• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1070-1078
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• 1998

Thermodynamic analysis on carbon dioxide reforming of methane was performed using a computer program which can handle condensed species in the products, and the reforming experiments were conducted over $Al_2O_3$, $La_2O_3$, ZSM-5, MCM-41, KIT-1 supported nickel catalysts, and a commercial ICI 46-1. It was estabished that a system which consists of $CH_4$, $CO_2$, CO, $H_2$, $H_2O$, and C is appropriate for theoretical equilibrium calculations and addition of water vapor or oxygen was found to diminish the contribution of carbon dioxide in reforming. Silicate molecular sieve-supported catalysts such as Ni/ZSM-5, Ni/MCM-41, Ni/KIT-1 were effective for high $CH_4$ and $CO_2$ conversions as well as for high CO yield. Coke formation was suppressed when CaO was added as a promoter. Ni/Ca/KIT-1 which contains 10% Ni with 3% Ca showed conversion approaching equilibrium levels above $650^{\circ}C$ and maintained constant activity over 20 h. Despite increased space velocity, relatively high conversion and CO yield were observed.

• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.1
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• pp.15-25
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• 2020

Biogas production potential was experimentally estimated for mono- and co-digestion of cow manure and waste grass. The two organic wastes were mixed at five different ratios (100:0, 75:25, 50:50, 25:75, 0:100) on the volatile solids basis, and were assessed using biochemical methane potential (BMP) test. Thee reaction temperatures, 25℃, 30℃ and 35℃, were applied as well, resulting in 15 different combinations for the test. The results showed that both higher temperature and waste grass mixing ratio resulted in higher methane yield and maximum methane production rate. Based on the experimental results, a theoretical farm- or community-scale (240 or 2400 ㎥) anaerobic digester was designed to evaluate the energy balance associated with mono- and co-digestion of the wastes at different temperatures. Although the energy production increased as the temperature and the waste grass mixing ratio increased, the net energy gain, energy production subtracted by energy consumption for heating and maintenance, was estimated to be the highest at 30℃, followed by at 35℃ and 25℃. Therefore, it is advised that both the experimental methane production and the detailed design parameters must be considered for the optimization of the net energy gain from these wastes.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.494-500
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• 2016

In order to remove acetyl group from yellow poplar, deacetylation was performed using sodium hydroxide (NaOH) prior to oxalic acid pretreatment. During the deacetylation ($60^{\circ}C$ for 80 min, 0.8% NaOH), most of the acetyl group were removed from hemicellulose. Simultaneous saccharification and fermentation (SSF) and semi-SSF were carried out based on solid loading (10, 12.5, 15%) of deacetylated biomass and pre-hydrolysis with enzymes (0, 6, 12, 24 h). The highest ethanol was obtained as 26.73 g/L after 120 h when 10% of biomass was used for SSF. It is corresponding to 88.41% of theoretical ethanol yield. At the 12.5% and 15% of biomass loading, the highest ethanol was obtained from 6 h pre-hydrolysis. It was 32.34 g/L and 27.15 g/L, respectively, and corresponding to ethanol yield of 85.58 and 59.87%. In order to remove fermentation inhibitors from hydrolysates, overliming was performed using calcium hydroxide ($Ca(OH)_2$). The highest ethanol was 5.28 g/L after 72 h of fermentation.

• Journal of the Korean Society for Marine Environment & Energy
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• v.9 no.3
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• pp.154-159
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• 2006

