• Title/Summary/Keyword: temperature dependent parameters

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Morphological Structural and Electrical Properties of DC Magnetron Sputtered Mo Thin Films for Solar Cell Application

  • Fan, Rong;Jung, Sung-Hee;Chung, Chee-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.389-389
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    • 2012
  • Molybdenum is one of the most important materials used as a back ohmic contact for $Cu(In,Ga)(Se,S)_2$ (CIGS) solar cells because it has good electrical properties as an inert and mechanically durable substrate during the absorber film growth. Sputter deposition is the common deposition process for Mo thin films. Molybdenum thin films were deposited on soda lime glass (SLG) substrates using direct-current planar magnetron sputtering technique. The outdiffusion of Na from the SLG through the Mo film to the CIGS based solar cell, also plays an important role in enhancing the device electrical properties and its performance. The structure, surface morphology and electrical characteristics of Mo thin films are generally dependent on deposition parameters such as DC power, pressure, distance between target and substrate, and deposition temperature. The aim of the present study is to show the resistivity of Mo layers, their crystallinity and morphologies, which are influenced by the substrate temperature. The thickness of Mo films is measured by Tencor-P1 profiler. The crystal structures are analyzed using X-ray diffraction (XRD: X'Pert MPD PRO / Philips). The resistivity of Mo thin films was measured by Hall effect measurement system (HMS-3000/0.55T). The surface morphology and grain shape of the films were examined by field emission scanning electron microscopy (FESEM: Hitachi S-4300). The chemical composition of the films was obtained by the energy dispersive X-ray spectroscopy (EDX). Finally the optimum substrate temperature as well as deposition conditions for Mo thin films will be developed.

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Computational Modeling of Charge-Discharge Characteristics of Lithium-Ion Batteries (리튬이온 전지의 충방전 특성에 대한 전산 모델링)

  • Lee, Dae-Hyun;Yoon, Do-Young
    • Journal of Energy Engineering
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    • v.20 no.4
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    • pp.278-285
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    • 2011
  • Computational modelling and simulation for the charge-discharge characteristics of Lithium-ion batteries have been carried out. The battery system consists of a simplified 2-dimensional single cell for the modelling, in which the thermal modelling on the charge-discharge characteristics was conducted in the temperature range from 288 K through 318 K by using FEMLAB as an engineering PDE solver. While material parameters adopted in the present modelling were dependent on the system temperature, their thermal modelling were applied on the simulations of the charge-discharge period and the rate of transferring charges systematically. The resulting simulation shows that the cycle of the charge-discharge shorten itself by reducing the system temperature, regardless of the charge-discharge rates. In addition, the mass-transport phenomena of Lithium ion have been discussed in connection with the charge-discharge characteristics in the battery.

Shelf-life prediction of packaged cigarette subjected to different degrees of sealing (봉함도에 따른 포장담배의 저장수명 예측)

  • Keun-hoi Lee;young-hoh Kim;young-taek Lee;Kwang-soo Rhim;yong-tae Kim
    • Journal of the Korean Society of Tobacco Science
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    • v.12 no.2
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    • pp.59-65
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    • 1990
  • In order to predict the shelf-life of cigarettes packaged in typical flexible film under conditions of various temperature, relative humidity and sealing degree, a computer iterative technique was used. Although there were some significant differences at initial equilibrium relative humidity(55%), the experimental results agree fairly well with predictions following the student's t test($\alpha$=0.01) in most cases. Essentially, the higher the storage temperature, the shorter the shelf-life of the cigarette product. The bigger the differences from the initial equilibrium relative humidity, the shorter the storage period of the cigarette. Moisture transfer through the film at relatively high temperature gave higher confidence. The sealing degree, one of the storage parameters, appeared to be a major influencing factor to shelf-life. Slopes($\beta$) of the temp., sealing degree and %rh of the dependent variable to shelf life were 0.49, -0.39 and -0, 28 respectively, when analysed by multiple regression of SPSS software. Below 600m1/min sealing decree of the packed cigarette through the sealing Position at 30mmH20 differential pressure, the shelf-life could be increased by more than six months.

