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40, 50, 60wt%)+surface modified nano alumina(1_phr) composites. 20 kinds specimen were prepared with containing micro, nano alumina and GDE as a micro composites(10, 20, 30, 40, 50, 60, 70wt%) or a nano/micro alumina composites(1phr/40, 50, 60wt%). Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The glass transition temperature and coefficients of thermal expansion was evaluated by DSC and TMA. The glass transition temperature decreased and coefficients of thermal expansion become smaller with filled contents of epoxy/micro alumina composites. On the other hand, $T_g$ and CTE as GDE addition variation(1,2,3,5g) of epoxy/micro-nano alumina composites decreased and increased respectively.

A Quantitative Model for Estimating Fishery Production Damages as a Result of Thermal Effluents from Nuclear Power Plants (원자력발전소의 온배수 배출량을 고려한 어업생산감소율 추정 모델)

  • Zhang, Chang-Ik;Lee, Sung-Il;Lee, Jong-Hee
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.42 no.5
    • /
    • pp.494-502
    • /
    • 2009
  • A quantitative model was developed in order to estimate fishery production damage due to anthropogenically induced environmental changes. The model is described in the following equation, $Y_D=\frac{{\phi}_D}{{\phi}_G}[Y_0{\cdot}(t_p-t_0)-\frac{Y_0}{{\phi}_G}(1-e^{-{\phi}_G(t_p-t_0)})]$, where, $Y_D$ is annual amount of fishery production by nuclear power plant. ${\varphi}$ D and ${\varphi}$ G are instantaneous decreasing coefficient of fishery production by nuclear power plant and instantaneous decreasing coefficient of gross fishery production, respectively. $Y_0$ is annual mean fishery production without damages. $t_p$ is the present time, and $t_0$ is the starting time of damages. The model was applied to fishing grounds near a nuclear power plant on the east coast of Korea. Since fishery production damages have become bigger with increasing emission of thermal effluents from generators activities in the power plant, this factor has also been considered as, $\delta_{D_i}=\delta_D\({\sum}\limits_{i=0}^{n}\;W_i/W_T\)$, where, $\delta_{Di}$ is the cumulative damage rate in fishery production from generators, $\delta_D$ is the total cumulative damage rate in fishery production, $W_i$ is the emission amount of thermal effluents by generator i, and n is the number of generators in the nuclear power plant. This model can be used to conduct initial estimates of fishery production damages, before more detailed assessments are undertaken.

Degradation Assessment of Thermoplastic Synthetic Resin Using Propagation Characteristics of Ultrasound (초음파 전파특성을 이용한 열가소성 합성수지의 열화 평가)

  • Jeon, Woo-Sang;Kim, Gi-Jin;Kwon, Sung-Duk
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.34 no.2
    • /
    • pp.141-147
    • /
    • 2014
  • A nondestructive ultrasonic technique was applied to evaluate the thermal characteristics and degradation of synthetic polymer resin (plastics) with better cost-effectiveness and functionality than glass and metal. Thermoplastic and transparent acrylic resin (PMMA) specimens were annealed at below the glass transition temperature ($T_g$), and the propagation characteristics (attenuation and velocity) were measured. The attenuation increased and the velocity decreased with thermal degradation. The results showed that the thermal aging of the specimens could be evaluated quantitatively and that the Tg could be evaluated qualitatively.

A Study on Curing of Poly(phenylene sulfide sulfone) (Poly(phenylene sulfide sulfone)의 경화에 관한 연구)

  • Seo, Kwan-Ho;Park, Lee-Soon;Oh, Dae-Hee
    • Applied Chemistry for Engineering
    • /
    • v.4 no.3
    • /
    • pp.544-548
    • /
    • 1993
  • Glass transition temperatures($T_g$) of poly(phenylene sulfide sulfone)[PPSS], which were heat treated at various temperature and time, were studied by DSC. Up to $230^{\circ}C$, $T_g$ of heat treated PPSS were increased with increasing the heat treated time. When the sample was heated at $260^{\circ}C$ for 30 minute and $280^{\circ}C$ for 10 minute, however, $T_g$ of those samples were decreased. These phenomena can be explained by the factors of chain extension reaction, oxidative crosslinking, and thermal crosslinking.

  • PDF

Effect of Neighbor Base Sequences on the Base Pair Stabilities at d(CXG) and d(GXC) in Human ε-globin Promoter (사람의 ε-글로빈 프로모트에서 d(CXG)와 d(GXC)의 안정성에 인접한 염기 서열들의 영향 에 관한 연구)

  • Chung, In-Ae;Gang, Jong-Back
    • Journal of Life Science
    • /
    • v.12 no.2
    • /
    • pp.208-212
    • /
    • 2002
  • Human $\varepsilon$-globin DNA fragment was used to determine the thermal stabilities of base pairs at d(CXG) and d(GXC) by Temperature Gradient Gel Electrophoresis(TGGE). The base pair stability depends on the hydrogen bonding interaction and base stacking interaction of neighbor base sequence. The orders of base pair stabilities were T.AG.A = A.G>C.T>T.C>C.A>A.C for d(GXC).d(GYC).

