• 열처리공학회지
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• 제14권6호
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• pp.345-349
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• 2001

This study has investigated the effect of thermal stability and mechanical property of $Fe_{80-X}P_{10}C_6B_4M_X$(X=2, 4, 6, M=transition metal) amorphous alloys fabricated by the melt-spun process. The glass transition temperature($T_g$), crystallization temperature($T_x$) and hardness increase with decreasing electron concentration (e/a) from about 7.38 to 7.18. The decrease of e/a implies the increase in the attractive bonding state between the M elements and other constituent element. The decrease in a/e leads to the enhancement of the attractive bonding state among the constituent elements which is favorable for the increase in $T_g$, $T_x$ and hardness.

• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.424-430
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• 2011

A novel T-type polyurethane 7 containing 1-(2,5-dioxyphenyl)-2-(5-(1,2,2-tricyanovinyl)-2-thienyl)ethenes as NLO chromophores, which constitute part of the polymer backbone, was prepared. Polyurethane 7 is soluble in common organic solvents such as DMF and DMSO. It shows a thermal stability up to $270^{\circ}C$ from TGA thermogram with $T_g$ value obtained from DSC thermogram near $155^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer film at 1560 nm fundamental wavelength is $3.56{\times}10^{-9}$ esu. Polymer 7 exhibits a thermal stability even at $5^{\circ}C$ higher than $T_g$, and no significant SHG decay is observed below $160^{\circ}C$, which is acceptable for nonlinear optical device applications.

• 전기학회논문지
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• 제65권9호
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• pp.1504-1510
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• 2016

The aim of this study is to improve properties both glass transition temperature($T_g$) and coefficient of thermal expansion(CTE) using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40, 50, 60wt%)+surface modified nano alumina(1_phr) composites. 20 kinds specimen were prepared with containing micro, nano alumina and GDE as a micro composites(10, 20, 30, 40, 50, 60, 70wt%) or a nano/micro alumina composites(1phr/40, 50, 60wt%). Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The glass transition temperature and coefficients of thermal expansion was evaluated by DSC and TMA. The glass transition temperature decreased and coefficients of thermal expansion become smaller with filled contents of epoxy/micro alumina composites. On the other hand, $T_g$ and CTE as GDE addition variation(1,2,3,5g) of epoxy/micro-nano alumina composites decreased and increased respectively.

• 한국수산과학회지
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• 제42권5호
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• pp.494-502
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• 2009

A quantitative model was developed in order to estimate fishery production damage due to anthropogenically induced environmental changes. The model is described in the following equation, $Y_D=\frac{{\phi}_D}{{\phi}_G}[Y_0{\cdot}(t_p-t_0)-\frac{Y_0}{{\phi}_G}(1-e^{-{\phi}_G(t_p-t_0)})]$, where, $Y_D$ is annual amount of fishery production by nuclear power plant. ${\varphi}$ D and ${\varphi}$ G are instantaneous decreasing coefficient of fishery production by nuclear power plant and instantaneous decreasing coefficient of gross fishery production, respectively. $Y_0$ is annual mean fishery production without damages. $t_p$ is the present time, and $t_0$ is the starting time of damages. The model was applied to fishing grounds near a nuclear power plant on the east coast of Korea. Since fishery production damages have become bigger with increasing emission of thermal effluents from generators activities in the power plant, this factor has also been considered as, $\delta_{D_i}=\delta_D\({\sum}\limits_{i=0}^{n}\;W_i/W_T\)$, where, $\delta_{Di}$ is the cumulative damage rate in fishery production from generators, $\delta_D$ is the total cumulative damage rate in fishery production, $W_i$ is the emission amount of thermal effluents by generator i, and n is the number of generators in the nuclear power plant. This model can be used to conduct initial estimates of fishery production damages, before more detailed assessments are undertaken.

• 비파괴검사학회지
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• 제34권2호
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• pp.141-147
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• 2014

경제성과 함께 다양한 기능성으로 유리 및 금속제를 대체하고 있는 고분자 합성수지인 플라스틱(plastic) 재료의 열화(thermal degradation) 및 열적 특성을 비파괴적으로 평가하기 위하여 초음파의 전파특성(속도 및 감쇠)이 사용되었다. 플라스틱 재료중 범용 열가소성 재료인 높은 투명도의 아크릴 수지(PMMA)에 대해 유리전이온도($T_g$) 범위내에서 열화온도 및 열화시간에 따른 다양한 열화시편에 대해 전파특성 변화가 측정되었다. 열화가 진전될수록 감쇄는 증가하였고 속도는 감소함을 보였으며, 초음파 전파특성의 측정을 통해 열가소성 플라스틱 재료의 정량적 열화평가 및 유리전이온도($T_g$) 영역의 정성적 추정이 가능하였다.

