• 한국염색가공학회지
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• 제7권2호
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• pp.17-23
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• 1995

In order to study the dyeing property of acrylic and cotton blends with cationic and reactive dyes, staining on cotton of cationic dyes, stability of cationic dyes, and fastness properties in various conditions were investigated. The restlts obatined from this study are summarized as follows: 1. Cationic oxazine dyes showed good stability in comparison with cationic azo dyes. 2. Staining of cationic dyes on cotton was gradually increased with pH and neutral salt concentration, but decreased with dyeing time and dyeing temperture.

• 한국의류산업학회지
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• 제23권6호
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• pp.844-851
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• 2021

Due to the increase in consumers' interest about well-being, interest in eco-friendly products has been increasing due to the harmful effects of various harmful substances contained in textile products and environmental issues. As a result, natural dyes of less potential risk than synthetic dyes and digital textile printing(DTP) textile products with less environmental pollution are drawing attention. However, due to the lack of evaluation criteria for DTP textile products with natural ink and the nature of many colors are stacked layer by layer for dying, the need for simultaneous analysis is emerging. To evaluate whether the natural dye is derived from natural ingredients, the biocarbon content is analyzed. However, in the case of ink made using natural dyes and DTP textile products using natural ink, it is difficult to analyze the biocarbon content due to the limitation of the presence of a small amount of dye contained therein. In this study, we were shown the possibility of natural derived verification by cross-checking the analytes of natural dyes (Persicaria tinctoria, an indigo dye; Dactylopius coccus, a light red; and Curcum longa L., i.e., turmeric) and natural ink with HPLC-MS/MS. The coefficient of determination was 0.999 or higher, the limit of quantification was 0.647-3.664 ㎍/L and a %RSD of each indicator material was less than 10. Then, the extraction amount of natural dyes for five patterned fabrics was analyzed.

• 한국염색가공학회지
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• 제17권3호
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• pp.1-7
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• 2005

Cationic dyeable polyester(CDP) was produced through melt blending of cationic chips having $2mol\%$ of sodium salt of dimethyl ester of 5-sulfoisophthalic acid(DMS salt) and normal polyester chips in different proportions to obtain yarns having varying amount of comonomer in the fiber. The modified polyesters showed increased moisture regain, decreased viscosity, lower softening point and improved antistatic characteristics, according to the amount of modifier. In dyeing at $100^{\circ}C$ the dyeing rate of cationic dyes with CDP fiber increased slowly than that of disperse dyes. In dyeing at $120^{\circ}C$ cationic dyes reached to equilibrium at 30min and disperse dyes at 10min. Cationic dyes in dyeing of CDP fabric have a better wash fastness compared with disperse dyes, also rubbing fastness of cationic dyes is better than that of disperse dyes. The light fastness of CDP fabric for cationic and disperse dyes is not good. The fastness of 75d/36f CDP fabric is higher than 75d/72f fabric. Solvent wicking fastness of CDP with cationic dyes is better than that of disperse dyes.

• 한국염색가공학회지
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• 제22권1호
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• pp.1-7
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• 2010

The five new red disperse dyes for unmodified pure polypropylene fibers were synthesized. As a coupling component, a di-n-hexyl substituent was used in common, while various substituents were used for the diazo component. The dye having electron donating group at diazo component showed hypsochromic shift compared to the unsubstituted dye, while the dyes having electron withdrawing groups showed bathochromic shift. Owing to their extreme hydrophobicity caused by the di-n-hexyl substituent, all dyes exhibited very high affinity toward pure polypropylene fibers. Fastness to washing was very good for all dyes and fastness to light was good except two purplish red dyes.

• 한국염색가공학회지
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• 제19권2호
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• pp.36-43
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• 2007

Dyeing and fastness properties of a dyeable PP fiber were examined with four different types of disperse dyes. It was found that the dyed PP fiber could be cleared by soaping without using sodium hydrosulphite, and that the heat setting above $140^{\circ}C$ resulted in the melting of the PP fiber. The rates of dyeing and the extents of exhaustion of three primary E type dyes were different with each other, the apparent color strength did not increase with increasing dye concentration, and color fastness to washing was not satisfactory. In the cases of both high wash fastness and high light fastness dyes, the rates of dyeing were slow and the extents of exhaustion were very low. On the other hand, the dyeing rates of three primary S type dyes were similar and the build-up properties were good with good color fastnesses. It might be concluded that the best disperse dyes for the dyeable PP fiber were S type dyes.

