• Title/Summary/Keyword: temperature dependent viscosity

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Thixotropic Properties of Gelatinized Rice Starch Solutions (쌀 전분 호화액의 틱소트로픽 성질)

  • Kim, Ju-Bong;Kim, Young-Suk;Lee, Shin-Young;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.16 no.4
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    • pp.451-456
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    • 1984
  • Rheological properties of gelatinized rice starch solutions were investigated with Brookfield rotational viscometer. The 8% starch solution showed thixotropic behavior with yield stress. The alkali gelatinized starch was more thixotropic than the thermal gelatinized one. The time dependent characteristics of starch solutions followed Tiu's model. The value of rate constant $(a_1)$ in Tiu's model increased linearly with shear rate, and was exponentially dependent on concentration and temperature. Temperature dependency of rate constant and apparent viscosity followed Arrhenius type equation and the activation energy were about 14.3 and 6.8 Kcal/g mole, respectively. The $a_1-value$ was found to be useful to evaluate changes in structaral decay on the shearing time of gelatinized rice starch solutions.

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Time-dependent variations of accretion disk (Accretion disk의 시간에 따른 변화)

  • 나혜원;김경미;최규홍
    • Journal of Astronomy and Space Sciences
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    • v.4 no.1
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    • pp.11-23
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    • 1987
  • In dward nova we assume the primary star as a white dwarf and the secondary as the late type star which filled Roche lobe. Mass flow from the secondary star leads to the formation of thin accretion disk around the white dwarf. We use the $\alpha$ parameter as viscosity to maintain the disk form and propose that the outburst in dwarf nova cause the step increase of source term. With these assumptions we solve the basic equations of stellar structure using New-Raphson method. We show the physical parameters like temperature, density, pressure, opacity, surface density, height and flux to the radius of disk. Changing the value of $\alpha$, we compare several parameters when mass flow rate is constant with those of when luminosity of disk is brightest. At the same time, we obtain time-dependent variations of luminosity and mass of disk. We propose the suitable range of $\alpha$is 0.15-0.18 to the difference of luminosity. We compare several parameters of disk with those of the normal late type stars which have the same molecular weight of disk. These show the temperature and pressure of disk are similar to those of normal stars but the density of disk is lower. Maybe the outburst in dwarf nova is due to the variation of the $\alpha$ value instead of increment of mass flow from the secondary star.

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Rheological Properties of Pear Juice Concentrates (배주스 농축액의 리올로지 특성)

  • Choi, Hee-Don;Kim, Kyung-Tack;Hong, Hee-Do;Lee, Boo-Yong;Kim, Sung-Su
    • Korean Journal of Food Science and Technology
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    • v.27 no.6
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    • pp.845-851
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    • 1995
  • To improve the utilization of pear in its processing, the cloudy and clear juice concentrates were prepared and their rheological properties were investigated in the range of temperatures($5{\sim}60^{\circ}C$) and concentrations($15{\sim}60^{\circ}Brix$). Pear juice concentrates showed flow behavior close to Newtonian fluids. Their flow behavior was also explained by applying Power law model and Herschel-Bulkley model. Flow behavior index did not have good correlation with concentration, but decreased with the increase of temperature, showing pseudoplastic properties. Consistency index increased with the increase of concentration and with the decrease of temperature. The effect of temperature and concentration on the apparent viscosity at 1500 1/s shear rate was examined by applying Arrhenius equation. The activation energy for flow of the cloudy and clear pear juice concentrates increased from $1.5140{\times}10^4\;to\;3.4141{\times}10^4\;J/kg{\cdot}mol$, and from $1.4762{\times}10^4\;to\;3.4963{\times}10^4\;J/kg{\cdot}mol$ with the increase of concentration, respectively. The influence of temperature on the apparent viscosity was more pronounced at higher concentration. And the concentration-dependent constant A decreased from $0.0789\;to\;0.0484^{\circ}Brix^{-1}$, and from $0.0786\;to\;0.0476^{\circ}Brix^1$ with the increase of temperature, respectively.