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Analysis on the Dynamic Characteristics of a Rubber Mount Considering Temperature and Material Uncertainties (온도와 물성의 불확실성을 고려한 고무 마운트의 동특성 해석)

  • Lee, Doo-Ho;Hwang, In-Sung
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.24 no.4
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    • pp.383-389
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    • 2011
  • In this paper, a statistical calibration method is proposed in order to identify the variability of complex modulus for a rubber material due to operational temperature and experimental/model errors. To describe temperature- and frequency-dependent material properties, a fractional derivative model and a shift factor relationship are used. A likelihood function is defined as a product of the probability density functions where experimental values lie on the model. The variation of the fractional derivative model parameters is obtained by maximizing the likelihood function. Using the proposed method, the variability of a synthetic rubber material is estimated and applied to a rubber mount problem. The dynamic characteristics of the rubber mount are calculated using a finite element model of which material properties are sampled from Monte Carlo simulation. The calculated dynamic stiffnesses show very large variation.

Temperature-Dependent Characteristics of SBD and PiN Diodes in 4H-SiC (온도에 따른 4H-SiC에 기반한 SBD, PiN 특성 비교)

  • Seo, Ji-Ho;Cho, Seulki;Lee, Young-Jae;An, Jae-In;Min, Seong-Ji;Lee, Daeseok;Koo, Sang-Mo;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.6
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    • pp.362-366
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    • 2018
  • Silicon carbide is widely used in power semiconductor devices owing to its high energy gap. In particular, Schottky barrier diode (SBD) and PiN diodes fabricated on 4H-SiC wafers are being applied to various fields such as power devices. The characteristics of SBD and PiN diodes can be extracted from C-V and I-V characteristics. The measured Schottky barrier height (SBH) was 1.23 eV in the temperature range of 298~473 K, and the average ideal factor is 1.17. The results show that the device with the Schottky contact is characterized by the theory of thermal emission. As the temperature increases, the parameters are changed and the Vth is shifted to lower voltages.

Effects of Molding Conditions on the Deflection of Rib Moldings of Fiber-reinforced Plastic Composites in Compression Molding (섬유강화 플라스틱 복합재료의 압축성형에서 리브 성형품의 휨에 미치는 성형조건의 영향)

  • Kim, Jin-Woo;Lee, Jung-Hoon;Lee, Dong-Gi
    • Journal of Advanced Engineering and Technology
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    • v.10 no.3
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    • pp.285-290
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    • 2017
  • Molding of body with ribs is the most difficult during flow molding process. The rib area is easy to be deformed at the rear side due to wall thickness variation. In this study, relationships between molding condition and deflection of rib-shaped part is investigated during the compression molding of fiber reinforced plastic composites, and the following results are derived. Polypropylene(PP), Polystyrene(PS), and stampable sheet(SS 40wt%) show the increment of deflection along with releasing temperature. For the correlation between incremental holding pressure load and deflection, stampable sheet exhibits lower deflection along with higher holding pressure, while PS shows significant increase of deflection with higher holding pressure, PP shows completely different characteristic, significant reduction of deflection along with higher holding pressure. Regarding to mold temperature and deflection, deflection amount of SS is the biggest, and PS shows the smallest. In addition, all three kinds shows the highest amount of deflection at 173C. Deflection is reduced when mold closing speed is increased. Amount of deflection in SS is larger and is not highly dependent on molding conditions like holding pressure and cooling parameters, compared with single component material like PP. This can be elucidated by anisotropic and inhomogeneous characteristics of glass fiber during filling process of stampable sheet composite.

Analysis and Prediction for Abutment Behavior of Prestressed Concrete Girder Integral Abutment Bridges (프리스트레스트 콘크리트 거더 일체식 교량의 교대 거동 해석과 예측)

  • Kim, Woo-Seok
    • Journal of the Korea Concrete Institute
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    • v.23 no.5
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    • pp.667-674
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    • 2011
  • This paper discusses the analysis method of prestressed concrete girder integral abutment bridges for a 75-year bridge life and the development of prediction models for abutment displacements under thermal loading due to annual temperature fluctuation and time-dependent loading. The developed nonlinear numerical modeling methodologies considered soil-structure interaction between supporting piles and surrounding soils and between abutment and backfills. Material nonlinearity was also considered to simulate differential rotation in construction joints between abutment and backwall. Based on the numerical modeling methodologies, a parametric study of 243 analysis cases, considering five parameters: (1) thermal expansion coefficient, (2) bridge length, (3) backfill height, (4) backfill stiffness, and (5) pile soil stiffness, was performed to established prediction models for abutment displacements over a bridge life. The parametric study results revealed that thermal expansion coefficient, bridge length, and pile-soil stiffness significantly influenced the abutment displacement. Bridge length parameter significantly influenced the abutment top displacement at the centroid of the superstructure, which is similar to the free expansion analysis results. Developed prediction model can be used for a preliminary design of integral abutment bridges.

