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A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand

  • Wang, Xiu-Li;Han, Na;Lin, Hong-Yan;Xu, Chuang;Luan, Jian;Liu, Guo-Cheng
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3793-3796
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    • 2012
  • A novel 3D compound $\{[Cu(L)(H_2O)_4][Cu_2(SIP)_2(L)_2]\}{\cdot}2H_2O$ (1) (L = N,N-bis(4-pyridinecarboxamide)-1,4-butane, SIP = 5-sulfoisophthalate) is hydrothermally synthesized. X-ray diffraction analysis reveals that compound 1 is composed of 2D anionic $[Cu_2(SIP)_2(L)_2]_n{^{2n-}}$ double-layers and discrete 1D cationic $[CuL(H_2O)_4]_n{^{2n+}}$ polymeric chains, which represents a rare 3D polypseudo-rotaxane MOF from intercalation of 1D and 2D framework. In addition, the luminescent property and electrochemical behavior of compound 1 have been investigated.

Material and rheological properties of (glycidoxypropyl) trimethoxysilane modified colloidal silica coatings

  • Kang Hyun Uk;Park Jung Kook;Kim Sung Hyun
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.175-182
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    • 2004
  • Colloidal coating solution was prepared to enhance the hydrophilic property of the film surface. Water and ethanol were used as the dispersion media and (glycidoxypropyl) trimethoxysilane (GPS) as a binder in the colloidal silica coatings. Ethylene diamine was added to the colloidal silica solution as the curing agent. The colloidal silica solution was regarded as a hard-sphere suspension model with low volume fraction of the silica particles. Rheological properties of the silica suspensions modified with GPS have been investigated as a function of pH and concentration. The acidic solution showed high viscosity change by fast hydrolysis reaction and adsorption of the organic binders on the surface of silica particles. However, the hydrolysis was slow at the basic condition and the binders combined with themselves by condensation. The viscosity change was smallest at pH 7. The viscosity increased with the curing time after adding ethylenediamine, and the increase of viscosity at low pH was higher than that at high pH. The hydrophilic properties of the coating film were investigated by the contact angle of water and film surface. The smallest contact angle was shown under the strong acidic condition of pH 2.

ALMOST-INVERTIBLE SPACES

  • Long, Paul E.;Herrington, Larry L.;Jankovic, Dragan S.
    • Bulletin of the Korean Mathematical Society
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    • v.23 no.2
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    • pp.91-102
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    • 1986
  • A topological space (X,.tau.) is called invertible [7] if for each proper open set U in (X,.tau.) there exists a homoemorphsim h:(X,.tau.).rarw.(X,.tau.) such that h(X-U).contnd.U. Doyle and Hocking [7] and Levine [13], as well as others have investigated properties of invertible spaces. Recently, Crosseley and Hildebrand [5] have introduced the concept of semi-invertibility, which is weaker than that of invertibility, by replacing "homemorphism" in the definition of invertibility with "semihomemorphism", A space (X,.tau.) is said to be semi-invertible if for each proper semi-open set U in (X,.tau.) there exists a semihomemorphism h:(X,.tau.).rarw.(X,.tau.) such that h(X-U).contnd.U. The purpose of the present article is to introduce the class of almost-invertible spaces containing the class of semi-invertible spaces and to investigate its properties. One of the primary concerns will be to determine when a given local property in an almost-invertible space is also a global property. We point out that many of the results obtained can be applied in the cases of semi-invertible spaces and invertible spaces. For example, it is shown that if an invertible space (X,.tau.) has a nonempty open subset U which is, as a subspace, H-closed (resp. lightly compact, pseudocompact, S-closed, Urysohn, Urysohn-closed, extremally disconnected), then so is (X,.tau.).hen so is (X,.tau.).

