• Title/Summary/Keyword: ternary mixture

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Flame Extinguishing Concentrations of Mixed Gaseous Agents (가스계 혼합소화약제의 불꽃소화농도)

  • 김재덕;임종성;이윤우;이윤용
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.34-40
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    • 2001
  • Fire extinguishing efficiency of mixed gaseous agents were investigated by the cup-burner test and predicting by the model of flame extinguishing concentration. The binary mixed agents that tested were carbon dioxide/HFC-23, carbon dioxide/HCFC-22, carbon dioxide/HFC-227ea, carbon dioxide/HFC-125, carbon dioxide/FIC-13I1, Hexafluoropropylene/HFC-23 and ternary mixed agents were carbon dioxide/HFC-23/HFC-l34a, carbon dioxide/HFC-23/HFC-227ea, carbon dioxide/HFC-23/HFC-125. A model which contains the flame extinguishing concentration and composition of pure components predicted the flame extinguishing concentration of mixture well. This model was superior when each component of the mixture exhibit physical fire extinguishing performance.

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A Study on Explosive Limits of Flammable Materials - Explosive Limits of Ternary System by Means of Solution Thermodynamics and MRSM Model - (가연성물질의 폭발한계에 관한 연구 - 용액열역학 및 MRSM 모델에 의한 3성분계 폭발한계 -)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.91-97
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    • 2005
  • The research on the explosive limits is one of fundamental fields of combustion process, and information on the explosive limits of mixture of fuel and oxidant, with or without additives, is very important for the prevention in industrial fire and explosion accidents. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Batten, Le Chatelier and MRSM(modified response surface methodology) model. In this study, the reference values of lower explosive limits(LEL) of the ethanol+toluene+ethylacetate system were compared with the calculated values by using the solution thermodynamics and the MRSM model, respectively. The values calculated by the proposed equations were a good agreement with literature data within a few percent. By means of this methodology, it is possible to evaluate reliability of experimental data of the lower explosive limits of the flammable mixtures. Also, from given results, it is possible to predict explosive limits of the other flammable liquid mixtures used in the chemical process by the use of the proposed equations.

Synthesis of Cordierite and Preparation of Refractory Setter from Domestic Raw Materials (Cordierite의 합성 및 내화갑제조에 관한 연구)

  • 지응업;최상욱;김광호
    • Journal of the Korean Ceramic Society
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    • v.12 no.4
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    • pp.19-28
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    • 1975
  • In order to obtain the superior refractory setter having better spalling resistance, cordierite was synthesized from domestic raw materials. Raw mixtures were fired between 125$0^{\circ}C$ and 140$0^{\circ}C$, and qualitative determination of crytallization was investigated by x-ray diffraction analysis. The results obtained are as follows; 1) The optimum batch composition of synthesized cordierite is 80.5% of Hadong kaolin (pink), 14% of Kyulsung tromolite talc and 5.5% of magnesia clinker, and the firing temperature is 1375$^{\circ}C$. 2) The composition of the refractory setter which exhibits the best values for the thermal properties is 40% of synthesized cordierite, 30% of kaolin chamotte(contains more than 60% of mullite), and 30% of Japanese clay. 3) The optimum particle size distribution of ternary mixture consists of 50% of coarse articles (3.327-1.168mm), 25% of intermediate particles (1.168-0.208mm) and 25% of fine particles (0.208-0.000mm).

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Thermal Decomposition Characteristics on Sodium Azide and Metallic Oxide Mixtures (나트륨 아지드와 금속산화물과의 혼합물에 대한 열분해 특성)

  • 이내우;최재욱;박광수;설수덕;왕석주
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.106-113
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    • 1997
  • The thermal characteristics of two binary mixtures by sodium azide/manganese dioxide and ferric oxide, two ternary mixtures by sodium azide/silicon dioxide/manganese dioxide and ferric oxide were studied to obtain the basic data of gas-generating agents for air bags. The thermal reaction for all mixtures started at about $420^{\circ}C$, but the temperature at which the reaction rate reached a maximum was different with the states of samples. According to reaction results, nitrogen, nitrogen oxide and nitrogen dioxide were detected by GC-MS and so many kinds of new chemicals from sodium azide and metal oxide mixtures by XRD. NMS is considered as most stable and reasonable mixture for this types of gas-generating agents.

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Chromatographic Separation of Maltopentaose from Maltooligosaccharides

  • Lee, Jae-Wook;Kwon, Tae-Ouk;Moon, Il-Shik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.1
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    • pp.47-53
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    • 2003
  • An experimental study on the chromatographic separation of maltopentaose from a mixture, including glucose, maltose, maltotriose, and maltopentaose, was carried out in a nonionic polymeric sorbent column while varying the operating conditions, such as the solution pH, buffer contents, and isopropyl alcohol (1PA) concentration. Unlike the pH and buffer contents, the IPA concentration had a Significant impact on the single component chromatograms for maltopentaose. The retention times of the maltooligosaccharides with the nonionic polymeric sorbent Sp207 were in the following order: glucose < maltose < maltotriose < maltopentaose. From the experimental binary, ternary, and quaternary chromatograms, gradient chromatographic separation with a changing IPA concentration as a function of time was required to obtain high-purity maltopentaose and reduce the elution time.