Effects of High Pressure and Sodium Nitrite Levels on Cured Color Development and Residual Nitrite Concentration in Pork Homogenates

  • Hong, Geun-Pyo;Kim, Ji-Sook;Chun, Ji-Yeon;Min, Sang-Gi
    • Food Science of Animal Resources
    • /
    • v.31 no.5
    • /
    • pp.641-648
    • /
    • 2011
  • This study investigated the effects of high pressure with or without thermal treatment on the cured color development and residual nitrite contents of model meat systems (pork, NaCl and sodium nitrite). At low nitrite levels (${\leq}50{\mu}g/g$), 200 MPa of pressure alone (P) did not develop the cured meat color (p>0.05). Thermal treatment (T) showed curing pigmentation (higher CIE L* and CIE a*), and the impacts were more effective when pressure was combined with thermal treatment (PT). In contrast, nitrite levels did not contribute to the cured meat color when ${\geq}200{\mu}g/g$ of nitrite was added to the meat. At high nitrite levels, although the typical cured color that is induced by thermal treatment did not present by pressure alone, the PT treatment still showed a pinker color with low residual nitrite content compared to the T treatment. The higher the pressure level (300 MPa), the greater the cured meat pigmentation with lower residual nitrite. Therefore, the present study demonstrates the possible application of high pressure, both for cured pigmentation and reducing residual nitrite, respective to typical thermal treatments.

Synthesis and Nonlinear Optical Properties of Novel Y-Type Polyesters with Enhanced Thermal Stability of Second Harmonic Generation

  • Kim, Jin-Hyang;Lee, Ju-Yeon;Won, Dong-Seon;Rhee, Bum-Ku
    • Macromolecular Research
    • /
    • v.15 no.6
    • /
    • pp.506-512
    • /
    • 2007
  • 2,3-Di-(2'-hydroxyethoxy)-4'-nitrostilbene (3) was prepared and condensed with terephthaloyl chloride, adipoyl chloride, and sebacoyl chloride to yield novel Y-type polyesters (4-6) containing the NLO-chromophores 2,3-dioxynitrostilbenyl groups, which constituted parts of the polymer backbones. Polymers 4-6 were soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymers 4-5 showed thermal stability up to $300^{\circ}C$ in thermogravimetric analysis with glass transition temperatures $(T_g)$, obtained from differential scanning calorimetry, in the range $81-95^{\circ}C$. The second harmonic generation (SHG) coefficients $(d_{33})$ of the poled polymer films at the 1064 nm fundamental wavelength were around $3.68{\times}10^{-9}$ esu. The dipole alignment exhibited high thermal stability up to $T_g$, and there was no SHG decay below $T_g$ due to the partial main-chain character of the polymer structure.

The Relationship between Weight of Single Garments and Thermal Insulation with a Thermal Manikin (써멀마네킨을 이용한 단일의복의 중량과 보온력에 관한 연구)

  • Choi, Jeong-Wha;Lee, Hyo-Hyun
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.33 no.2
    • /
    • pp.173-186
    • /
    • 2009
  • The purpose of this study was to examine the relationship between the weight of seasonal garments worn by Korean women in their daily lives and thermal insulation. We selected a total of 121 garments(13 kinds of Under garments, 51 Upper garments, 32 Lower garments, 15 Headgear, 10 Gloves Footgear) based on our previous survey using questionnaire and interview. Thermal insulation of single garment was measured with a thermal manikin. Also we measured garment weight, covering area, thickness, air permeability on the each garment(chamber air temperature: $21.5{\pm}0.5^{\circ}C$, humidity: $50{\pm}5%R.H.$ air speed: 0.15m/s). The results are as follow: The very strong positive correlation(r=0.905, p<.01) was recognized between the weight of single garment and thermal insulation. The regression equation of thermal insulation can be represented as follows: Thermal Insulation(clo)=$0.03+0.0004{\times}Garment$ Weight(g)($r^2$=0.820, SEE =0.059). There are significant differences in the thermal insulation and garment weight by season and garment type(p<.05). The each garment category's thermal insulation and garment weight has as follows: Under garment(0.06clo, 89g), Blouse Shirt T-shirt(0.13clo, 200g), Cardigan Sweater Vest(0.14clo, 287g), Coat Jacket Jumper(0.41clo, 890g), Skirt(0.16clo, 276g), Trousers(0.20clo, 438g), Headgear(0.03clo, 102g), Gloves Footgear(0.03clo, 33g).