• Title/Summary/Keyword: temperature limit

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Effect of CaO and Hot Rolling on the High Temperature Oxidation of Magnesium Alloys (CaO 첨가와 열간압연이 마그네슘 합금의 고온산화에 미치는 영향)

  • Xu, Chunyu;Trung, Trinh Van;Won, Sung-Bin;Lee, Dong-Bok
    • Journal of Surface Science and Engineering
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    • v.45 no.4
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    • pp.155-161
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    • 2012
  • Magnesium alloys of AZ31, AZ31 + (0.5, 1, 1.5)wt.% CaO were cast, hot rolled, and oxidized between 450 and $650^{\circ}C$ in atmospheric air. The added CaO enabled to cast the AZ31 alloy in air. It decomposed and precipitated along the grain boundaries of the AZ31 alloy as $Al_2Ca$. The more the amount of CaO was, the more $Al_2Ca$ formed. The oxidation limit was about $450^{\circ}C$ for the AZ31 alloy. But, It increased to $650^{\circ}C$ in the CaO-added alloys. Hot rolling destroyed the precipitates that formed along the grain boundaries of the AZ31 alloy. During oxidation, MgO oxide scales that incorporated CaO formed at the outer surface of the formed oxide layer.

Voltammetric Determination of Cobalt(Ⅱ) Using Carbon Paste Electrodes Modified with 1-(2-Pyridylazo)-2-naphthol

  • 배준웅;박유철;이상학;전우성;장혜영
    • Bulletin of the Korean Chemical Society
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    • v.17 no.11
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    • pp.995-999
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    • 1996
  • A method for the determination of cobalt(Ⅱ) by differential pulse voltammetry using a carbon paste electrode constructed by incorporating 1-(2-pyridylazo)-2-naphthol(PAN) into a conventional carbon paste mixture composed of graphite powder and Nujol oil has been developed. Several influencing factors for the determination of cobalt(Ⅱ) were studied in detail and the optimum analytical conditions were found to be as follows: pH, 4.6; composition of electrode, 20%; temperature of deposition, 43 ℃; time of preconcentration, 15 min. Regeneration of the electrode surface for the continuous uses of the electrode was achieved by exposing the carbon paste electrode to an acidic solution. Response of the electrode was reproducible for the uses of five times and the relative standard deviations were 6.7 and 4.6% for 2.0×10-5 M and 4.0×10-6 M cobalt(Ⅱ), respectively. The calibration curve for cobalt(Ⅱ) obtained by differential pulse voltammetry was divided into two linear ranges of 1.7× 10-6-1.3×10-4 M and 2.0×10-7-8.0×10-7 M. The detection limit was estimated to be 1.3×10-7 M. The effects of coexisting ions were also investigated to test the applicability of the proposed method to the determination of cobalt(Ⅱ) in real samples.

Investigation of Terahertz Generation from Bulk and Periodically Poled LiTaO3 Crystal with a Cherenkov Phase Matching Scheme

  • Li, Zhongyang;Bing, Pibin;Yuan, Sheng;Xu, Degang;Yao, Jianquan
    • Journal of the Optical Society of Korea
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    • v.19 no.3
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    • pp.297-302
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    • 2015
  • Terahertz (THz) wave generation from bulk and periodically poled $LiTaO_3$ (PPLT) with a Cherenkov phase matching scheme is numerically investigated. It is shown that by using the crystal birefringence of bulk $LiTaO_3$ and a grating vector of PPLT, THz waves can be efficiently generated by difference frequency generation (DFG) with a Cherenkov phase matching scheme. The frequency tuning characteristics of the THz wave via varying wavelength of difference frequency waves, phase matching angle, poling period of PPLT and working temperature are theoretically analyzed. The parametric gain coefficient in the low-loss limit and the absorption coefficient of the THz wave during the DFG process in the vicinity of polariton resonances are numerically analyzed. A THz wave can be efficiently generated by utilizing the giant second order nonlinearities of $LiTaO_3$ in the vicinity of polariton resonances.

