• Title/Summary/Keyword: temperature limit

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Lithium Bis(oxalate)borate as an Electrolyte Salt for Supercapacitors in Elevated Temperature Applications

  • Madzvamuse, Alfred;Hamenu, Louis;Mohammed, Latifatu;Bon, Chris Yeajoon;Kim, Sang Jun;Park, Jeong Ho;Ko, Jang Myoun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.4
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    • pp.314-322
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    • 2017
  • The electrolyte plays one of the most significant roles in the performance of electrochemical supercapacitors. Most liquid organic electrolytes used commercially have temperature and potential range constraints, which limit the possible energy and power output of the supercapacitor. The effect of elevated temperature on a lithium bis(oxalate)borate(LiBOB) salt-based electrolyte was evaluated in a symmetric supercapacitor assembled with activated carbon electrodes and different electrolyte blends of acetonitrile(ACN) and propylene carbonate(PC). The electrochemical properties were investigated using linear sweep voltammetry, cyclic voltammetry, galvanostatic charge-discharge cycles, and electrochemical impedance spectroscopy. In particular, it was shown that LiBOB is stable at an operational temperature of $80^{\circ}C$, and that, blending the solvents helps to improve the overall performance of the supercapacitor. The cells retained about 81% of the initial specific capacitance after 1000 galvanic cycles in the potential range of 0-2.5 V. Thus, LiBOB/ACN:PC electrolytes exhibit a promising role in supercapacitor applications under elevated temperature conditions.

Development of Web-based Design Compatibility Assessment Program for High Temperature Reactor (고온로 설계 적합성평가 프로그램 개발)

  • Cho, Doo Ho;Surh, Han Bum;Choi, Jae Boong;Huh, Nam Su;Choi, Young Hwan
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.9 no.1
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    • pp.48-55
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    • 2013
  • In this paper, W-DCAP-HTR(Web-based Design Compatibility Assessment Program for High Temperature Reactor) which will be used to check the design criteria for high temperature reactor is newly proposed. To do this, the assessment procedure of the ASME Sec.III Div.5 such as time-dependent primary stress limit, accumulated inelastic strain, and creep-fatigue damage evaluation were investigated. Furthermore, the trend of candidate materials for high temperature reactor was also reviewed. Then, all assessment procedures for high temperature reactor have been computerized to enhance the efficiency and to reduce the possibility of human error during calculating procedure by hand calculation. It can be directly conducted by adopting the actual thermal and structural analysis results. The validation of W-DCAP-HTR has been demonstrated by benchmark analysis.

Microbial Quality Change Model of Korean Pan-Fried Meat Patties Exposed to Fluctuating Temperature Conditions

  • Kim, So-Jung;An, Duck-Soon;Lee, Hyuek-Jae;Lee, Dong-Sun
    • Preventive Nutrition and Food Science
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    • v.13 no.4
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    • pp.348-353
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    • 2008
  • Aerobic bacterial growth on Korean pan.fried meat patties as a primary quality deterioration factor was modeled as a function of temperature to estimate microbial spoilage on a real.time basis under dynamic storage conditions. Bacteria counts in the stretch.wrapped foods held at constant temperatures of 0, 5, 10 and $15^{\circ}C$ were measured throughout storage. The bootstrapping method was applied to generate many resampled data sets of mean microbial counts, which were then used to estimate the parameters of the microbial growth model of Baranyi & Roberts in the form of differential equations. The temperature functions of the primary model parameters were set up with confidence limits. Incorporating the temperature dependent parameters into the differential equations of bacterial growth could produce predictions closely representing the experimental data under constant and fluctuating temperature conditions.

A Study on The Effect of Humidity and Temperature of Hydroxy Propyl Methyl Cellulose Dust (Hydroxy Propyl Methyl Cellulose 분진의 습도와 온도에 대한 영향성 연구)

