• Title/Summary/Keyword: the second derivative

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Highly Selective Derivative Spectrophotometry for Determination of Nickel Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Solutions

  • Eskandari, Habibollah
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1137-1142
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    • 2004
  • A spectrophotometric and first derivative spectrophotometric method was developed in aquatic Tween 80 micellar solutions for selective determination of nickel without using any pre-separation step. 1-(2-Pyridylazo)-2-naphthol (PAN), as a sensitive chromogenic complexing agent formed a red-colored Ni(II)-PAN complex in Tween 80 media with satisfactory solubility and stability. Conditions such as pH, PAN concentration, type and concentration of micellizing agent were optimized. Molar absorptivity of Ni-PAN complex was found $4.62\;{\times}\;10^4L\;cm^{?1}\;mol^{?1}$ at 569 nm, under the optimum condition. Calibration graphs were derived by zero, first and second derivative spectrophotometry at maximum wavelengths of 569, 578 and 571 nm with linear ranges of 30-1800, 20-2500 and 30-2000 ng $mL^{?1}$ , respectively. Precision as standard deviation as well as accuracy as recovery percent were in the range of 1-20 ng $mL^{?1}$, and 93.3-103.3%, respectively, for the entire of the linear ranges. Spectrophotometric detection limit was 3 ng $mL^{?1}$ and effects of diverse ions on the first derivative determination of nickel were studied to investigate selectivity of the method. Interferences of cobalt and copper on the nickel determination were prevented using o-phenanthroline as masking agent. The recommended procedures were applied to the various synthetic and stainless steel alloys, tea leaves and human hair, with satisfactory results.

A Model reference adaptive speed control of marine diesel engine by fusion of PID controller and fuzzy controller

  • Yoo, Heui-Han
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.7
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    • pp.791-799
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    • 2006
  • The aim of this paper is to design an adaptive speed control system of a marine diesel engine by fusion of hard computing based proportional integral derivative (PID) control and soft computing based fuzzy control methods. The model of a marine diesel engine is considered as a typical non oscillatory second order system. When its model and the actual marine diesel engine ate not matched, it is hard to control the speed of the marine diesel engine. Therefore, this paper proposes two methods in order to obtain the speed control characteristics of a marine diesel engine. One is an efficient method to determine the PID control parameters of the nominal model of a marine diesel engine. Second is a reference adaptive speed control method that uses a fuzzy controller and derivative operator for tracking the nominal model of the marine diesel engine. It was found that the proposed PID parameters adjustment method is better than the Ziegler & Nichols' method, and that a model reference adaptive control is superior to using only PID controller. The improved control method proposed here, could be applied to other systems when a model of a system does not match the actual system.

BEHAVIOR OF HOLOMORPHIC FUNCTIONS ON THE BOUNDARY OF THE UNIT DISC

  • Ornek, Bulent Nafi
    • The Pure and Applied Mathematics
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    • v.24 no.3
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    • pp.129-145
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    • 2017
  • In this paper, we establish lower estimates for the modulus of the non-tangential derivative of the holomorphic functionf(z) at the boundary of the unit disc. Also, we shall give an estimate below |f''(b)| according to the first nonzero Taylor coefficient of about two zeros, namely z = 0 and $z_0{\neq}0$.

A surface extension method using several functions

  • 김회섭
    • Proceedings of the Korean Society of Computational and Applied Mathematics Conference
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    • 2003.09a
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    • pp.3.2-3
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    • 2003
  • We propose a method of surface extension method using several functions. Interpolation theory is well developed in curve and surface. But extrapolation theory is not well developed because it is not unique outside the useful domain. It requires continuous, first derivative, second derivative continuous extension for matching in NC(Numerical Control) machine. In the past, we generate data outside the useful area and refit those data using least squares method. this has some problems which have some errors within the useful area. We keep the useful area and extend the unuseful area by a function

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CONCERNING THE RADIUS OF CONVERGENCE OF NEWTON'S METHOD AND APPLICATIONS

  • Argyros, Ioannis K.
    • Journal of applied mathematics & informatics
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    • v.6 no.3
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    • pp.685-696
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    • 1999
  • We present local and semilocal convergence results for New-ton's method in a Banach space setting. In particular using Lipschitz-type assumptions on the second Frechet-derivative we find results con-cerning the radius of convergence of Newton's method. Such results are useful in the context of predictor-corrector continuation procedures. Finally we provide numerical examples to show that our results can ap-ply where earlier ones using Lipschitz assumption on the first Frechet-derivative fail.

SEMILOCAL CONVERGENCE THEOREMS FOR A CERTAIN CLASS OF ITERATIVE PROCEDURES

  • Ioannis K. Argyros
    • Journal of applied mathematics & informatics
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    • v.7 no.1
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    • pp.29-40
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    • 2000
  • We provide semilocal convergence theorems for Newton-like methods in Banach space using outer and generalized inverses. In contrast to earlier results we use hypotheses on the second instead of the first Frechet-derivative. This way our Newton-Kantorovich hypotheses differ from earlier ones. Our results can be used to solve undetermined systems, nonlinear least square problems and ill-posed nonlinear operator equations.

Edge Detection using Second Order Derivative Strain (미분방식을 이용한 에지 추출)

  • Kim, Alla;Lee, Hyun-Jik;Kim, Yoon-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.165-167
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    • 2008
  • 본 논문에서는 기존의 에지 추출 알고리즘을 비교하여 알고리즘이 영상 처리 과정에 미치는 영향을 분석하였다. 기존의 에지 추출 알고리즘인 Sobel, Prewitt, Roberts 등을 비교 분석 한 뒤 1차 미분 조건에 2차 미분의 단점을 보완한 에지 추출 마스크 방식을 제안한다.

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Method for Detection of Saturation of a Current Transformer (전류변성기의 포화 검출을 위한 알고리즘 개발)

  • Nam, Soon-Ryul;Choi, Joon-Ho;Kang, Sang-Hee;Min, Sang-Won
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.5
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    • pp.879-884
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    • 2009
  • A Method for detection of saturation of a current transformer(CT) is proposed. The algorithm is initiated when the end point of a saturation period is detected. This detection is achieved by checking the time interval between the adjacent zero-crossing points of the second derivative of the secondary current. Once the end point of the saturation period is detected, the beginning point of the corresponding saturation period is determined by backward examination of the sum of the secondary current from the end point. The performance of the algorithm was evaluated for a-g faults on a 345 kV 100km overhead transmission line. The Electromagnetic Transient Program(EMTP) was used to generate fault current signals for different fault inception angles and different remanent fluxes. The performance evaluation shows that the proposed algorithm successfully detects the saturation period even in the presence of a remanent flux.

Fixed-point Iteration for the Plastic Deformation Analysis of Anisotropic Materials (이방성 재료의 소성변형 해석을 위한 고정점 축차)

  • Seung-Yong Yang;Jeoung Han Kim
    • Journal of Powder Materials
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    • v.30 no.1
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    • pp.29-34
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    • 2023
  • A fixed-point iteration is proposed to integrate the stress and state variables in the incremental analysis of plastic deformation. The Conventional Newton-Raphson method requires a second-order derivative of the yield function to generate a complicated code, and the convergence cannot be guaranteed beforehand. The proposed fixed-point iteration does not require a second-order derivative of the yield function, and convergence is ensured for a given strain increment. The fixed-point iteration is easier to implement, and the computational time is shortened compared with the Newton-Raphson method. The plane-stress condition is considered for the biaxial loading conditions to confirm the convergence of the fixed-point iteration. 3-dimensional tensile specimen is considered to compare the computational times in the ABAQUS/explicit finite element analysis.