It is essential to understand the decomposition characteristics for developing the optimum anaerobic digestion system of organic wastes. In this study, BMP (Biochemical Methane Potential) test using serum bottle was conducted to evaluate the anaerobic degradability of fish offal. 3 different groups of fish offal including waste from mackerel and hairtail handling except viscera and fish viscera were chosen for the substrates. Grinded fish offal was transferred anaerobically to serum bottle in amounts of 50 ml, 100 ml and 150 ml, respectively. BMP test was carried out in triplicate. Cumulative methane production and methane production rate depending on incubation time were evaluated. These results varied depending on substrate characteristics. The average values of ultimate methane yield ranged between $420ml{\cdot}CH_4/g{\cdot}VS$ and $490ml{\cdot}CH_4/g{\cdot}VS$, and the methane production and degradation rate of viscera were higher than those of other parts of fish offal. According to the analysis of elemental composition, average C/N ratio of fish offal used in this study was 5.2. Theoretical ultimate methane yield calculated from elemental composition was $522ml{\cdot}CH_4/g{\cdot}VS$. Biodegradability was calculated as 0.847.

• Korean Journal of Medicinal Crop Science
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• v.5 no.4
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• pp.284-288
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• 1997

In order to study on suitable harvest time of adlay utilizing self-feeding combine harvester with four rows, which is originally designed for rice harvest, harvesting were carried out at four different times (40, 50, 60 and 70 days after anthesis) . For efficient operation, appropriate working rows were 2 rows at 50 days after anthesis and working speed was 0.26m/sec at 60 days after anthesis. Theoretical working capability was 11.23a/hr at 60 days after anthesis. As the harvesting was delayed, water content of adlay decreased. Water content of culm+leaf was $69.7{\sim}55.3%$ and water content of grain was 34.2% at 60 days after anthesis. The later adlay was harvested. the higher the percent of ripened grain was. But the immature grain was decreased. Remnants was less than 1.8% at 60 days after anthesis. The later adlay was harvested, the heavier volume weight was. Yield was the highest at 60 days after anthesis. When utilizing self-feeding combine harvester with four rows, which was originally designed for rice harvest, suitable harvesting time was 60 days after anthesis. Therefore, theoretically suitable harvest time was 68 days after anthesis.

• Journal of Ginseng Research
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• v.42 no.3
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• pp.270-276
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• 2018

Background: Notoginsenoside Ft1 is a promising potential candidate for cardiovascular and cancer disease therapy owing to its positive pharmacological activities. However, the yield of Ft1 is ultralow utilizing reported methods. Herein, an acid hydrolyzing strategy was implemented in the acquirement of rare notoginsenoside Ft1. Methods: Chemical profiles were identified by ultraperformance liquid chromatography coupled with quadruple-time-of-flight and electrospray ionization mass spectrometry (UPLC-Q/TOF-ESI-MS). The acid hydrolyzing dynamic changes of chemical compositions and the possible transformation pathways of saponins were monitored by ultrahigh-performance LC coupled with tandem MS (UHPLC-MS/ MS). Results and conclusion: Notoginsenoside Ft1 was epimerized from notoginsenoside ST4, which was generated through cleaving the carbohydrate side chains at C-20 of notoginsenosides Fa and Fc, and vinaginsenoside R7, and further converted to other compounds via hydroxylation at C-25 or hydrolysis of the carbohydrate side chains at C-3 under the acid conditions. High temperature contributed to the hydroxylation reaction at C-25 and 25% acetic acid concentration was conducive to the preparation of notoginsenoside Ft1. C-20 epimers of notoginsenoside Ft1 and ST4 were successfully separated utilizing solvent method of acetic acid solution. The theoretical preparation yield rate of notoginsenoside Ft1 was about 1.8%, which would be beneficial to further study on its bioactivities and clinical application.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.4
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• pp.53-61
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• 2018

Anaerobic digestion (AD) is one of the most widely used process that can convert the organic fraction of waste activated sludge (WAS) into biogas. However, most researched actual methane yields of anaerobic digester (AD) on lab scale is lower than theoretical ones. Bioelectrochemical, anaerobic digester was used to increase methane yield from waste activated sludge. The influence of anaerobic digestion sludge and raw sludge mixing ratio (3:7, 5:5) on methane yield and organic matter removal efficiency were explored. As a result, when the mixing ratio of bioelectrochemical anaerobic sludge was 5:5 compared with 3:7, the highest methane yields were 294.2 mL $CH_4/L$ (0.63 times increase) and 52.5% (7.5% increase), the bioelectrochemical anaerobic digester(5:5) was more stable in the pH, t otal alkalinity and VFAs, respectively. These results showed that the increase in the mixing ratio of anaerobic digestion sludge was found to be effective for maintaining the stable performance of bioelectrochemical anaerobic digester.

