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Physical and Chemical Properties of Cover Soils of waste Landfills in Kyonggi-Do Area (경기도 지역 쓰레기 매립지 복토층 토양의 이화학성)

  • 이상모;김기대;이은주;김판기;이군택
    • Journal of Soil and Groundwater Environment
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    • v.7 no.1
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    • pp.53-62
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    • 2002
  • The physical and chemical properties of cover soils of 10 waste landfill sites in Kyonggi-Do area, where social circumstances at present forces to consider the reuse of landfill, were investigated to provide the informations of soil environment which are necessary to establish the appropriate ecological restoration plan of waste landfills. The pH and electrical conductivity of soils were higher in landfills sites than in reference sites (area around landfill sites), indicating the salt accumulation in surface soil. However, total-N and organic matter contents were lower in landfills sites than in reference sites. In landfill sites, the total-N and plant available-P contents were less than 0.15% and 20mg/kg, respectively. Exchangeable cations (K, Ca, Mg and Na) and heavy metal (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) contents varied between the landfill sites, but were higher in landfills sites than in reference sites. The major exchangeable cation of soil was Ca. Heavy metal contents were much lower than the critical concentration which phytotoxicity is considered to be possible and the standard for agricultural land of Korean Soil Environmental Preservation Act. Therefore, the proper soil management plan to increase the soil fertility is recommended for the ecological restoration of landfill using natural or artificial vegetation.

Effects of Dietary Fiber Extracts from Brewer's Spent Grain on Quality Characteristics of Chicken Patties Cooked in Convective Oven

  • Kim, Hyun-Wook;Hwang, Ko-Eun;Song, Dong-Heon;Lee, Soo-Yeon;Choi, Min-Sung;Lim, Yun-Bin;Choi, Ji-Hun;Choi, Yun-Sang;Kim, Hack-Youn;Kim, Cheon-Jei
    • Food Science of Animal Resources
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    • v.33 no.1
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    • pp.45-52
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    • 2013
  • Brewer's spent grain (BSG) is a by-product of beer manufacturing. This study was conducted to evaluate the effect of dietary fiber extracts from brewer's spent grain on quality characteristics of chicken patties. The total fiber content of BSG dietary fiber extracts after extraction increased from 58.11% to 68.57%, and the extracted dietary fiber extracts were added to chicken patties at 0, 1, 2, 3, and 4%, respectively. The effects of the BSG dietary fiber extracts on pH, color, cooking loss, reduction in patty diameter, salt-soluble protein solubility, texture, and sensory characteristics of chicken patties were evaluated. The addition of BSG dietary fiber extracts decreased pH and lightness values, and increased redness and yellowness. Chicken patties formulated with 3-4% BSG dietary fiber extracts had the lowest cooking loss among all treatments (p<0.05). The diameter of chicken patties was not affected by the addition of BSG dietary fiber extracts. Additionally, no significant difference was observed in salt-soluble protein solubility after adding 3% BSG dietary fiber extracts compared to that in the control. Textural and sensory properties were different among the chicken patties, and the 3% BSG dietary fiber-added chicken patty had the highest acceptability. Our results indicate that 3% BSG dietary fiber extract can be used as a good source of dietary fiber for improving the quality characteristics of chicken patties.

Study on GO Dispersion of PC/GO Composites according to In-situ Polymerization Method (In-situ 중합방법에 따른 폴리카보네이트(PC)/그래핀 옥사이드(GO) 복합체의 GO 분산성 연구)

  • Lee, Bom Yi;Park, Ju Young;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.336-340
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    • 2015
  • Three different types of polycarbonate (PC)/graphene oxide (GO) composites using diphenyl carbonate as a monomer were fabricated by melt polymerization. Those were the PC/GO composite (PC/GO) using a twin extruder, in-situ PC/GO composite (PC/GO-cat.) using a catalyst, and in-situ PC/GO composite (PC/GO-COCl) using a GO-COCl treated by -COCl, Chemical structures of the composites were confirmed by C-H and C=O stretching peak at $3000cm^{-1}$ and $1750cm^{-1}$, respectively. The slope for the storage (G') versus loss (G") modulus plot decreased with an increase in the heterogeneous property of polymer melts. So we can check the GO dispersion of the PC/GO composites using by the slop for G'-G" plot. According to the G'- G" slopes for three different types of PC/GO composites, GO was well dispersed within PC matrix in case of PC/GO and PC/GO-cat.. It was also confirmed by atomic force microscope (AFM) photos. One of the reasons for the poor GO dispersion of PC/GO-COCl is branching and crosslinking processes occurred during polymerization, which was further confirmed by a plot for the complex modulus versus phase difference.