• 공업화학
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• 제4권3호
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• pp.544-548
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• 1993

Poly(phenylene sulfide sulfone)[PPSS]를 시간과 온도를 변화시키면서 열처리를 하였을 때 이들의 유리전이 온도($T_g$)를 DSC로서 조사하였다. 그 결과 PPSS의 $T_g$는 열처리온도가 $230^{\circ}C$까지는 열처리 시간이 길어질수록 증가하다가 평형에 도달하였다. 열처리 온도가 $245^{\circ}C$ 이상에서는 열처리 시간이 길어질수록 $T_g$가 증가하다가 어느 정도 시간이 되면 감소한 뒤 다시 증가하는 것으로 나타났다. 이 현상을 경화가 진행됨에 따른 chain extension반응과 oxidative crosslinking 및 thermal crosslinking으로 설명하였다.

• 생명과학회지
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• 제12권2호
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• pp.208-212
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• 2002

온도 기울기 전기영동장치를 이용하여 d(CXG)와 d(GXC) 염기의 열 안정성을 결정하는데 사람의 $\varepsilon$-글로빈 DNA조각을 사용하였다. 염기 쌍의 안정성은 이웃하는 염기서열에 의한 수소결합과 base stocking 상호작용에 의존한다. 염기 쌍의 안정성은 d(CXG) d(CYG)의 경우에 T.AG.A = A.G>C.T>T.C>C.A>A.C이다.

• 한국축산식품학회지
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• 제31권5호
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• pp.641-648
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• 2011

This study investigated the effects of high pressure with or without thermal treatment on the cured color development and residual nitrite contents of model meat systems (pork, NaCl and sodium nitrite). At low nitrite levels (${\leq}50{\mu}g/g$), 200 MPa of pressure alone (P) did not develop the cured meat color (p>0.05). Thermal treatment (T) showed curing pigmentation (higher CIE L* and CIE a*), and the impacts were more effective when pressure was combined with thermal treatment (PT). In contrast, nitrite levels did not contribute to the cured meat color when ${\geq}200{\mu}g/g$ of nitrite was added to the meat. At high nitrite levels, although the typical cured color that is induced by thermal treatment did not present by pressure alone, the PT treatment still showed a pinker color with low residual nitrite content compared to the T treatment. The higher the pressure level (300 MPa), the greater the cured meat pigmentation with lower residual nitrite. Therefore, the present study demonstrates the possible application of high pressure, both for cured pigmentation and reducing residual nitrite, respective to typical thermal treatments.

• Macromolecular Research
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• 제15권6호
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• pp.506-512
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• 2007

2,3-Di-(2'-hydroxyethoxy)-4'-nitrostilbene (3) was prepared and condensed with terephthaloyl chloride, adipoyl chloride, and sebacoyl chloride to yield novel Y-type polyesters (4-6) containing the NLO-chromophores 2,3-dioxynitrostilbenyl groups, which constituted parts of the polymer backbones. Polymers 4-6 were soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymers 4-5 showed thermal stability up to $300^{\circ}C$ in thermogravimetric analysis with glass transition temperatures $(T_g)$, obtained from differential scanning calorimetry, in the range $81-95^{\circ}C$. The second harmonic generation (SHG) coefficients $(d_{33})$ of the poled polymer films at the 1064 nm fundamental wavelength were around $3.68{\times}10^{-9}$ esu. The dipole alignment exhibited high thermal stability up to $T_g$, and there was no SHG decay below $T_g$ due to the partial main-chain character of the polymer structure.

• 한국의류학회지
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• 제33권2호
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• pp.173-186
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• 2009

The purpose of this study was to examine the relationship between the weight of seasonal garments worn by Korean women in their daily lives and thermal insulation. We selected a total of 121 garments(13 kinds of Under garments, 51 Upper garments, 32 Lower garments, 15 Headgear, 10 Gloves Footgear) based on our previous survey using questionnaire and interview. Thermal insulation of single garment was measured with a thermal manikin. Also we measured garment weight, covering area, thickness, air permeability on the each garment(chamber air temperature: $21.5{\pm}0.5^{\circ}C$, humidity: $50{\pm}5%R.H.$ air speed: 0.15m/s). The results are as follow: The very strong positive correlation(r=0.905, p<.01) was recognized between the weight of single garment and thermal insulation. The regression equation of thermal insulation can be represented as follows: Thermal Insulation(clo)=$0.03+0.0004{\times}Garment$ Weight(g)($r^2$=0.820, SEE =0.059). There are significant differences in the thermal insulation and garment weight by season and garment type(p<.05). The each garment category's thermal insulation and garment weight has as follows: Under garment(0.06clo, 89g), Blouse Shirt T-shirt(0.13clo, 200g), Cardigan Sweater Vest(0.14clo, 287g), Coat Jacket Jumper(0.41clo, 890g), Skirt(0.16clo, 276g), Trousers(0.20clo, 438g), Headgear(0.03clo, 102g), Gloves Footgear(0.03clo, 33g).