Improved Fluorescent Determination Method of Cellular Sphingoid Bases in High-performance Liquid Chromatography

  • Yoon, Hong-Tak;Yoo, Hwan-Soo;Shin, Bum-Kyu;Lee, Woo-Jin;Kim, Hwan-Mook;Hong, Seon-Pyo;Moon, Dong-Cheul;Lee, Yong-Moon
    • Archives of Pharmacal Research
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    • v.22 no.3
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    • pp.294-299
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    • 1999
  • Precolumn orthophthaldehyde (OPA) labeling method of sphingoid bases, sphingosine and sphinganine, was investigated to obtain high fluorescent detectability. In order to improve the fluorescent yield, we investigated the optimal solubility of sphingoid bases for five pre-incubation solvents by incorporating the heating procedure before OPA derivatization. The pre-incubation in ethanol prominently increased the fluorescent peak height of OPA derivative for each sphingoid bases in high performance liquid chromatography. About tenfold increase of detectability was archived by pre-incubating lipid extracts pellets in ethanol at $60^{\circ}C$ for 30 min. Optimal derivatization was performed in 30 min at ambient temperature and the fluorescent intensity of OPA derivative was stable for two weeks at $4^{\circ}C$. The detection limit of sphingosine was 0.1 pmol as injected amount. This method was applied to the determination of cellular sphingosine and sphinganine in various human lung cancer cells. This OPA procedure was prospective to be useful for quantitating the amount of sphingoid bases in other cancer cells.

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IoT Basic Study on Development of Duct Burner Integrated with SCR Catalyst (SCR 촉매 일체형 덕트 버너 개발에 대한 IoT 기초연구)

  • Jang, Sung-Cheol;Shim, Yo-Seop
    • Journal of Internet of Things and Convergence
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    • v.7 no.3
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    • pp.75-80
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    • 2021
  • Since the optimization of the diesel engine for the ship cannot satisfy the NOx emission limit by the method of reducing the NOx emission, it is necessary to reduce the NOx by post-processing the exhaust gas. In this study, we will review the feasibility of designing a binary nozzle and mixing chamber duct for effectively converting the number of elements into NH3 in the oil burner for the SCR catalyst unit integrated duct in the ship under development through the computational heat flow analysis for the velocity distribution and temperature distribution.

Uniaxial fatigue, creep and stress-strain responses of steel 30CrNiMo8

  • Brnic, Josip;Brcic, Marino;Krscanski, Sanjin;Lanc, Domagoj;Chen, Sijie
    • Steel and Composite Structures
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    • v.31 no.4
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    • pp.409-417
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    • 2019
  • The choice of individual material for industrial application is primarily based on knowledge of its behavior in similar applications and similar environmental conditions. Contemporary design implies knowledge of material behavior and knowledge in the area of structural analysis supported by large capacity computers. Bearing this in mind, this paper presents and analyzes the experimental results related to the mechanical properties of the material considered (30CrNiMo8/1.6580/AISI 4340) at different temperatures as well as its creep and fatigue behavior. All experimental tests were carried out as uniaxial tests. The test results related to the mechanical properties are presented in the form of engineering stress-strain diagrams. The results related to the creep behavior of the material are shown in the form of creep curves, while the fatigue of the material is shown in the form of stress - life (S - N) diagram. Based on these experimental results, the values of the following properties are determined: ultimate tensile strength (${\sigma}_{m,20}=696MPa$), yield strength (${\sigma}_{0.2,20}=355.5MPa$), modulus of elasticity ($E_{,20}=217GPa$) and fatigue limit (${\sigma}_{f,20,R=-1}=280.4MPa$). Results related to fatigue tests were obtained at room temperature and stress ratio R = -1.

Flow Characteristics Analysis for the Chemical Decontamination of the Kori-1 Nuclear Power Plant

  • Cho, Seo-Yeon;Kim, ByongSup;Bang, Youngsuk;Kim, KeonYeop
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.1
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    • pp.51-58
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    • 2021
  • Chemical decontamination of primary systems in a nuclear power plant (NPP) prior to commencing the main decommissioning activities is required to reduce radiation exposure during its process. The entire process is repeated until the desired decontamination factor is obtained. To achieve improved decontamination factors over a shorter time with fewer cycles, the appropriate flow characteristics are required. In addition, to prepare an operating procedure that is adaptable to various conditions and situations, the transient analysis results would be required for operator action and system impact assessment. In this study, the flow characteristics in the steady-state and transient conditions for the chemical decontamination operations of the Kori-1 NPP were analyzed and compared via the MARS-KS code simulation. Loss of residual heat removal (RHR) and steam generator tube rupture (SGTR) simulations were conducted for the postulated abnormal events. Loss of RHR results showed the reactor coolant system (RCS) temperature increase, which can damage the reactor coolant pump (RCP)s by its cavitation. The SGTR results indicated a void formation in the RCS interior by the decrease in pressurizer (PZR) pressure, which can cause surface exposure and tripping of the RCPs unless proper actions are taken before the required pressure limit is achieved.

