• Title/Summary/Keyword: ternary system

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Carpet Weaving on the Territory of Kazakhstan as a Reflection of the Traditional Worldview of Nomads

  • Aigul AGELEUOVA
    • Acta Via Serica
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    • v.8 no.1
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    • pp.31-54
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    • 2023
  • The article deals with issues related to the tradition of carpet production on the territory of Kazakhstan where, for the most part, tribes engaged in nomadic livestock raising lived. Analyzing the technological component of this traditional craft, the author focuses on the main factor that influenced carpet weaving along with arts and crafts-the nomadic method of production of the Kazakhs. The study of the ideological component that accompanies the process of making various types of carpets allows us to conclude that it has a sacred meaning and subordination to myth, rite, and ritual. At the mythmaking level, the process of making carpets, like any other activity among nomads, personified the process of creating the world, the marriage of Kok-Tengri (Heaven) and Zher-Su (Earth), and the creation of the Cosmos from Chaos. The process of carpet weaving, as well as the process of making felt, symbolized the act of creation, the marriage of Heaven and Earth, and male and female principles. The study of various types of ornaments that Kazakhs and their ancestors used to decorate carpets allows us to conclude that the ornament applied to carpet products was the bearer of the most valuable information about the mythological worldview of the people. Carpets in their structure reproduced the structure of the Universe, which has a binary, ternary, and quaternary system. The ornament has turned into a kind of coded text, reflecting ideas about the cosmogonic structure of the Universe and an awareness of the harmony of the world. The location of Kazakhstan on the northern routes of the Sogdian Road (Great Silk Road) allowed the spread of various ideas, due to which carpet weaving was influenced by other peoples in technical and stylistic design.

A Study on the Flowability Properties of the High Flowing Self-Compacting Concrete for Members of Bridge Precast (프리캐스트 교량부재용 초유동 자기충전 콘크리트의 유동 특성에 관한 연구)

  • Choi, Yun Wang;Kim, Yong Jic;Kang, Hyun Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.1A
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    • pp.155-163
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    • 2008
  • On the construction site with trends of large scale, high rise and specialization, testing construction of high performance concrete, superior to conventional concrete, is continued to increase. For bridge construction, application of full staging method is gradually decreasing due to noise, dust, and prolonged construction period. Recently, precast construction, which is optimized to urban environment and shorter work period, gains popularity significantly. In bridge structure, overcrowding arrangement of bar is used to ensure its safety. For the manufacturing of overcrowding arrangement of bar, High flowing self-compacting concrete, which is superior to conventional concrete in flowability and compacting property, should be implemented. In this study, the application of blast-furnace slag and fly ash to binary and ternary blended system on the High flowing self-compacting concrete for bridge structure with overcrowding arrangement of bar is evaluated by flowability in accordance with the first class regulations of Japan Society of Civil Engineering (JSCE).

Characteristics of Heavy Metal Oxide Glasses in BaO-GeO2-La2O3-ZnO-Sb2O3 System for Infrared Lens (적외선 렌즈용 BaO-GeO2-La2O3-ZnO-Sb2O3계 중금속 산화물 유리의 특성)

  • Sang-Jin Park;Bok-Hyun Oh;Sang-Jin Lee
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.414-421
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    • 2023
  • Infrared radiation (IR) refers to the region of the electromagnetic radiation spectrum where wavelengths range from about 700 nm to 1 mm. Any object with a temperature above absolute zero (0 K) radiates in the infrared region, and a material that transmits radiant energy in the range of 0.74 to 1.4 um is referred to as a near-infrared optical material. Germanate-based glass is attracting attention as a glass material for infrared optical lenses because of its simple manufacturing process. With the recent development of the glass molding press (GMP) process, thermal imaging cameras using oxide-based infrared lenses can be easily mass-produced, expanding their uses. To improve the mechanical and optical properties of commercial materials consisting of ternary systems, germanate-based heavy metal oxide glasses were prepared using a melt-cooling method. The fabricated samples were evaluated for thermal, structural, and optical properties using DSC, XRD, and XRF, respectively. To derive a composition with high glass stability for lens applications, ZnO and Sb2O3 were substituted at 0, 1, 2, 3, and 4 mol%. The glass with 1 mol% added Sb2O3 was confirmed to have the optimal conditions, with an optical transmittance of 80 % or more, a glass transition temperature of 660 ℃, a refractive index of 1.810, and a Vickers hardness of 558. The possibility of its application as an alternative infrared lens material to existing commercial materials capable of GMP processing was confirmed.

