• Title/Summary/Keyword: temperature limit

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Fundamental study on combustion characteristics of methanol fuel in a constant volume chamber (정적연소기를 사용한 메탄올의 연소특성에 관한 연구)

  • 이태원;이중순;정성식;하종률
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.2
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    • pp.389-396
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    • 1994
  • It is very important to clarify the ignition and flame propagation processes of methanol fuel in the Spark-ignition engine. High speed Schlieren photography and pressure trace analyses were used to study on combustion characteristics of methanol fuel in a constant volume chamber. Methanol-air mixtures equivalence rations from lean limit to 1.4 were ignited at initial pressure (0.1, 0.3, 0.5 MPa), temperature (313 343, 373 K) and ignition energy (40, 180 mJ). As the result of this study, we verified the characteristics such as ignition delay, effective thermal efficiency, flame propagation velocity, lean limit, ignitability and combustion duration. Obatained results are as follows. (1) The time to 10% reach of maximum pressure was 40-50% of the total combustion duration for this experimental condition hardly affected by equivalence ratio. (2) The Effective thermal efficiency, as calculated from maximum pressure was the highest when the mixture was slightly lean $({\phi} 0.8-0.9)$ and maximum pressure was the highest when the mixiture was slightly rich $({\phi} 1.2-1.2).$

Additive Coating of BaTiO3 Powder using Sol Coating Method II - Additive Coating Process using BaTiO3 Sol Added by Mg, Ca, Mn (졸 코팅 법을 이용한 BaTiO3 분체의 첨가제 코팅 II - Mg, Ca, Mn 이 첨가된 BaTiO3 졸을 이용한 첨가제 코팅 공정)

  • 신효순
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.960-966
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    • 2004
  • On the bases of the results from "Additive Coating of BaTiO$_3$ Powder using Sol Coating Method I", experimental condition was defined. Representative additives for BaTiO$_3$, that is to say, Mg, Ca and Mn were experimented. The sources of the metal ion were used by organometal complex. As added it, the stability of BaTiO$_3$ sol was evaluated. Mg and Ca were stable, however, The solubility limit of Mn-ATH was 0.05 mol ratio in Mn-ATH/sol. The solubility limit of Mg ion in BaTiO$_3$ was lower than 2 mol%. From the x Ray diffraction patterns, lattice parameters were different with temperature and additives, because the solubility of metal ion was varied in BaTiO$_3$. The dielectric constant of BaTiO$_3$ powders which coated with the 1.5 mol% Mg and calcined at 1200$^{\circ}C$ was increased with 20%.

The Effects of Injector and Swirler on the Flame Stability in a Model Combustor (모델연소기에서의 화염 안정화에 대한 분사기와 선회기의 영향)

  • Park, Seung-Hun;Lee, Dong-Hun;Bae, Choong-Sik
    • Journal of the Korean Society of Combustion
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    • v.3 no.2
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    • pp.13-27
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    • 1998
  • The optimization of frontal device including fuel nozzle and swirler is required to secure the mixing of fuel and air and the combustion stability leading the reduction of pollutant emissions and the increase of combustion efficiency in gas turbine combustor. The effects of injection nozzle and swirler on the flow field, spray characteristics and consequently the combustion stability, were experimentally investigated by measuring the velocity field, droplet sizes of fuel spray, lean combustion limit and the temperature field in the main combustion region. Flow fields and spray characteristics were measured with APV(Adaptive Phase Doppler Velocimetry) under atmospheric condition using kerosine fuel. Temperatures were measured by Pt-Pt13%Rh, R-type thermocouple which was 0.2mm thick. Spray and flame was visualized by ICCD(Intensified Charge Coupled Device) camera. It was found that the dual swirler resulted in the biggest recirculation zone with the highest reverse flow velocity at the central region, which lead the most stable combustion. The various combustion characteristics were observed as a function of the geometries of injector and swirler, that gave a tip for the better design of gas turbine combustor.