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Quality Factor Determination and Shelf-Life Prediction of Emulsified Ginseng Drink (인삼 유화 음료의 품질 인자 규명 및 저장 수명 예측)

  • Baik, Eun-Kyung;Seo, Yong-Ki;Lee, Geun;Lee, Dong-Un;Park, Seok-Jun;Lee, Jin-Hee;Lee, Kang-Pyo;Kim, Dong-Seob;Hur, Nam-Yun;Baik, Moo-Yeol
    • Korean Journal of Food Science and Technology
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    • v.37 no.4
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    • pp.597-602
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    • 2005
  • Quality factors of emulsified ginseng drink were determined during storage at various temperatures, and its shelf-life was predicted based on changes in emulsion stability, acidify, viscosity, and yellowness. Viscosity was highly dependent on storage temperature. Emulsion stability changed rapidly during early storage period (1st step), then slowly thereafter (2nd step). $Q_{10}$ values of emulsion stability were 2.50 and 1.38 for 1st and 2nd steps, respectively. Viscosity, acidity, and yellowness showed $Q_{10}$ values of 3.45, 1.77, and 1.99, respectively. Although $Q_{10}$ value of 2 has been generally used to predict shelf stability of food materials, our results suggest adopting same $Q_{10}$ value to predict shelf stability of emulsified ginseng drink is not appropriate.

Studies on Rheological Characterizaiton of Rhamsan Gum Produced by Alcaligenes -comparative studies on rheological Characterization of Rhamsan and Xanthangum- (Alcaligenes에 의해서 생성된 Rhamsan Gum의 리올리지 특성에 관한 연구)

  • Lee, Im-Seon;Kim, Mi-Ok;Koo, Sung-Ja
    • Korean journal of food and cookery science
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    • v.8 no.2
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    • pp.155-163
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    • 1992
  • Rhamsan gum produced by Alcaligenes was rheologically characterized, and compared to that of xanthan gum. The rheological properties were derermined from the change in the value of intrinsic viscosity with pH and salt concentration. at the range of pH 2~11 and salt concentration of 0~1.0 M KCl, the intrinsic viscosties of rhanisan gum were in the range of 8.2 to 36.2 dl/g and those of xanthan gum 8.19 to 44 dl/g. In the absence of salt, the intrinsic viscosity of rhamsan gum and Xanthan gum increased as the pH of solution increased up to neutral pH, and then decreased at alkaline pH. The intrinisc viscosities of rhamsan and anthan gum were not affec6ted by the increment of salt concentration. the chain stiffness paramenter for the rhamsan gum was 0.016. The overlap paramoeters of rhamsan and xanthan gum were 0.025 and 0.022 g/dl, respectively. rhamsan and xanthan gum were shear rate dependent or pseudoplastic. The yield stress of rhamsan gum increased slightly, but the shear index decreased as the concentration increased. The apparent viscosityes of rhamsan and xanthan gum decreased as the temperature increased. The salt effect of divalent cations (calcium, magnesium) was lower than monovalent cations (sodium, potassium).

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Thermal Degradation of Thermoplastic Polyurethane Modified with Polycarbonate (열가소성 폴리우레탄으로 개질된 폴리카보네이트에서 TPU의 열분해)

  • 권회진;차윤종;최순자
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.314-325
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    • 2000
  • Thermal degradation of thermoplasitc polyurethane modified polycarbonate has been investigated by means of DSC, GPC and FT-IR techniques. The polyurethanes used in this study are TPU-35 and TPU-53 containing 35.5 and 53.4 wt% of hard segments, respectively. The more content of hard segment, the higher the glass transition temperature (T$_{g}$) of TPU was observed. On the other hand, the T$_{g}$ of the TPU modified PC decreased with the content of TPU and the annealing temperature regardless of the hard segment contents. The latter behavior nay arise from the thermal degradation of TPU upon annealing process: the observed thermal degradation temperatures were at 240 and 25$0^{\circ}C$ for the PC/TPU-35 and PC/TPU-53, respectively. The molecular weight, molecular weight distribution and viscosity agree well with the DSC measurement, which implicates a thermal degradation of TPU. In addition, thermal stability of the TPU modified PC linearly decreased with an incorporation of TPU. Transesterification or any interaction was not observed using FT-IR: the evidence was no frequency shift or any variance betwere the carbonyl stretching and NH group. For the specimens prepared below the degradation temperature, the enhancement of the thickness dependent impact strength of the PC/TPU blend was observed, and the morphology of the two blends was compared.d.

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Estimation on clamping load of high strength bolts considering various environment conditions