• 한국의류산업학회지
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• 제7권3호
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• pp.339-345
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• 2005

It is difficult to dye nylon/viscose rayon mixture fabrics by one-bath one-step dyeing method, because acid dyes and reactive dyes require acidic dyebath for adsorption and alkaline dyebath for fixation respectively. In order to overcome the disadvantage of the conventional two bath two step dyeing method of nylon/viscose rayon mixture fabric, it was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. The pretreated nylon/viscose rayon mixture fabrics produced cationized fabrics that could be dyed with acid dyes and reactive dyes under neutral condition. This study was carried out to investigate dyeing possibilities, surface reflectance spectra and color characteristics of cationized nylon/viscose rayon mixture fabrics with acid dyes and reactive dyes in a non-electrolytic and neutral dyebath by one bath one step dyeing method.

• 한국염색가공학회지
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• 제20권5호
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• pp.14-22
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• 2008

The present paper focuses on the application of commercial acid dyes and wool reactive dyes to casein protein fabric. Nine acid dyes and six wool reactive dyes were compared their dyeing properties as well as color fastness. The exhaustion yields were higher than 80 % which dramatically increased at pH 3. Excellent wash fastness was obtained with metal-complex acid and wool reactive dyes. Both light and rubbing fastness were overall good, but perspiration fastness was comparatively poor.

• 한국염색가공학회지
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• 제21권5호
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• pp.21-26
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• 2009

In order to analyze numerically the hydrophobicity of the new dyes synthesized for unmodified pure polypropylene fibers, the octanol-water partition coefficient (logP), which is one of molecular descriptors representing hydrophobicity of organic compounds, was obtained by a semi-empirical method using Chem3D software. For the dyes of higher logP than around 5, the affinity of the dyes towards unmodified polypropylene fiber was substantial. In contrast to the new dyes for polypropylene, conventional disperse dyes have logP values lower than 5 and exhibited poor affinity.

• 한국의류산업학회지
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• 제3권1호
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• pp.48-52
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• 2001

The study was conducted to find out suitable flame proofing on silk fabrics and to examine closely the flame retardancy effect and the physical properties changes of the silk, which was dyed by natural dyes and synthetic dyes, treated with agent (Diphenylbutylamidophosphate (DPBAP)). The results of the study were as follows: 1) Silk could be treated with DPBAP easily soluble in water by means of simple Pad-Dry-Cure. 2) The add-on of silk fabrics dyed by natural dyes was more than that of silk fabrics dyed by synthetic dyes. 3) The silk fabrics dyed by india ink among natural dyes has more flame retardancy effect in before treating with flame proofing agent than in after treating with it. 4) The physical properties (stiffness and tensile strength) of the silk fabrics treated with flame retardancy agent were little changed.

• 한국염색가공학회지
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• 제28권3호
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• pp.175-182
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• 2016

To investigate dyeing behaviors in accordance with dye structure in cold pad batch dyeing of cotton knit, monochlorotriazine-vinylsulfone bifunctional dyes and monofluorotriazine-vinylsulfone bifunctional dyes were prepared. The spectral property and solubility of the dyes were tested and compared with the imported dyes. In addition, exhaustion behaviors of individual and mixed dye solutions were measured to examine the influence of dye structure on dyeing behavior in cold pad batch dyeing. The substantivity, fixation, migration index and half dyeing time were also calculated for further analysis of dyeing behavior of the prepared dyes. As a result, both dyes exhibited the superior solubilities and satisfactory light absorption properties. Also, monofluorotriazine-vinylsulfone bifunctional dyes showed moderate sensitivity to alkalinity and proper kinetic index values compared with the monochlorotriazine-vinylsulfone bifunctional dyes and the imported dyes. The results indicated monofluorotriazine-vinylsulfone bifunctional structure of the dye is suitable for cold pad batch dyeing.