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Characterization of amylopectins isolated from dry and moist type sweet potato starch (분질 및 점질 고구마 전분의 아밀로펙틴 특성)

  • Kim, Sung-Ran;Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.34 no.1
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    • pp.26-31
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    • 1991
  • The physicochemical properties of starches from dry(Suwon 147) and moist type(Hwangmi) sweet potato were investigated and molecular structural properties of their amylopectins were also studied by gel chromatography. Suwon 147 starch bad lower swelling power and higher gelatinization temperature than Hwangmi starch. $\beta-Amylolysis\;limit(%)$ of Suwon 147 and Hwangmi amylopectin were 57.6% and 57.0%, respectively. Average unit chain length of amylopectins were 24.8 glucose units for Suwon 147 and 21.9 for Hwangmi. The elution profiles by Sephadex G-50 after debranched amylopectins of the two starches were similar but DPs of each peak were different.

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Efficient Removal of Arsenic Using Magnetic Multi-Granule Nanoclusters

  • Lee, Seung-Ho;Cha, Jinmyung;Sim, Kyunjong;Lee, Jin-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.605-609
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    • 2014
  • Magnetic multi-granule nanoclusters (MGNCs) were investigated as an inexpensive means to effectively remove arsenic from aqueous environment, particularly groundwater sources consumed by humans. Various size MGNCs were examined to determine both their capacity and efficiency for arsenic adsorption for different initial arsenic concentrations. The MGNCs showed highly efficient arsenic adsorption characteristics, thereby meeting the allowable safety limit of $10{\mu}g/L$ (ppb), prescribed by the World Health Organization (WHO), and confirming that 0.4 g and 0.6 g of MGNCs were sufficient to remove 0.5 mg/L and 1.0 mg/L of arsenate ($AsO_4{^{3-}}$) from water, respectively. Adsorption isotherm models for the MGNCs were used to estimate the adsorption parameters. They showed similar parameters for both the Langmuir and Sips models, confirming that the adsorption process in this work was active at a region of low arsenic concentration. The actual efficiency of arsenate removal was then tested against 1 L of artificial arsenic-contaminated groundwater with an arsenic concentration of 0.6 mg/L in the presence of competing ions. In this case, only 1.0 g of 100 nm MGNCs was sufficient to reduce the arsenic concentrations to below the WHO permissible safety limit for drinking water, without adjusting the pH or temperature, which is highly advantageous for practical field applications.

Appropriateness of MSDS by Means of the Measurement of Combustible Properties of Anisole (아니솔의 연소특성치의 측정에 의한 MSDS의 적정성)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.29 no.2
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    • pp.20-24
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    • 2015
  • For the safe handling of anisole, this study was investigated the explosion limits of anisole in the reference data. The flash points and auto-ignition temperatures (AITs) by ignition delay time were experimented. The lower flash points of Anisole by using closed-cup tester were experimented in $39^{\circ}C$ and $42^{\circ}C$. The lower flash points of Anisole by using open cup tester were experimented in $50^{\circ}C$ and $54^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for Anisole. The AIT of Anisole was experimented as $390^{\circ}C$. The lower explosion limit (LEL) by the measured the lower flash point for Anisole were calculated as 1.07 Vol%.

The Measurement of Fire and Explosion Properties of n-Hexadecane (노말헥사데칸의 화재 및 폭발 특성치의 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.29 no.3
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    • pp.39-45
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    • 2014
  • For the safe handling of n-hexadecane, the lower flash points and the upper flash point, fire point, AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-hexadecane were calculated. The lower flash points of n-hexadecane by using the Setaflash and the Pensky-Martens closed testers were measured $128^{\circ}C$ and $126^{\circ}C$, respectively. The lower flash points of the Tag and the Cleveland open cup testers were measured $136^{\circ}C$ and $132^{\circ}C$, respectively. The fire points of the Tag and the Cleveland open cup testers were measured $144^{\circ}C$. respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-hexadecane. The experimental AIT of n-hexadecane was $200^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $128^{\circ}C$ and upper flash point $180^{\circ}C$ for n-hexadecane were 0.42 Vol.% and 4.70 Vol.%.