Sustainable SCC with high volume recycled concrete aggregates and SCMs for improved mechanical and environmental performances

  • Zhanggen Guo;Ling Zhou;Qiansen Sun;Zhiwei Gao;Qinglong Miao;Haixia Ding
    • Advances in concrete construction
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    • v.16 no.6
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    • pp.303-316
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    • 2023
  • Using industrial wastes and construction and demolition (C&D) wastes is potentially advantageous for concrete production in terms of sustainability improvement. In this paper, a sustainable Self-Compacting Concrete (SCC) made with industrial wastes and C&D wastes was proposed by considerably replacing natural counterparts with recycled coarse aggregates (RCAs) and supplementary cementitious materials (SCMs) (i.e., Fly ash (FA), ground granulated blast furnace slag (GGBS) and silica fume (SF)). A total of 12 SCC mixes with various RCAs and different combination SCMs were prepared, which comprise binary, ternary and quaternary mixes. The mechanical properties in terms of compressive strength and static elasticity modulus of recycled aggregates (RA-SCC) mixes were determined and analyzed. Microstructural study was implemented to analyze the reason of improvement on mechanical properties. By means of life cycle assessment (LCA) method, the environmental impacts of RA-SCC with various RCAs and SCMs were quantified, analyzed and compared in the system boundary of "cradle-to-gate". In addition, the comparison of LCA results with respect to mechanical properties was conducted. The results demonstrate that the addition of proposed combination SCMs leads to significant improvement in mechanical properties of quaternary RA-SCC mixes with FA, GGBS and SF. Furthermore, quaternary RA-SCC mixes emit lowest environmental burdens without compromising mechanical properties. Thus, using the combination of FA, GGBS and SF as cement substitution to manufacture RA-SCC significantly improves the sustainability of SCC by minimizing the depletion of cement and non-renewable natural resources.

A close look at the influence of praseodymium (III) oxide on the structural, physical, and γ-ray protection capacity of a ternary B2O3-PbO-CdO glass system

  • R.H. Shoeir;M. Afifi;Abdelghaffar S. Dhmees;M.I. Sayyed;K.A. Mahmoud
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.2258-2265
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    • 2024
  • The present investigation aims to study the role of Pr2O3 on the structural, physical, and radiation shielding properties of a dense cadmium lead borate glass. The XRD was used to affirm the glassy amorphous structure of fabricated sample materials. Moreover, the FTIR was used to record the change in the FT-IR spectra due to the addition of Pr2O3 in the wavenumber interval between 400 and 4000 cm-1. The features of glass surfaces and the elemental analyses for the synthesized Pr2O3-reinforced cadmium lead borate glasses were performed using a SEM, supported by an energy-dispersive spectrometer. The γ-ray protection capacity was evaluated using the Monte Carlo method in a wide energy interval ranging between 0.015 and 15 MeV. The linear attenuation coefficient (LAC) at 1 MeV was reduced by a factor of 10 % from 0.372 cm-1 to 0.340 cm-1. The decrease in the LAC values negatively affected the other shielding properties such as half-value thickness and the transmission factor. Although the linear attenuation coefficient is decreased slightly with the partial substitution of CdO by Pr2O3 compound, the fabricated glass samples still have a high shielding capacity compared to the traditional commercial glasses as well as previous similar reported glasses.