Reduction of Temporal Image Sticking in AC Plasma Display Panels through the Use of High He Contents

  • Park, Choon-Sang;Kim, Sun-Ho;Kim, Jae-Hyun;Tae, Heung-Sik
    • Journal of Information Display
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    • v.10 no.4
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    • pp.195-201
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    • 2009
  • The temporal dark- and bright-image sticking phenomena were examined relative to the He contents under 11% Xe content in the 50-in HD and FHD AC-PDPs with a ternary gas mixture (Xe-He-Ne). To compare the temporal dark- and bright-image sticking phenomena under various He contents, the differences in the disappearing time, display luminance, perceived luminance, infrared emission, color coordinate, color temperature, and discharge current before and after discharge were measured under 0, 35, 50, and 70% He contents. It was found that temporal dark- and bright-image sticking were reduced in proportion to the increase in He %. Thus, a high He content contributes to the reduction of temporal dark- and bright-image sticking.

Finite Element Analysis of Combustion Reaction on Iron and Metal Oxides Interface (Fe-금속 산화물 계면에서 연소반응의 유한 요소해석)

  • Gu, Mun-Seon;Choe, Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.118.2-118.2
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    • 2017
  • Combustion behavior of Fe, CuO, NiO, ZnO and $Fe_2O_3$ powder mixture was carried out by finite element method (FEM) to understand a reaction at iron and metal oxide interface. The FEM was done by using ANSYS Fluent 17.0. Initial and boundary conditions are 1 atmosphere, room temperature, 0.1MPa of oxygen partial pressure, $T_{S1}=1127^{\circ}C$, $T_{S2}=327^{\circ}C$ for a cylindrical shape specimen with dia. $35{\times}80$ [mm]. The maximum combustion temperature is $1537^{\circ}C$ for the condition of conduction, convection and radiation. The combustion temperature and rate are about $847^{\circ}C$ and 3.9mm/sec, respectively. The combustion wave is enough to make ternary ferrite phase like $CuNiZnFe_2O_3$.

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Determination of Mono- and Oligosaccharides Derivatized with p-Aminobenzoic Ethyl Ester by Reverse Phase HPLC

  • Kwon, Hyokjoon;Kim, Joon
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.859-864
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    • 1995
  • Mono- and oligosaccharides are derivatized with p-aminobenzoic ethyl ester (ABEE), strongly absorbs UV light at 254 nm, in the presence of sodium cyanoborohydride. C18-bonded silica column is used for the separation of sugar-ABEE derivatives in an isocratic mode. RP-HPLC conditions are optimized by using ternary mixture as mobile phase and $45^{\circ}C$ as a column temperature. Sugar-ABEE derivatives are separated well within a short run time (ca. 25 min) by reverse-phase partition chromatographic mode. The ($1{\rightarrow}6$) linkage type of dihexose-ABEE derivatives has shorter retention time than ($1{\rightarrow}4$)-linkage type. After acid hydrolysis of glycoproteins with 2M trifluoroacetic acid, monosaccharide composition and contents are determined. This procedure is very useful for the simultaneous analysis of neutral and amino sugars in a single chromatographic step using RP-HPLC without reacetylation of deacetylated amino sugars, which are produced by acid hydrolysis.

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Approximate Nonrandom Two-Fluid Lattice-Hole Theory. Thermodynamic Properties of Real Mixtures

  • 유기풍;신훈용;이철수
    • Bulletin of the Korean Chemical Society
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    • v.18 no.8
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    • pp.841-850
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    • 1997
  • A simple molecular theory of mixtures is formulated based on the nonrandom two-fluid lattice-hole theory of fluids. The model is applicable to mixtures over a density range from zero to liquid density. Pure fluids can be completely characterized with only two molecular parameters and an additional binary interaction energy is required for a binary mixture. The thermodynamic properties of ternary and higher order mixtures are completely defined in terms of the pure fluid parameters and the binary interaction energies. The Quantitative prediction of vapor-liquid, and solid-vapor equilibria of various mixtures are demonstrated. The model is useful, in particular, for mixtures whose molecules differ greatly in size. For real mixtures, satisfactory agreements are resulted from experiment. Also, the equation of state (EOS) is characterized well, even the liquid-liquid equilibria behaviors of organic mixtures and polymer solutions with a temperature-dependent binary interaction energy parameter.

Onset of Marangoni Convection in a Ternary Mixture with Surfactant (계면활성제가 포함된 삼성분계 해석을 통한 마란고니 대류 발생 연구)

  • 김제익;강용태;최창균
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.11
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    • pp.964-969
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    • 2003
  • The objective of this study is to investigate the effect of surfactant on the onset of Marangoni convection adapting a non-linear surface equation of state. The surface tension gradient with respect to the absorbate concentration, ${\gamma}$, is linearly related to the surface concentration of a surfactant with a coeffcient $x_{A}$. The numerical results show that the role of the initial surfactant concentration to Marangoni instability changes from the stabilizer to the destabilizer depending on the change of the sign of $x_{A}$ from negative to positive. It is concluded that for $x_{A}$>0 there is a critical modified Marangoni number of surfactant $M_{Ac}$ $^{*}$ above which liquid layer is always unstable against long wave disturbances.rbances.