Release Behavior of Olmesartan Medoxomil from Solid Dispersion Prepared by PVP Addition (PVP 첨가에 의해 제조된 올메사탄 메독소밀 고체분산체의 방출패턴 연구)

  • Oh, Seung-Chang;Lee, Cheon Jung;Lee, Hyun Gu;Park, Jin Young;Jeong, Hyun Ki;Kim, Young-Lae;Lim, Dong-Kwon;Lee, Dongwon;Khang, Gilson
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.33-39
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    • 2015
  • Olmesartan affiliated to biopharmaceutics classification system class 2 is a poorly water soluble drug. For this reason, olmesartan showed a low bioavailability and a lot of difficulties in the process of designing the pharmaceutical formulation. We prepared the solid dispersions of olmesartan. We confirmed the dissolution rate of drug which was prepared by manufacturing. The pharmaceutical formulation of solid dispersions was designed by using PVP as water soluble polymer. We analyzed morphological feature of solid dispersion by employing a scanning electron microscope. Then, the crystalline property of solid dispersion was confirmed through X-ray diffraction and differential scanning calorimeter. Also, the chemical change of solid dispersion was confirmed by the Fourier transform infrared spectroscopy. In vitro dissolution test was used to analyze the dissolution rate of solid dispersion. The prepared solid dissolution olmesartan confirmed the dissolution rate in the pH 1.2. It was compared with olmetec and improved dissolution rate through solid dispersion.

Effect of Silicate Fertilizer Application on Zoysiagrass (Zoysia japonica Steud.) Field (들잔디 재배지에서 규산질비료 살포 효과)

  • Bae, Eun-Ji;Kim, Chung-Yeol;Yoon, Jun Hyuck;Lee, Kwang-Soo;Park, Yong-Bae
    • Weed & Turfgrass Science
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    • v.7 no.3
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    • pp.247-257
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    • 2018
  • This study was conducted to find out the optimum silicate fertilization for improving the quality and density of zoysiagrass (Zoysia japonica Steud.), the growth of zoysiagrass and changes in chemical properties of soil in field experiments treated with different levels of silicate fertilizer during 3 years from 2012 to 2014. An increase in the silicate fertilizer from 100, 200, to $400kg\;10a^{-1}$ led to a significant increase in the fresh and dry weight of shoots and stolons, the number of shoots and length of stolon, but were not significantly different between 200 and $400kg\;10a^{-1}$. Moreover, soil pH, EC and the contents of available $SiO_2$ were increased as the rate of silicate fertilizer application increased. Thus, these results demonstrated that the silicate fertilizer rate for maximum growth of zoysiagrass was $200kg\;10a^{-1}$ in consideration of improving growth of zoysiagrass and the chemical property of the soil.

The Effect of Graphene on the Electrical Properties of a Stretchable Carbon Electrode (그래핀 첨가에 따른 신축성 카본전극의 전기적 특성 변화)

  • Lee, T.W.;Park, H.H.
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.77-82
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    • 2014
  • Stretchable electrodes are focused due to many demands for soft electronics. One of the candidates, carbon black composites have advantages of low cost, easy processing and decreasing resistivity in a certain range during stretching. However, the electrical conductivity of carbon black composites is not enough for electronic devices. Graphene is 2-dimensional nanostructured carbon based material which shows good electrical properties and flexibility. They may help to improve electrical conductivity of the carbon black composites. In this study, graphene was added to a carbon black electrode to enhance electrical properties and investigated. Electrical resistivity of graphene added carbon electrode decreased comparing with that of carbon black electrode because graphene bridged non-contacting carbon black aggregates to strengthen the conductive network. Also graphene reduced an increase in the resistance of the carbon black electrode applied to strain because they connected gap of separated carbon black aggregates and aligned along the stretching direction at the same time. In conclusion, an addition of graphene to carbon black gives two benefits on the electrical properties of carbon black composite as a stretchable electrode.

Biosynthesis of Isoprenoids: Characterization of a Functionally Active Recombinant 2-C-methyl-D-erythritol 4-phosphate Cytidyltransferase (IspD) from Mycobacterium tuberculosis H37Rv

  • Shi, Wenjun;Feng, Jianfang;Zhang, Min;Lai, Xuhui;Xu, Shengfeng;Zhang, Xuelian;Wang, Honghai
    • BMB Reports
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    • v.40 no.6
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    • pp.911-920
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    • 2007
  • Tuberculosis, caused by Mycobacterium tuberculosis, continues to be one of the leading infectious diseases to humans. It is urgent to discover novel drug targets for the development of antitubercular agents. The 2-C-methyl-Derythritol-4-phosphate (MEP) pathway for isoprenoid biosynthesis has been considered as an attractive target for the discovery of novel antibiotics for its essentiality in bacteria and absence in mammals. MEP cytidyltransferase (IspD), the third-step enzyme of the pathway, catalyzes MEP and CTP to form 4-diphosphocytidyl-2-C-methylerythritol (CDP-ME) and PPi. In the work, ispD gene from M. tuberculosis H37Rv (MtIspD) was cloned and expressed. With N-terminal fusion of a histidine-tagged sequence, MtIspD could be purified to homogeneity by one-step nickel affinity chromatography. MtIspD exists as a homodimer with an apparent molecular mass of 52 kDa. Enzyme property analysis revealed that MtIspD has high specificity for pyrimidine bases and narrow divalent cation requirements, with maximal activity found in the presence of CTP and $Mg^{2+}$. The turnover number of MtIspD is $3.4 s^{-1}$. The Km for MEP and CTP are 43 and $92{\mu}M$, respectively. Furthermore, MtIspD shows thermal instable above $50^{\circ}C$. Circular dichroism spectra revealed that the alteration of tertiary conformation is closely related with sharp loss of enzyme activity at higher temperature. This study is expected to help better understand the features of IspD and provide useful information for the development of novel antibiotics to treat M. tuberculosis.