  • Nah, Hwan-Seon;Choi, Sung-Mo
    • Steel and Composite Structures
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    • v.24 no.4
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    • pp.399-408
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    • 2017
  • Of high strength bolts, the torque shear type bolt is known to be clamped normally when pin-tails are broken. Sometimes the clamping loads on slip critical connections considerably fluctuate from the required tension due to variation of torque coefficient. This is why the viscosity of lubricant affects the torque coefficient by temperature. In this study, the clamping tests of high strength bolts were performed independently at laboratory conditions and at outdoor environment. The temperatures of outdoor environment candidates were ranged from $-11^{\circ}C$ to $34^{\circ}C$ for six years. The temperature at laboratory condition was composed from $-10^{\circ}C$ to $50^{\circ}C$ at each $10^{\circ}C$ interval. At outdoor environment conditions, the clamping load of high strength bolt was varied from 159 to 210 kN and the torque value was varied from 405 to 556 Nm. The torque coefficients at outdoor environment were calculated from 0.126 to 0.158 when tensions were measured from 179 to 192 kN by using tension meter. The torque coefficients at outdoor environment conditions were analyzed as the range from 0.118 to 0.152. From these tests, the diverse equations of torque coefficient, tension dependent to temperature can be acquired by statistic regressive analysis. The variable of torque coefficient at laboratory conditions is 0.13% per each $1^{\circ}C$ when it reaches 2.73% per each $1^{\circ}C$ at outdoor environment conditions. When the results at laboratory conditions and at outdoor environment were combined to get the revised equations, the change in torque coefficient was modified as 0.2% per each $1^{\circ}C$ and the increment of tension was adjusted as 1.89 % per each $1^{\circ}C$.

On the dynamic instability analysis of mechanical face seals (기계평면시일의 동적 불안정성에 관한 연구)

  • 김청균;서태석
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.6
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    • pp.1509-1514
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    • 1990
  • To investigate the seal dynamic instability for a misaligned and coned mechanical face seal, the finite difference approximation was employed to solve the modified Reynolds equation for an incompressible fluid and temperature dependent viscosity. Using the solution, the results for axial force, transverse moment, restoring moment, and ratio of the transverse moment and the restoring moment are calculated for the whole range from zero to full angular misalignment. The results indicate that the transverse moment due to the angular misalignment and coning terms affects considerably the dynamic instability of face seals. It is shown that the simplified treatment of Reynolds equation using the narrow seal approximation overestimate the ratio of the transverse moment to the restoring moment especially at touch.

Numerical Study of Secondary Coating Die Geometry Effects on High Speed Optical Glass Fiber Coating Process (광섬유 2차 코팅다이 형상 변화에 따른 유리섬유 고속 코팅공정 영향성 해석연구)

  • Kim, Kyoungjin;Park, Joong-Youn
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.12-18
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    • 2019
  • The protective double layer polymer coatings on silica optical fibers are realized by wet-on-wet liquid coating process and they play an important role in final quality of mass produced optical fibers. This numerical study aims to analyze the effects of secondary coating die design parameters by employing two dimensional axisymmetric model of coating cup and coating die geometry and computational fluid dynamics simulations which include temperature dependent viscosity of polymer coating liquids and viscous dissipation heating. Under high speed fiber drawing conditions and pressurized coating liquid supply, the effects of converging die angle are investigated in order to appreciate the change of coating liquid flow patterns such as flow recirculation zone near coating die as well as primary and secondary coating layer thicknesses. The auxiliary coating die to converging coating die is also tested and the results find that this concept is advantageous in achieving stable double layer coatings on silica glass fiber.

Synthesis of Multi-Walled Carbon Nanotube/Polystyrene (MWCNT/PS) Composites by Solution Process and Their Thermal Behavior (용액공정을 이용한 다중벽 탄소 나노튜브/폴리스티렌(MWCNT/PS) 복합체 합성 및 열적 거동)

  • Teng, Dayong;Shin, Young Hwan;Kwon, Younghwan
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.421-426
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    • 2008
  • Multi-walled carbon nanotube/polystyrene (MWCNT/PS) composites with various MWCNT contents were prepared by using a solution process with an aid of surfactant. Particularly, PS's with 3 different molecular weights (${\bar{M}}_n$ = 101500 g/mole for PS-1, ${\bar{M}}_n$ = 89900 g/mole for PS-2, and ${\bar{M}}_n$ = 85000 g/mole for PS-3) were used in this study. Thermal behavior of these composites was examined by using an oscillator rheometer at $210^{\circ}C$ and $180^{\circ}C$, of above and below the critical flow temperature ($T_{cf}{\sim}195^{\circ}C$) of PS matrix, respectively. The storage and loss modulus, and the complex viscosity of these composites increased with increasing MWCNT content at both temperatures. Largest increases in the frequency-dependent moduli and complex viscosity were observed between 2 wt% and 5 wt% of MWCNTs at $210^{\circ}C$ and $180^{\circ}C$. Only the composite at $210^{\circ}C$ showed the rheological phase transition from a viscous-dominant to an elastic-dominant behavior of the composites at a certain MWCNT content. The MWCNT content at the rheological phase transition of MWCNT/PS composites generally increased with decreasing molecular weight of PS, and was measured to be 3.5 wt% for MWCNT/PS-1, 3.2 wt% for MWCNT/PS-2, and 3.0 wt% for MWCNT/PS-3 composites.