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노말헥사데칸의 화재 및 폭발 특성치의 측정

The Measurement of Fire and Explosion Properties of n-Hexadecane

  • 하동명 (세명대학교 보건안전공학과)
  • Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University)
  • 투고 : 2014.02.17
  • 심사 : 2014.05.12
  • 발행 : 2014.06.30

초록

For the safe handling of n-hexadecane, the lower flash points and the upper flash point, fire point, AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-hexadecane were calculated. The lower flash points of n-hexadecane by using the Setaflash and the Pensky-Martens closed testers were measured $128^{\circ}C$ and $126^{\circ}C$, respectively. The lower flash points of the Tag and the Cleveland open cup testers were measured $136^{\circ}C$ and $132^{\circ}C$, respectively. The fire points of the Tag and the Cleveland open cup testers were measured $144^{\circ}C$. respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-hexadecane. The experimental AIT of n-hexadecane was $200^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $128^{\circ}C$ and upper flash point $180^{\circ}C$ for n-hexadecane were 0.42 Vol.% and 4.70 Vol.%.

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참고문헌

  1. F.P. Lees, "Loss Prevention in the Process Industries", Vol. 2, 2nd ed., Butterworth-Heinemann, 1996.
  2. T.H. Ladwig, "Industrial Fire Prevention and Protection", Van Nostrand Reinhold, 1991.
  3. A.E. Cote and J.L. Linville, "Fire Protection Handbook", 18th ed., NFPA, 2002.
  4. R.E. Montemayor, J.E. Rogerson, J.C. Colbert and S.B. Schiller, "Reference Verification Fluids for Flash point Determination", J. of Testing and Evaluation, Vol. 27, No. 6, pp. 423-427, 1999. https://doi.org/10.1520/JTE12171J
  5. D.M. Ha, "The Investigation of Combustible Hazard by Measurement of Flash Point and Auto-ignition Temperature of n-Dodecane", J. of the Korean Institute of Fire Sci. & Eng., Vol. 25, No. 2, pp. 120-125, 2011.
  6. D.M. Ha, "The Investigation of Compatibility of Combustible Characteristics for n-Tridecane", J. of the Korean Society of Safety, Vol. 27, No. 3, pp. 83-88, 2012.
  7. D.M. Ha, "The Evaluation of Hazard by Measurement of Combustible Characteristics of n-Tetradecane", J. of the Korean Society of Safety, Vol. 27, No. 5, pp. 70-76, 2012.
  8. D.M. Ha, "The Measurement of Combustible Characteristics of n-Undecane", J. of the Korean Institute of Fire Sci. & Eng., Vol. 27, No. 2, pp. 11-17, 2013. https://doi.org/10.7731/KIFSE.2013.27.2.011
  9. D.M. Ha, "The Measurement of Fire and Explosion Properties of n-Pentadecane", J. of the Korean Society of Safety, Vol. 28, No. 4, pp. 53-57, 2013. https://doi.org/10.14346/JKOSOS.2013.28.4.053
  10. R.H. Perry and D.W. Green, "Perry's Chemical Engineers' Handbook", 7th ed., McGraw-Hill, 1997.
  11. NFPA, "Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids", FPA 325M, NFPA, 1991.
  12. SFPE, "SFPE Handbook of Fire Protection Engineering", 2nd ed., SFPE, 1995.
  13. V. Babrauskas, "Ignition Handbook", Fire Science Publishers, SFPE, 2003
  14. J.A. Dean, "Lange's handbook of Chemistry", 14th ed. McGraw-Hill, 1992.
  15. E.W. Flick, "Industrial Solvent Handbook", 3rd. ed., Noyes, Data Corp., Park Ridge, N.J., 1985.
  16. C.J. Hilado and S.W. Clark, "Autoignition Temperature of Organic Chemicals", Chemical Engineering, Vol. 4, pp.75-80, 1972.
  17. G.M. Zabetakis, "Flammability Characteristics of Combustible Gases and Vapors", US Bureau of Mines, Bulletin, 1965.
  18. G.S. Scott, G.W. Jones and F.E. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases", Analytical Chemistry, Vol. 20, No.3, pp. 238-241, 1948. https://doi.org/10.1021/ac60015a015
  19. C.E. Frank and A.U. Blackham, "Investigation of Hydrocarbon Ignition", Technical Note, NACA, 1952.
  20. J. Gmehing, U. Onken and W. Arlt, "Vapor-Liquid Equilibrium Data Collection", DECHEMA, 1980.
  21. R.E Lenga and K.L. Votoupal, "The Sigma Aldrich Library of Regulatory and Safety Data, Volume I-III", Sigma Chemical Company and Aldrich Chemical Company Inc., 1993.
  22. W.A. Affens and G.W. McLaren, "Flammability Properties of Hydrocarbon Solutions in Air", J. of Chemical and Engineering Data, Vol. 17, No. 4, pp.482-488, 1972. https://doi.org/10.1021/je60055a040
  23. N.N. Semenov, "Some Problems in Chemical Kinetics and Reactivity", Vol. 2, Princeton University Press, Princeton, N.J., 1959.

피인용 문헌

  1. The Measurement and Prediction of Fire and Explosion Properties of n-Nonane vol.31, pp.5, 2016, https://doi.org/10.14346/JKOSOS.2016.31.5.42