• Journal of the Korea Organic Resources Recycling Association
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• v.29 no.2
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• pp.31-38
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• 2021

The aim of this study is to evaluate the possibility of treating slaughterhouse by-products using microbial electrolysis cells (MECs). The diluted pig liver was fed to MEC reactors with the influent COD concentrations of 772, 1,222, and 1,431 mg/L, and the applied voltage were 0.3, 0.6, and 0.9 V. The highest methane production of 5.9 mL was obtained at the influent COD concentration of 1,431 mg/L and applied voltage of 0.9 V. In all tested conditions, COD removal rate was increased as the influent COD concentration increased with average removal rate of 62.3~81.1%. The maximum methane yield of 129~229 mL/g COD was obtained, which is approximately 80% of theoretical maximum value. It might be due to the bioelectrochemical reaction greatly increased the biodegradability of pig liver. Future research is required to improve the methane yield and digestibility through optimizing the reactor design and operating conditions.

• Structural Engineering and Mechanics
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• v.30 no.6
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• pp.733-761
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• 2008

The failure of reinforced concrete structures in recent earthquakes caused concern about the performance of beam column joints. Confinement of joint is one of the ways to improve the performance of beam column joints during earthquakes. This paper describes an experimental study of exterior beam-column joints with two non-conventional reinforcement arrangements. One exterior beam-column joint of a six story building in seismic zone III of India was designed for earthquake loading. The transverse reinforcement of the joint assemblages were detailed as per IS 13920:1993 and IS 456:2000 respectively. The proposed nonconventional reinforcement was provided in the form of diagonal reinforcement on the faces of the joint, as a replacement of stirrups in the joint region for joints detailed as per IS 13920 and as additional reinforcement for joints detailed as per IS 456. These newly proposed detailing have the basic advantage of reducing the reinforcement congestion at the joint region. In order to study and compare the performance of joint with different detailing, four types of one-third scale specimens were cast (two numbers in each type). The main objective of the present study is to investigate the effectiveness of the proposed reinforcement detailing. All the specimens were tested under reverse cyclic loading, with appropriate axial load. From the test results, it was found that the beam-column joint having confining reinforcement as per IS: 456 with nonconventional detailing performed well. Test results indicate that the non-conventionally detailed specimens, Type 2 and Type 4 have an improvement in average ductility of 16% and 119% than their conventionally detailed counter parts (Type1 and Type 3). Further, the joint shear capacity of the Type 2 and Type 4 specimens are improved by 8.4% and 15.6% than the corresponding specimens of Type 1 and Type 3 respectively. The present study proposes a closed form expression to compute the yield and ultimate load of the system. This is accomplished using the theory of statics and the failure pattern observed during testing. Good correlation is found between the theoretical and experimental results.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.4D
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• pp.489-496
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• 2011

Bike system is one of the green transportation systems and spotlighted recently. In the TOD (Transit-Oriented Development) based transportation and urban planning, bike system will be the major part as linkage modes. In this paper, bike demand estimation model was firstly established in Korea, with considering of personal and household characteristics of traveller, social and economic characteristics of city, weather conditions, and so on. The model reflects population density, the number of students except elementary school students, the number of vehicles, the length of bike roads, and monthly income. The adjusted $R^2$ was 0.738: the model is highly fitted. The results of this paper yield bike demand estimation in the urban planning area: further estimated results will be using to determine economic feasibility and size of bike facility. In other words, this paper is expected to provide the theoretical basis that supporting justification and investment efficiency of bike plans, which are actively progressed recently.