Effect of Cu Addition on Oxide Growth of Al-7 mass%Mg Alloy at High Temperature

  • Seong-Ho Ha;Abdul Wahid Shah;Bong-Hwan Kim;Young-Ok Yoon;Hyun-Kyu Lim;Shae K. Kim
    • Archives of Metallurgy and Materials
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    • v.66 no.3
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    • pp.699-702
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    • 2021
  • Effect of Cu addition on oxide growth of Al-7 mass%Mg alloy at high temperature was investigated. As-cast microstructures of Al-7 mass%Mg and Al-7 mass%Mg-1 mass%Cu alloys showed α-Al dendrites and area of secondary particles. The 1 mass%Cu addition into Al-7 mass%Mg alloy formed Mg32(Al, Cu)49 ternary phase with β-Al3Mg2. The total fraction of two Mg-containing phases in Cu-added alloy was higher than the β-Al3Mg2 fraction in Cu-free alloy. From measured weight gains depending on time at 500℃ under an air atmosphere, it was shown that all samples exhibited significant weight gains depending on time. Al-7mass%Mg-1mass%Cu alloy showed the relatively increased oxidation rate when compared with Cu-free alloy. All the oxidized cross-sections throughout the entire oxidation time showed coarse and dark areas regarded as oxides grown from the surface to inside, but bigger oxidized areas were formed in the Al-7mass%Mg-1mass%Cu alloy containing higher fraction of Mg-based phases in the as-cast microstructure. As a result of compositional analysis on the oxide clusters, it was found that the oxide clusters contained Mg-based oxides formed through internal oxidation during a long time exposure to oxidizing environments.

Surfactant Washing of Organics from a Contaminated Site I. Clean Up of Hydrocarbon Contaminated Soils (Surfactant washing에 의한 토양 내의 유기물 제거에 관한 연구 I. 탄화수소로 오염된 토양의 정화)

  • Lim, Jong-Choo
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.357-364
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    • 1997
  • The objective of this study was to find optimum nonionic surfactants for clean up of soils contaminated by hydrocarbon oils. PIT(phase inversion temperature) measurements in ternary systems containing pure hydrocarbons, pure nonionic surfactants, and water were carried out and interfacial tensions were measured as a function of time for n-hexadecane oil drops brought into contact with various mixtures of nonionic surfactant and water. Batch surfactant washing experiments were performed based on the measurement, results of PIT and interfacial tension and the results showed that maximum removal of n-hexadecane occurred at the PIT of the system. For the $C_{12}E_5(C_{12}H_{25}O(CH_2CH_2O)_5H)$ system, maximum n-hexadecane removal of 73.4% occurred at the PIT of $52^{\circ}C$. In contrast, n-hexadecane removal at $25^{\circ}C$ and at $60^{\circ}C$, each corresponding to the conditions of below PIT and above PIT of the system, was found to be 57.1% and 57.0% respectively. The maximum removal of a hydrocarbon at the PIT of a system, where the hydrophilic and hydrophobic properties are balanced, was found to be due to the existence of high oil solubilization into a middle-phase microemulsion and ultralow interfacial of the order of $10^{-2}$ to $10^{-3}$ dyne/cm between middle-phase microemulsion and excess oil phase.

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Identification of C4orf32 as a Novel Type I Endoplasmic Reticulum Resident Membrane Protein (Type I 소포체 목표화 막단백질에 속하는 새로운 C4orf32 막단백질의 동정)

  • Lee, Seung-Hwan;Park, Sang-Won;Lee, Jin-A;Jang, Deok-Jin
    • Journal of Life Science
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    • v.29 no.9
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    • pp.949-954
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    • 2019
  • Membrane topology is a key characteristic of membrane proteins. We previously reported the cloning of the chromosome 4 open-reading frame 32 (C4orf32) gene as a potential membrane protein; however, the cellular localization and membrane topology of C4orf32 was as yet unknown. In this study, we found that green fluorescent protein (GFP) fused to the C-terminus of C4orf32 (C4orf32-GFP) was localized to the endoplasmic reticulum (ER). We applied three tools to identify determinants of C4orf32 topology: protease protection, fluorescence protease protection (FPP), and an inducible system using the ternary complex between FK506 binding protein 12 (FKBP), rapamycin, and the rapamycin-binding domain of mTOR (FRB) (the FRB-rapamycin-FKBP system). Using protease protection and FPP assays, we found that the GFP tag in C4orf32-GFP was localized to the cytoplasmic surface of the ER membrane of HeLa cells. Protease protection and FPP assays are useful and complimentary tools for identifying the topology of GFP fusion membrane proteins. The FRB-rapamycin-FKBP system was also used to study the topology of C4orf32. In the absence of rapamycin, a monomeric red fluorescent protein-FKBP fusion (mRFP-FKBP) and C4orf32-GFP-FRB were localized to the cytoplasm and the ER membrane, respectively. However, in the presence of rapamycin, the mRFP-FKBP was shifted from the cytoplasm to the ER and colocalized with the C4orf32-GFP-FRB. These results indicate that the FRB moiety is facing the cytoplasmic surface of ER membrane. Overall, our results clearly suggest that C4orf32 belongs to the family of type I ER resident membrane proteins.