  • Lim Woo-Sub;Mok Yun-Soo;Choi Jae-Wook
    • Journal of the Korean Society of Safety
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    • v.19 no.3 s.67
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    • pp.65-69
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    • 2004
  • This study was performed with Hartmann type dust explosion apparatus and Godbert-Greenwald furnace apparatus in order to research the effect of temperature and humidity affecting LEL, minimum ignition temperature of Hydroxy Propyl Methyl Cellulose. The experimental determinations in the range between $20^{\circ}C\;and\;60^{\circ}C$ of temperature was not affected $LEL(180g/m^3)$ but LEL showed $200g/m^3\;and\;250g/m^3\;at\;80^{|circ}C\;and\;100^{\circ}C$. As the change of humidity LEL was $180g/m^3\;for\;50\%,\;200g/m^3\;for\;60\%\;and\;250g/m^3\;for\;70\%$ but dust explosion didn't occur over $80\%$. The ignition temperature of HPMC dust clouds was increased as increasing of humidity. So, the minimum ignition temperatures at $50\%,\;60\%,\;70\%\;80\%$ of humidity was $363^{\circ}C,\;375^{\circ}C,\;397^{\circ}C,\;405^{\circ}C$.

The Effective Heating Control Method of the Radiant Floor Heating System (바닥복사 난방공간의 효율적인 난방제어방법)

  • Cho, S.H.;Tae, C.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.3
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    • pp.317-329
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    • 1996
  • By describing the floor slab of a radiant heating system as a one dimensional transient heat exchanger problem, a dynamic analysis model to incorperate with TRNSYS program was developed and their results were compared with experimental results. Results showed that the both of TPOC(Two Parameter On-off Control) and TPSC(Two Parameter Switching Control) method using room air temperature and floor surface temperature as the control parameters does not maintain room air and floor surface temperature exactly at the setting temperatures. But TPSC method is a better candidate for the temperature regulations of room air and floor surface temperature than TPOC method which can keep on the upper and lower limit temperature according to outside temeperature and wall structure etc. And better thermal circumstance can be given by TPSC method than On-off and TPOC method and the overheating which can be occured at the radiant floor heating system with on-off heating control will be reduced.

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Variation of the Curie Temperature in $BaTiO_3$ Doping $Cd_5(PO_4)_3Cl$ ($BaTiO_3$에서 $Cd_5(PO_4)_3Cl$의 첨가로 인한 Curie 온도변화)

  • Kim, Gwang-Chul
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.1
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    • pp.95-99
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    • 2011
  • $(1-x)BaTiO_3+(x)Cd_5(PO_4)_3Cl$ ceramics were prepared by the conventional ceramic technique, i.e., solid state reaction at high temperature. The concentration of $Cd_5(PO_4)_3C$ was varied from 0.01 to 0.15 mole fraction. In order to study the phase transitions of our ceramics, the Raman scattering spectra were measured as functions of concentration x and temperature. It was found that the soluble limit of $Cd_5(PO_4)_3Cl$ in $BaTiO_3$ was the x=0.05 composition and $BaTiO_3$ phase disappeared above x=0.10. A new phase identified as $Ba_4Ti_3P_2O_{15}$ was detected in all samples of our compositions. The Curie temperature shifts up to $130^{\circ}C$ as the concentration x increases from zero to 0.05 and shift down to $95^{\circ}C$ as further increases to 0.08. For the increase of the Curie temperature, it is suggested that it can result from the inhibition of displacement of $Ti^{4+}$ in the distorted octahedron due to well dispersed $Ba_4Ti_3P_2O_{15}$ and $Cd_5(PO_4)_3Cl$ phase.

Probabilistic Fracture Mechanics Analysis of Boling Water Reactor Vessel for Cool-Down and Low Temperature Over-Pressurization Transients

  • Park, Jeong Soon;Choi, Young Hwan;Jhung, Myung Jo
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.545-553
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    • 2016
  • The failure probabilities of the reactor pressure vessel (RPV) for low temperature over-pressurization (LTOP) and cool-down transients are calculated in this study. For the cool-down transient, a pressure-temperature limit curve is generated in accordance with Section XI, Appendix G of the American Society of Mechanical Engineers (ASME) code, from which safety margin factors are deliberately removed for the probabilistic fracture mechanics analysis. Then, sensitivity analyses are conducted to understand the effects of some input parameters. For the LTOP transient, the failure of the RPV mostly occurs during the period of the abrupt pressure rise. For the cool-down transient, the decrease of the fracture toughness with temperature and time plays a main role in RPV failure at the end of the cool-down process. As expected, the failure probability increases with increasing fluence, Cu and Ni contents, and initial reference temperature-nil ductility transition ($RT_{NDT}$). The effect of warm prestressing on the vessel failure probability for LTOP is not significant because most of the failures happen before the stress intensity factor reaches the peak value while its effect reduces the failure probability by more than one order of magnitude for the cool-down transient.

