• Advances in materials Research
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• v.3 no.2
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• pp.117-128
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• 2014

Processable conducting polyaniline derivative with free amine functional groups was successfully synthesized from the monomer o-phenylenediamine in aqueous hydrochloric acid medium using ammonium persulfate as an oxidative initiator. The synthesized poly(o-phenylenediamine) (PoPD) in critical condition was found to be completely soluble in common organic solvents like dimethyl sulfoxide, N,N-dimethyl formamide etc. From the intrinsic viscosity measurement, the optimum condition for the polymerization was established. The polymer was characterized by ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, proton magnetic resonance spectroscopy ($^1HNMR$) and thermogravimetric (TGA) analyses. The weight average molecular weights of the synthesized polymers were determined by the dynamic light scattering (DLS) method. From the spectroscopic analysis the structure was found to resemble that of polyaniline derivative with free amine functional groups attached to ortho/meta position in the phenyl ring. However, very little ladder unit was also present with in the polymer chain. The moderate thermal stability of the synthesized polymer could be found from the TGA analysis. The average DC conductivity of $2.8{\times}10^{-4}S/cm$ was observed for the synthesized polymer pellet after doping with hydrochloric acid.

• Steel and Composite Structures
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• v.20 no.5
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• pp.1119-1131
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• 2016

As a first attempt, an inverse hybrid numerical method for small scale parameter estimation of functionally graded (FG) nanobeams using measured frequencies is presented. The governing equations are obtained with the Eringen's nonlocal elasticity assumptions and the first-order shear deformation theory (FSDT). The equations are discretized by using the differential quadrature method (DQM). The discretized equations are transferred from temporal domain to frequency domain and frequencies of the nanobeam are obtained. By applying random error to these frequencies, measured frequencies are generated. The measured frequencies are considered as input data and inversely, the small scale parameter of the beam is obtained by minimizing a defined functional. The functional is defined as root mean square error between the measured frequencies and calculated frequencies by the DQM. Then, the conjugate gradient (CG) optimization method is employed to minimize the functional and the small scale parameter is obtained. Efficiency, convergence and accuracy of the presented hybrid method for small scale parameter estimation of the beams for different applied random error, boundary conditions, length-to-thickness ratio and volume fraction coefficients are demonstrated.

• Coupled systems mechanics
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• v.6 no.3
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• pp.369-376
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• 2017

Intermolecular interaction energies and conformer geometries of the hydrogen bonded acrylamide dimers have been studied by using the second-order Møller-Plesset (MP2) perturbation theory and the density functional theory (DFT) with 17 density functionals. Dunning's correlation consistent basis sets (up to aug-cc-pVTZ) have been used to study the basis set effects. The DFT calculated interaction energies are compared to the reference energy data calculated by the MP2 method and the coupled cluster method at the complete basis set (CCSD(T)/CBS) limit in order to determine the relative performance of the studied density functionals. Overall, dispersion-energy-corrected density functionals outperform uncorrected ones. The ${\omega}B97XD$ density functional is particularly effective in terms of both accuracy and computational cost in estimating the reference energy values using small basis sets and is highly recommended for similar calculations for larger systems.

• Food Science of Animal Resources
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• v.42 no.3
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• pp.536-555
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• 2022

The most abundant Orthoptera in Mexico is a small grasshopper (Sphenarium purpurascens) which is considered a food source with increased nutritional value due to its high protein content. Insect proteins have gained relevance because of their high potential as gelling, texturing, and extender agents in the food industry. The objective of this study was to evaluate the effect of substituting meat with a soluble protein extract from grasshopper obtained by alkalisation or alkalisation-piezoelectric ultrasound, on the techno-functional, physicochemical, and sensory characteristics of cooked meat models (sausages). The soluble protein was extracted in NaHCO₃ pH 8 and a piezoelectric ultrasound 5-mm sonotrode at 20 kHz with 99% amplitude. Different formulations with meat substitution: 0%, 5%, 10%, and 15% were prepared and characterised for their rheological behaviour, emulsion stability, weight loss by cooking, total protein content, colour, and texture. Sensory evaluation was conducted with consumers using a test involving check-all-that-apply and overall liking. The alkalisation-piezoelectric ultrasound method improved the solubility and the techno-functional properties of the soluble grasshopper protein when applied in sausages at maximum levels of 10% meat substitution. The sensory evaluation indicated that the formulation with 5% meat substitution exhibited the same acceptability as the control sample. Given these results, the soluble protein treated with alkalisation and piezoelectric ultrasound could be used as an extender in meat products.

• Membrane and Water Treatment
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• v.5 no.1
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• pp.31-40
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• 2014

Papermaking tobacco sheet is an important reclaimed process for cigarette making. Traditionally, the pressure driven membrane was often used to isolate the effective compounds from the tobacco sheet extract. However, this method is difficult to remove small ionic compounds. Besides, membrane fouling is a major problem for effective use of these pressure driven membrane technologies. In this study, the electrodialysis process is used to removal the chloride ions and nitrate ions, thus the smoking quality of papermaking tobacco sheet extract can get improved. Three types of electrolytes ($Na_2SO_4$, NaCl and HCl) are chosen to prevent the generation of precipitation. The results indicate that 0.1mol/L HCl at current density of $30mA/cm^2$ is the optimal condition for the electrodialysis process. The removal rates of the Cland $NO{_3}^-$ in tobacco sheet extract are 97% and 98.4%, respectively. The electrodialysis process cost was estimated to be 0.11$/L. Naturally, electrodialysis is not only technological feasible, environmental-friendly and economical-attractive for tobacco extract treatment.