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A New Adamantane-like Tetranuclear Manganese(III) Complex Based on Flexible Schiff-base Ligand: Synthesis, Crystal Structure and Magnetic Property

  • Zhang, Ran;Ni, Zhong-Hai;Zhang, Li-Fang;Kou, Hui-Zhong
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.1965-1969
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    • 2014
  • A new tetranuclear Mn(III) complex $[Mn^{III}{_4}(sae)_4({\mu}_3-O)({\mu}_{1,1}-N_3)(OH)(H_2O)_2]{\cdot}H_2O$ (1) ($H_2sae$ = 2-salicylideneamino-1-ethanol) has been synthesized by the reaction of $MnCl_2{\cdot}4H_2O$, $H_2sae$ and sodium azide in the mixed solvent of methanol, acetonitrile and water. The X-ray diffraction analysis shows that the four Mn(III) ions in complex 1 have a unique adamantine arrangement, whereas the coordination environment of each Mn(III) ions is different. Magnetic studies indicate that complex 1 manifests antiferromagnetic behaviors. The magnetic susceptibilities of complex 1 have been fitted by two magnetic models based on the suitable analysis of its magnetic structural topology.

Mechanical Property of Ultra Fine Grained Steel Weld by Hybrid Welding (하이브리드 용접에 의한 세립강 용접부의 기계적 성질에 관한 연구)

  • Dong, H.W.;Ahn, Y.S.
    • Journal of Power System Engineering
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    • v.15 no.1
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    • pp.45-50
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    • 2011
  • The effect of Mn and Ti contents in filler wire on the microstructure and mechanical property of weld metal has been investigated after hybrid welding with ultra fine grained (UFG) steel. The microstructure and distribution of alloy compositions at the top region of weld zone were quite different with those at the bottom region after hybrid welding. The bottom region of weld zone contained higher Mn and Ti contents, and consequently the hardness of bottom region was higher than that of top region. With the increase of Mn and Ti contents in filler wire, the volume percent of acicular ferrite in weld metal decreased, and the weld zone showed higher hardness and better impact property.

Fast Integer-Pel Motion Estimation Based on Statistical Property for H.264/AVC (H.264/AVC를 위한 통계 특성 기반 정수 화소 단위 고속 움직임 예측 기법)

  • Noh, Jin-Young;Hong, Min-Cheol
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.37 no.8A
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    • pp.669-678
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    • 2012
  • In this paper, we propose an efficient fast integer-pel motion estimation for H.264/AVC using local statistics of local motion vectors. Using neighboring motion vectors, we define a new statistical property that is used to determine a mode of motion search range of current block. In addition, an adaptive motion search range compensated method that is based on cumulative statistics of previous coded blocks is addressed to solve the problem of the statistical motion search range decision method. Experimental results show that proposed algorithm has the capability to reduce the computational cost over the other methods.

EMPLOYING COMMON LIMIT RANGE PROPERTY WITH VARIANTS OF R-WEAKLY COMMUTING MAPPINGS IN METRIC SPACES

  • CHAUHAN, SUNNY;VUJAKOVIC, JELENA;HAQ, SHAMSUL
    • The Pure and Applied Mathematics
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    • v.22 no.2
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    • pp.127-138
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    • 2015
  • The object of this paper is to emphasize the role of 'common limit range property' and utilize the same with variants of R-weakly commuting mappings for the existence of common fixed point under strict contractive conditions in metric spaces. We also furnish some interesting examples to validate our main result. Our results improve a host of previously known results including the ones contained in Pant [Contractive conditions and common fixed points, Acta Math. Acad. Paedagog. Nyhàzi. (N.S.) 24(2) (2008), 257-266 MR2461637 (2009h:54061)]. In the process, we also derive a fixed point result satisfying $\phi$-contractive condition.