Extraction properties and chemical stability of turmeric pigments in salt, sucrose, and acetic acid preservation (염, 당, 산 침지조건에서 심황색소의 추출특성 및 화학적 특성 변화)

  • Kang, Smee;Sung, Yunkyung;Hong, Jungil
    • Korean Journal of Food Science and Technology
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    • v.52 no.1
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    • pp.19-25
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    • 2020
  • Turmeric pigments have been used as coloring agents and functional ingredients. In this study, the extraction property and chemical stability of the pigments were evaluated in several preservative solutions containing NaCl, sucrose, and acetic acid. After 72 h of infusion, the protein and polyphenol levels and antioxidant activity of the turmeric extracts in the solutions were less pronounced than those in water. Acetic acid (12%) was more efficient at extracting curcuminoids from turmeric than water, NaCl (20%), or sucrose (25%). Curcumin was highly abundant in all solutions. The relative yield of bisdemethoxycurcumin (BMC) was the highest in acetic acid, whereas that of curcumin was highest in NaCl and sucrose solutions. Curcuminoids were relatively stable in sucrose and acetic acid; among them, BMC had the highest stability. The stability of the curcuminoid solution decreased based on the increase in NaCl content, whereas it was significantly enhanced in sucrose and acetic acid. The observations from this study can be applied to the processing and storage of turmeric-derived products in these preservative agents.

Hydraulic Stability and Wave Transmit Property of Stacked Geotextile Tube by Hydraulic Model Test (수리모형시험을 통한 다단식 지오텍스타일 튜브의 안정성 및 파랑 전달특성에 관한 연구)

  • Oh Young In;Shin Eun Chul
    • Journal of the Korean Geotechnical Society
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    • v.21 no.2
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    • pp.57-65
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    • 2005
  • Geotextile have been used for the past 30 years for various types of containers, such as small sandbag, 3-D fabric forms and aggregate filled gabion etc. While they are mainly used for flood and water control, they are also used against beach erosion fir shore protection. Especially, large-sized geotextile tube structures are used in various innovative coastal systems involving breakwaters. This paper presents the hydrodynamic behavior of geotextile tubes based on the results of hydraulic model tests. These tube are generally about 1.0 m to 2.0 m in diameter, thou띤 they can be sized for any application. The tubes can be used solely, or stacked to add greater height and usability. Stacked geotextile tubes will be created by adding the height necessary for some breakwaters and embankment, therefore increasing the usability of geotextile tubes. The hydraulic model test was conducted as structural condition and wave conditions. Structural condition is installation direction to the wave (perpendicular and 45$^{circ}$$), and wave condition is varied with the significant wave height ranging from 3.0 m to 6.0 m. Compared with previous test result, the stacked geotextile tube is more stable against wave attack than single tube. Also, the case of none-water depth above crest is more stable than 0.5H of water depth above crest. The incline installed stacked tube is more effective for wave adsorption.

Study of Oxygen Plasma Effects to Reduce the Contact Resistance of n-type GaN with Nitrogen Polarity (질소 분극면을 갖는 N형 질화물반도체의 접촉저항 감소를 위한 산소 플라즈마 효과에 관한 연구)

  • Nam, T.Y.;Kim, D.H.;Lee, W.H.;Kim, S.J.;Lee, B.G.;Kim, T.G.;Jo, Y.C.;Choi, Y.S.
    • Journal of the Korean Vacuum Society
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    • v.19 no.1
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    • pp.10-13
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    • 2010
  • We studied the effect of $O_2$ plasma treatments on the electrical property of Ti / Al ohmic contacts to N-face n-type GaN. The surface of N-face, n-type GaN has been treated with $O_2$ plasma for 120 s before the deposition of bilayered electrodes, Ti (50 nm) / Al (35 nm), and its contact resistance was compared with that of the reference sample without $O_2$ plasma. As a result, we found that the ohmic contact was reduced from $4.3\;{\times}\;10^{-1}\;{\Omega}cm^2$ to $1.25\;{\times}\;10^{-3}\;{\Omega}cm^2$ by applying $O_2$ plasma on the surface of n-type GaN, which was attributed to the reduction in the Schottky barrier height (SBH), caused by nitrogen vacancies formed during the $O_2$ plasma process.