Investigation of the interaction between spin density wave and superconductivity in two band high temperature iron based superconductor Ba1-xNaxFe2As2

  • Teklie Lissanu Tegegne
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.2
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    • pp.9-18
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    • 2024
  • The current study deals with the possible interplay between superconductivity and spin density wave in two band model high temperature iron based superconductor (FeBSC) Ba1-xNaxFe2As2. The electron and hole bands in the presence of the inter-band interaction between the two bands is becoming a vital issue to deal with the high temperature physics of the iron-based superconductors. In this research work, a model Hamiltonian appropriate for the system under consideration has been developed and the temperature dependent Green's function technique has been employed to get the solution for the equations of motion constructed for the two band model high temperature FeBSC Ba1-xNaxFe2As2. By making use of the decoupling procedure, the equations of motion for the dependence of superconducting transition temperature (TC) on spin density wave(SDW) order parameter (ΔSDW) in the electron intra-band (Δsc(e)) , hole intra-band (Δsc(h)) and inter-band (Δsc(eh)) for Ba1-xNaxFe2As2 have been obtained. We have also obtained the expression for the dependence of spin density wave transition temperature(TSDW) on ΔSDW for Ba1-xNaxFe2As2. Using some plausible approximations and appropriate experimental values for the parameters in the obtained equations of motion, phase diagrams of TC versus Δsc(e), Δsc(h) and Δsc(eh) are plotted. Furthermore, a phase diagram of TSDW versus ΔSDW is plotted for the material under consideration. Finally, using the above mentioned phase diagrams, the interplay between superconductivity and spin density wave in the two band model high temperature FeBSC Ba1-xNaxFe2As2 has been demonstrated to be a very distinct possibility. The agreement of the current finding with the experimental observations is quite commendable.

DEVELOPMENT OF ARTIFICIAL NEURAL NETWORK MODELS SUPPORTING RESERVOIR OPERATION FOR THE CONTROL OF DOWNSTREAM WATER QUALITY

  • Chung, Se-Woong;Kim, Ju-Hwan
    • Water Engineering Research
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    • v.3 no.2
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    • pp.143-153
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    • 2002
  • As the natural flows in rivers dramatically decrease during drought season in Korea, a deterioration of river water quality is accelerated. Thus, consideration of downstream water quality responding to changes in reservoir release is essential for an integrated watershed management with regards to water quantity and quality. In this study, water quality models based on artificial neural networks (ANNs) method were developed using historical downstream water quality (rm $\NH_3$-N) data obtained from a water treatment plant in Geum river and reservoir release data from Daechung dam. A nonlinear multiple regression model was developed and compared with the ANN models. In the models, the rm NH$_3$-N concentration for next time step is dependent on dam outflow, river water quality data such as pH, alkalinity, temperature, and rm $\NH_3$-N of previous time step. The model parameters were estimated using monthly data from Jan. 1993 to Dec. 1998, then another set of monthly data between Jan. 1999 and Dec. 2000 were used for verification. The predictive performance of the models was evaluated by comparing the statistical characteristics of predicted data with those of observed data. According to the results, the ANN models showed a better performance than the regression model in the applied cases.

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Synthesis and Luminescent Properties of $RE^3+(Eu^3+\;and\;Tb^3+$) Ions Activated CaGd4O7 Novel Phosphors

  • Pavitra, E.;Raju, G.Seeta Rama;Ko, Yeong-Hwan;Yu, Jae-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.359-359
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    • 2012
  • Trivalent rare-earth ($RE^{3+}=Eu^{3+}\;and\;Tb^{3+}$) ions activated $CaGd_4O_7$ phosphors were synthesized by a sol-gel process. After annealing at $1,500^{\circ}C$, the XRD patterns of the phosphor confirmed their monoclinic structure. The photoluminescence excitation spectra of $Eu^{3+}$ and $Tb^{3+}$ doped $CaGd_4O_7$ phosphor shows the broad-band excitations in the shorter wavelength region due to charge transfer band of completely filled $O^{2-}$ to the partially filled $Eu^{3+}$ ions and f-d transitions of $Tb^{3+}$ ions, respectively. The photoluminescence spectra show that the reddish-orange ions and green emission for $Eu^{3+}$ and $Tb^{3+}$ ions, respectively. Owing to the importance of thermal quenching property in the technological parameters, the temperature-dependent luminescence properties of these phosphors were measured for examing the suitability of their applications in the development of light emitting diodes (LEDs). In addition to those measurements, the cathodoluminescence properties were examined by changing the acceleration voltage and filament current. The calculated chromaticity coordinates of these phosphors were close proximity to those of commercially available phosphors for LED and field emission display devices.

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