Development of Solid Self-nanoemulsifying Drug Delivery Systems of Ticagrelor Using Porous Carriers (다공성의 캐리어를 이용한 티카그렐러 함유 고형의 자가 나노유화 약물전달시스템 개발)

  • Choi, Hyung Joo;Kim, Kyeong Soo
    • Journal of Life Science
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    • v.31 no.5
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    • pp.502-510
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    • 2021
  • The objective of this study was to develop a novel ticagrelor-loaded self-nanoemulsifying drug delivery system with an enhanced solubility and dissolution rate. Numerous oils and surfactants were screened, then medium chain triglyceride (MCT) oil and the surfactants polyoxyethylene sorbitan monooleate (Tween 80) and Labrafil M1944CS were selected for the preparation of the ticagrelor-loaded self-nanoemulsifying drug delivery system. A pseudo-ternary phase diagram was constructed to detect the nanoemulsion region. Of the various formulations tested, the liquid SNEDDS, composed of MCT (oil), Tween 80 (surfactant), and Labrafil M1944CS (cosurfactant) at a weight ratio of 20/70/10 produced the smallest emulsion droplet size (around 20.56±0.70 nm). Then, particle size, polydispersity, and zeta potential were measured using drugs containing liquid SNEDDS. The selected ticagrelor-loaded liquid SNEDDS was spray-dried to convert it into a ticagrelor-loaded solid SNEDDS with a suitable inert carrier, such as silicon dioxide, calcium silicate, or magnesium aluminometasilicate. The solid SNEDDS was characterized by scanning electron microscopy, transmission electron microscopy, and in vitro dissolution studies. SEM, PXRD, and DSC results suggested that amorphous ticagrelor was present in the solid SNEDDS. Also, the solid SNEDDS significantly increased the dissolution rate of ticagrelor. In particular, the emulsion particle size and the polydispersity index of the solid SNEDDS using silicon dioxide (SS1) as a carrier was the smallest among the evaluated solid SNEDDS, and the flowability and compressibility result of the SS1 was the most suitable for the manufacturing of solid dosage forms. Therefore, solid SNEDDS using silicon dioxide (SS1) could be a potential nano-sized drug delivery system for the poorly water-soluble drug ticagrelor.

Development of Self-microemulsifying Drug Delivery System for Enhancing the Bioavailability of Atorvastatin

  • Jin, Shun-Ji;Cho, Won-Kyung;Park, Hee-Jun;Cha, Kwang-Ho;Park, Jun-Sung;Koo, Ja-Seong;Wang, Hun-Sik;Kim, Jeong-Soo;Kim, Min-Soo;Hwang, Sung-Joo
    • Journal of Pharmaceutical Investigation
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    • v.41 no.2
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    • pp.103-109
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    • 2011
  • The objective of the study was to prepare self-microeulsifying drug delivery system (SMEDDS) incorporating atorvastatin calcium and evaluate its properties and oral bioavailability. Solubility of atorvastatin in various vehicles was determined. Pseudo-ternary phase diagrams were constructed to identify the good self-emulsification region. The droplet size distributions of the resultant emulsions were determined by dynamic light scattering measurement. The mean droplet size of chosen formulation (20% ethyl oleate, 40% tween-80, 40% Carbitol$^{(R)}$) was $23.4{\pm}1.3$ nm. The SMEDDS incorporating atorvastatin calcium appeared to be associated with better performance in dissolution and pharmacokinetic studies, compared with raw atorvastatin calcium. In dissolution test, the release percentage of atorvastatin from SMEDDS mixture could rapidly reach more than 95% within 3 min. Oral $AUC_{0{\rightarrow}8hr}$ values in SD rats was $1994{\pm}335\;ng{\cdot}hr/mL$, which significantly increased (P<0.05) compared with raw atorvastatin calcium. The SMEDDS formulation was relatively stable when stored at $4^{\circ}C$ during 3 months. Our studies illustrated the potential use of SMEDDS for the delivery of hydrophobic compounds, such as atorvastatin, by the oral route.