EMC/LVD Compatibility Evaluation of ITER AC/DC Converter Subrack by EN 61000 and IEC 61010 (ITER AC/DC Converter 서브랙의 EN 61000 및 IEC 61010에 의한 EMC/LVD 시험평가)

  • Shin, Hyun-Kook;Oh, Jong-Seok;Song, In-Ho;Suh, Jae-Hak;Choi, Jung-Wan
    • The Transactions of the Korean Institute of Power Electronics
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    • v.26 no.3
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    • pp.222-226
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    • 2021
  • To comply with CE marking requirements, the electromagnetic compatibility (EMC) and low-voltage directive (LVD) tests are conducted on the sub-racks of International Thermonuclear Experimental Reactor (ITER) AC/DC converters and bypass switches. The EMC tests consist of a series of tests, including the electromagnetic interference test, the electromagnetic field immunity test, and the rapid transient burst immunity test. In the LVD test, the electric shock protection test, the xcessive temperature limit and heat resistance of equipment tests, and the fire spread prevention test are performed. This work presents and reviews the European Directive for EMC/LVD and introduces the methods of EMC and LVD tests for the sub-racks of AC/DC converters and bypass switches. It also evaluates the test method and results to meet the European Directive requirements for CE marking. The sub-racks of ITER AC/DC converters and bypass switches successfully pass the EMC and LVD tests.

Laboratory evaluation of roller compacted concrete containing RAP

  • Ahmadi, Amin;Gogheri, Mohammad K.;Adresi, Mostafa;Amoosoltani, Ershad
    • Advances in concrete construction
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    • v.10 no.6
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    • pp.489-498
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    • 2020
  • This paper investigates mechanical properties of roller compacted concrete (RCC) involving reclaimed asphalt pavement (RAP). In this way, a set of 276 cylindrical RCC specimens were prepared with different RAP sizes (i.e., fine, coarse & total) at various ratios (i.e., 10%, 20%, and 40%). Results reveal that incorporation of RAP decreases unconfined compressive strength (UCS), modulus of elasticity (E), and indirect tensile (IDT) strength of RCC. For each RAP size, a regression model was used to maximize RAP content while satisfying the UCS lower limit (27.6 Mpa) mentioned by ACI as a minimum requirement for RCC used in pavement construction. Moreover, UCS of RAP incorporated mixes, dissimilar to that of control mixes, was found to be sensitive and insensitive to the testing temperature and curing time after 7 days, respectively. The results also demonstrate that the higher amounts of RAP, the more flexibility in RCC is. This issue was also proved by the results of modulus of elasticity test. In addition, the toughness index (TI) shows that increase in RAP content leads to up to 43% increase in energy absorbance capacity of RCC.

A Study on LED with Small Form Factor Suitable for Green A of Night Vision Imaging System (야간 투시 영상시스템의 Green A에 적합한 작은 형태인자를 가진 LED에 관한 연구)

  • Kim, Tae Hoon;Yu, Chang Han;Yoon, Hyeon Ju;Kim, Min Pyung;Yoon, Ho Shin
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.4
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    • pp.62-67
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    • 2021
  • In this study, we have successfully developed an unique NVIS Green A compatible LED by combining two technologies. One is white LED made with a black EMC (epoxy molding compound) lead frame. The other is NVIS Green A filter that shields the near infrared region made in the film method. The form factor of the developed NVIS Green A compatible LED was 2.0 × 2.0 × 0.95 mm. And it is possible to satisfy NVIS radiance and color limit specified in MIL-STD-3009 by controlling the concentration of Green A dye and the thickness of the NVIS filter as well as adjusting of color temperature of the white LED. From these results, we are expected that the developed NVIS Green A suitable LED is a promising solution for the weight reduction and the cost reduction of avionic applications.