On a Stability Property of Nonlinear Systems with Periodic Inputs Having Slowly Varying Average (주기적인 입력의 평균이 느리게 변하는 비선형 시스템의 안정성)

  • Choi Yong-un;Seo J.H.;Shim Hyungbo
    • Journal of Institute of Control, Robotics and Systems
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    • v.11 no.4
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    • pp.284-289
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    • 2005
  • It is known that, if an equilibrium of a nonlinear system has a stability property when an external input is frozen, then the property is maintained under the input being slowly varying. In this paper, we show that the same stability property is preserved not only under slowly varying input but also under slowly-varying-average input (which is not actually slowly varying but its ‘average’ is slowly varying) The input is assumed to be periodic and to vary sufficiently fast. We prove the claim by the average theory and some previous results on the slowly varying inputs.

A Study on the pH Reduction of Cement Concrete with Various Mixing Conditions (시멘트 콘크리트의 배합조건에 따른 pH 저감에 관한 연구)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.4
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    • pp.79-85
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    • 2008
  • The purpose of this study is to evaluate the mix design of pH reducing cement concrete which can be used for environment-friendly concrete. Cement pastes and concretes are prepared with water-binder ratios and various admixtures such as blast-furnace slag, fly ash and recycled cement, and tested for compressive strength and pH. pH is measured through pore solution expressed from hydrated cement paste by special apparatus. From the test results, regardless of water-binder ratio, The pH of expressed pore solution from hydrated cement paste which is made of ordinary portland cement with blast-furnace slag, fly ash is decreased with increasing of admixtures content, and compressive strength is also slightly improved. The compressive strength of cement paste made of recycled cement which is burnt at $1000^{\circ}C$, for 2 hours is considerably increased compared with that of none-burnt recycled cement due to restoration of hydraulic property, but pH is a little higher. Porous concrete with ordinary portland cement has high pH in the range of 12.22 to 12.59, however, that is reduced to the range of 8.95 to 10.39 by carbonation at the surface of porous concrete. The pH reduction of porous concrete is possible by various admixture addition, however their degrees are very slight. Therefore, to reduce the pH considerably, carbonation method of porous concrete is better in pH reduction methods for plant survival condition of pH of 9.0 or less. In this study, it is apparent that pH for the environment-friendly porous concrete products used in the construction field can be suppressed by this carbonation method and various admixtures addition.

The effect of disease insidence to BaYMV by the physio-chemical property of BaYMV by the physio-chemical property of infected soil.

  • Hyun, Jong-Nae;Hong, Yeon-Kyu;Kim, Hyun-Tae;Park, Kee-Do;Kim, Soon-Chul;Lee, Woon Key
    • Proceedings of the Korean Society of Plant Pathology Conference
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    • 2002.11a
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    • pp.107.2-108
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    • 2002
  • Barley Yellow Mosaic Virus(BaYMV) is responsible for ane of the most improtant disease in malting Barley in Korea. It is transcitted by soil borne fungus, Polymyza graminis To estimate the occurrence pattern of BaYMV by the physio-chemical property of soil collected from farmer's sield, this study was conducted. The rate of didsease occurrence to BaYMV investigated at 19 spots of 10th regions. The sample soil was collected by 20 pots among an ifected field and analyzed th soil characters in 2002. The rate of disease occurrence to BaYMV was about 79%,60%,65% in Sacheon, Kosung and Hadong areas, respectively, which is malting Barley growing regions but Pohang, Yeongduk, Euesung, Gunwee, which are growing Covered Barley doesn't infected BaYMV. The tested of RT-PCR was showed that the BaYMV, BMMV.SBWMV. were identified in Milyang but the others regions was infected only to BaYMV. The physio-chemical property of soil collected from infected soil show various range such as pH(4.98~8.05), EC(0.44~2.7%),OM(1.61~6.85), P2O5958~519), K(0.22~1.82), Ca(2.3~9.7), Mg(0.5~2.6), Na(0.14~0.43) The correlation coefficient between physio-chemical property fo the infected soil and infection rate shows significant to pH at 5% level. Although OM and Ca were high scores, it doesn't significant at 5% but it need to be more study in future.

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