Determination of Ag(Ⅰ) Ion at a Modified Carbon Paste Electrode Containing N,N'-Diphenyl Oxamide

  • Won, Mi-Sook;Yeom, Jeong-Sik;Yoon, Jang-Hee;Jeong, Euh-Duck;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.24 no.7
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    • pp.948-952
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    • 2003
  • New approach for the determination of Ag(I) ion was performed by using a carbon paste electrode (CPE) containing N,N'-Diphenyl oxamide (DPO) with anodic stripping voltammetry. The CMEs have been prepared by making carbon paste mixtures containing an appropriate amount of DPO salt coated onto graphite particles to analyze trace metal ions via complexation followed by stripping voltammetry. Various experimental parameters affecting the response, such as pH, deposition time, temperature, and electrode composition, were carefully optimized. Using differential pulse anodic stripping voltammetry, the logarithmic linear response range for the Ag(I) ion was 1.0 × $10^{-7}$ - 5.0 × $10^{-9}$ M at the deposition time of 10 min, with the detection limit was 7.0 × $10^{-10}$ M. The detection limit adopted from anodic stripping differential pulse voltammetry was 7.0 × $10^{-10}$ M for silver and the relative standard deviation was ± 3.2% at a 5.0 × $10^{-8}$ M of Ag(I) ion (n = 7). The proposed electrode shows a very good selectivity for Ag(I) in a standard solution containing several metals at optimized conditions.

Research on Silicon Nanowire Transistors for Future Wearable Electronic Systems (차세대 웨어러블 전자시스템용 실리콘 나노선 트랜지스터 연구)

  • Im, Kyeungmin;Kim, Minsuk;Kim, Yoonjoong;Lim, Doohyeok;Kim, Sangsig
    • Vacuum Magazine
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    • v.3 no.3
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    • pp.15-18
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    • 2016
  • In future wearable electronic systems, 3-dimensional (3D) devices have attracted much attention due to their high density integration and low-power functionality. Among 3D devices, gate-all-around (GAA) nanowire transistor provides superior gate controllability, resulting in suppressing short channel effect and other drawbacks in 2D metal-oxide-semiconductor field-effect transistor (MOSFET). Silicon nanowires (SiNWs) are the most promising building block for GAA structure device due to their compatibility with the current Si-based ultra large scale integration (ULSI) technology. Moreover, the theoretical limit for subthreshold swing (SS) of MOSFET is 60 mV/dec at room temperature, which causes the increase in Ioff current. To overcome theoretical limit for the SS, it is crucial that research into new types of device concepts should be performed. In our present studies, we have experimentally demonstrated feedback FET (FBFET) and tunnel FET (TFET) with sub-60 mV/dec based on SiNWs. Also, we fabricated SiNW based complementary TFET (c-TFET) and SiNW complementary metal-oxide-semiconductor (CMOS) inverter. Our research demonstrates the promising potential of SiNW electronic devices for future wearable electronic systems.

Reliability studies on RC beams exposed to fire based on IS456:2000 design methods

  • Balaji, Aneesha;Aathira, M.S.;Pillai, T.M. Madhavan;Nagarajan, Praveen
    • Structural Engineering and Mechanics
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    • v.59 no.5
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    • pp.853-866
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    • 2016
  • This paper examines a methodology for computing the probability of structural failure of reinforced concrete beams subjected to fire. The significant load variables considered are dead load, sustained live load and fire temperature. Resistance is expressed in terms of moment capacity with random variables taken as yield strength of steel, concrete class (or grade of concrete), beam width and depth. The flexural capacity is determined based on the design equations recommended in Indian standard IS456:2000. Simplified method named $500^{\circ}C$ isotherm method detailed in Eurocode 2 is incorporated for fire design. A transient thermal analysis is conducted using finite element software ANSYS$^{(R)}$ Release15. Reliability is evaluated from the initial state to 4h of fire exposure based on the first order reliability method (FORM). A procedure is coded in MATLAB for finding the reliability index. This procedure is validated with available literature. The effect of various parameters like effective cover, yield strength of steel, grade of concrete, distribution of reinforcement bars and aggregate type on reliability indices are studied. Parameters like effective cover of concrete, yield strength of steel has a significant effect on reliability of beams. Different failure modes like limit state of flexure and limit state of shear are checked.