Performance Characteristics of a Heat Pipe Having Water-Ethanol Mixture as Working Fluid for Evacuated Solar Collectors (물-에탄올 혼합물을 작동유체로 하는 진공관형 태양열 집열기용 히트파이프의 작동특성)

  • Jung, Eui-Guk;Boo, Joon-Hong;Kwak, Hee-Youl
    • Journal of the Korean Solar Energy Society
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    • v.28 no.5
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    • pp.78-84
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    • 2008
  • Heat pipes are considered to be promising candidates to enhance the heat transport capability of evacuated solar collectors in a wide temperature range. The working fluid must be selected properly considering various operating conditions of heat pipes for medium-high temperature range to avoid dry-out, local overheating, and frozen failure. The advantage of using binary mixture as heat pipe working fluid is that it can extend operating temperature range of the system as it can overcome operating temperature limit of a single fluid. Various operating temperature ranges were imposed in the experiments to simulate the actual operation of solar collectors using water-ethanol binary mixture. Tests were conducted for the coolant temperature range of -10$^{\circ}C$ to 120$^{\circ}C$, and mixing ratio range was from 0 to 1 based on mass fraction.

Changes in the External Heat Environment of Building Evaporative Cooling Systems in Response to Climate Change (기후변화 대응 건축물 기화냉각시스템 적용에 따른 외부 열환경 변화 연구)

  • Yoon, Yong-Han;Kwon, Ki-Uk
    • Journal of Environmental Science International
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    • v.27 no.12
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    • pp.1261-1269
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    • 2018
  • The purpose of this study was to investigate changes in the external thermal environment, following the application of evaporative cooling systems in buildings, in response to climate change. In order to verify changes in the external thermal environment, a T-test was performed on the microclimate, Thermal Comfort Index (TCI), and building surface temperature. Differences in microclimate, following the application of the evaporative cooling system in the building, were significant in terms of temperature and relative humidity. In particular, temperature decreased by more than 7% when the evaporative cooling system was applied. According to the results of the Thermal Comfort Index analysis, the Wet-Bulb Globe Temperature (WBGT) was below the limit of outdoor activities, indicating that outdoor activities were possible. The Universal Thermal Climate Index (UTCI) values were within the very strong heat stress range when the evaporative cooling system was not applied, When the system was applied, the UTCI values were within the strong heat stress range, indicating that they were lowered by one level. The building surface temperature decreased by ~10% or more when the evaporative cooling system was applied, compared to when it was not applied. Finally, the outside surface temperature of the building decreased by ~12% or more when the system was applied, compared to when it was not applied. We conclude that the energy saving effect of the building was significant.

Acclimation temperature influences the critical thermal maxima (CTmax) of red-spotted grouper

  • Rahman, Md Mofizur;Lee, Young-Don;Baek, Hea Ja
    • Fisheries and Aquatic Sciences
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    • v.24 no.7
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    • pp.235-242
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    • 2021
  • The present study investigated the critical thermal maxima (CTmax) of red-spotted grouper, Epinephelus akaara under different acclimation temperatures (Tacc). Fish were acclimated at 24℃, 28℃, and 32℃ water temperature for 2 weeks. Water temperature was increased at a rate of 1℃/h and CTmax level was measured following the critical thermal methodology (Paladino et al., 1980). The results showed that CTmax values of E. akaara were 35.61℃, 36.83℃, and 37.65℃ for fish acclimated at 24℃, 28℃, and 32℃, respectively. The acclimation response ratio (ARR) was 0.26. The CTmax values were significantly correlated with body size. Collectively, it is said that the CTmax value of red-spotted grouper can be affected by different adaptation temperature (24℃, 28℃, and 32℃) and the fish acclimated to a higher temperature has a higher CTmax level. Besides, the CTmax value of 35.61℃-37.65℃ indicating the upper thermal tolerance limit for E. akaara under different Tacc (24℃, 28℃, and 32℃). Understanding the thermal tolerance of E. akaara is of ecological importance in the conservation of this species.