• Advances in aircraft and spacecraft science
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• v.7 no.4
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• pp.353-369
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• 2020

This paper presents the flutter analysis and optimum design of axially functionally graded box beam cantilever wing section by considering various geometric and material parameters. The coupled dynamic equations of the continuous model of wing system in terms of material and cross-sectional properties are formulated based on extended Hamilton's principle. By expressing the lift and pitching moment in terms of plunge and pitch displacements, the resultant two continuous equations are simplified using Galerkin's reduced order model. The flutter velocity is predicted from the solution of resultant damped eigenvalue problem. Parametric studies are conducted to know the effects of geometric factors such as taper ratio, thickness, sweep angle as well as material volume fractions and functional grading index on the flutter velocity. A generalized surrogate model is constructed by training the radial basis function network with the parametric data. The optimized material and geometric parameters of the section are predicted by solving the constrained optimal problem using firefly metaheuristics algorithm that employs the developed surrogate model for the function evaluations. The trapezoidal hollow box beam section design with axial functional grading concept is illustrated with combination of aluminium alloy and aluminium with silicon carbide particulates. A good improvement in flutter velocity is noticed by the optimization.

• The Journal of Korean Physical Therapy
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• v.34 no.2
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• pp.51-56
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• 2022

Purpose: This study examined the effects of gym ball stabilization exercises on the physical functions of elementary school baseball players. Methods: The elementary school baseball players were assigned to an experimental group (n=21). The group performed gym ball stabilization exercises and the changes in the physical functions were measured using the visual response speed test, functional movements, physical balance ability, and pulmonary function. Results: The results of the visual response speed test showed changes in the time response speed. There was a significant change in the number of touches in 15 seconds in the upper arms and left and right legs (p<0.05) after 10 weeks. Also, there was a significant change in the reaction times of the left and right legs after 10 weeks (p<0.05). Further, there were significant differences in functional movements involving rotational stability and the total functional scores after 10 weeks (p<0.05). The player's body balance ability showed a significant difference after 10 weeks in the posterior-lateral and posterior-medial composite scores of the left and right legs (p<0.05). There was a significant change in the forced lung capacity and forced expiratory volume in 1 second after 10 weeks (p<0.05). Conclusion: These results show that the gym ball stabilization exercises effectively improved the visual response speed and functional movements, balance, and vital capacity of elementary school baseball players.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.24 no.5
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• pp.454-460
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• 2012

The purpose of the present work is to investigate the removal characteristics of positively charged filters for capturing negatively charged particles such as bacteria and virus in water. In order to reduce the pressure drop and increase the filtration efficiency, the filter media, modified by charge modifier having positive functional groups, is developed and evaluated. Improved liquid filters have been developed with the modified surface charge to capture and adsorb particles by electrokinetic interaction between the filter surface and particles contained in an aqueous liquid. The positively charged filter media is composed of glass fiber, cellulose and poly-ethylenimine resin for positively charging with the variation of volume ratio. The zeta potential value of the positively charged filter is +37.92 mV at the glass fiber and cellulose content ratio of 50 : 50 with resin content of 100%, while that of the PSL test particle is -23.5 mV at pH 7. The removal efficiency of the electro-positively charged filter is 98% for PSL particles of 0.11 ${\mu}m$, while that of the negatively charged filter is 7%. The positively charged filter media showed the potential to be an effective method for removing fine particles from the contaminated water for liquid filtration.

• Membrane and Water Treatment
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• v.7 no.1
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• pp.23-38
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• 2016

Batch adsorption of methyl orange (MO) from aqueous solution using three kinds of anion exchange membranes BI, BIII and DF-120B having different ion exchange capacities (IECs) and water uptakes ($W_R$) was investigated at room temperature. The FTIR spectra of anion exchange membranes was analysed before and after the adsorption of MO dye to investigate the intractions between dye molecules and anion exchange membranes. The effect of various parameters such as contact time, initial dye concentration and molarity of NaCl on the adsorption capacity was studied. The adsorption capacity found to be increased with contact time and initial dye concentration but decreased with ionic strength. The adsorption of MO on BI, BIII and DF-120B followed pseudo-first-order kinetics and the nonlinear forms of Freundlich and Langmuir were used to predict the isotherm parameters. This study demonstrates that anion exchange membranes could be used as useful adsorbents for removal of MO dye from wastewater.

• Structural Engineering and Mechanics
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• v.50 no.3
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• pp.403-417
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• 2014

The present paper addresses a general formulation for the thermo elastic analysis of a functionally graded cylindrical shell subjected to external loads. The shear deformation theory and energy method is employed for this purpose. This method presents the final relations by using a set of second order differential equations in terms of integral of material properties along the thickness direction. The proposed formulation can be considered for every distribution of material properties, whether functional or non functional. The obtained formulation can be used for manufactured materials or structures with numerical distribution of material properties which are obtained by using the experiments. The governing differential equation is applied for two well-known functionalities and some previous results are corrected with present true results.