• Proceedings of the KIEE Conference
• /
• 2007.07a
• /
• pp.1970-1971
• /
• 2007

The efficiency of such work highly depend on the worker's safety, who is protected by tools such as gloves, sleeves, blankets and flexible coverings among other manufactured natural-rubber goods. Use, storage and maintenance of these tools guarantee the quality and durability of the material. However, it might be observed that good tools made of such material are disapproved of when received from manufacturers or when they are removed from the warehouse for replacement. This work shows the experimental results obtained from ageing at a temperature of $100^{\circ}C$ for 48, 70 and 312 h, although the application of AC electrical tension in samples and the measuring of current leakage are presented. The measurements in samples were carried out with samples prepared from the deformulated commercial materials and respectively reformulated into thin films. The obtained results showed the mechanisms of conduction of samples in low and high electric fields. It was also identified an electric tension transition showing that in low fields it prevails the Ohm's law conduction, and in high electric fields it prevails the conduction of space charge limited current (SCLC). These results can support the natural rubber formulation process having as their main objective the reducing of the mechanisms that occur under high conduction current in high electric fields, which leads the material to a dielectric breakdown. It is necessary to research this raw material from different internationally standard clones to characterize dielectric and electric properties for industrial applications. Moreover, this natural material has a low commercial price when compared to the synthetic ones.

• Elastomers and Composites
• /
• v.48 no.1
• /
• pp.61-66
• /
• 2013

A family of Cr(III) complexes supported on tridentate dibenzimidazolyl ligands having a general formula: $[N(CH_3)(CH_2)_2(Bm-R)_2]CrCl_3$ [where Bm = benzimidazolyl, R = H (3a); -Me(3b); -Bn (3c)] have been synthesized and utilized them for the trans-1,4-specific polymerizations of 1,3-butadiene (BD), activated with methylalumoxane (MAO). The activity of BD polymerizations was sensitive to the type of ligand on the Cr metal, so that the activity decreases in the order of 3a > 3c > 3b. All the catalysts combined with MAO yielded polybutadienes with perfect trans-1,4 structure with moderate molecular weight.

• Journal of Adhesion and Interface
• /
• v.8 no.2
• /
• pp.15-21
• /
• 2007

To prepare a natural rubber-based pressure-sensitive adhesive (PSA) for protection film of opto- functionalized sheet, natural rubber (NR) was blended with a DCPD type tackifier and three types of aliphatic hydrocarbon resins, respectively. Also, to supply low cohesion strength of NR, in the fixed ratio of tackifier, synthetic rubber, styrene-isoprene-styrene (SIS) block copolymer was blended with NR as a function of SIS contents. PSA performance of prepared PSAs was evaluated using probe tack and peel strength. Probe tack of NR/tackifier blends was increased with increasing tackifier contents, and showed maximum peak. In addition, probe tack of NR/tackifier blends slightly increased with increasing softening point of aliphatic hydrocarbon resins. Their peel strength increased up to 50 wt% of tackifier contents, but in the over contents of tackifier, they showed stick-slip failure mode. Finally, probe tack of NR/SIS/tackifier blends showed the maximum values at 20~40 wt% of tackifier contents, but at 20 wt% of tackifier contents, they showed fibrillation. For this reason, peel strength showed maximum values at 40 wt% of tackifier contents.

• Journal of the Korean Society of Radiology
• /
• v.12 no.6
• /
• pp.777-783
• /
• 2018

The purpose of this study was to investigate the degree of tearing of the rubber when the spike of the syringe connector was connected to the bottle of the contrast medium composed of the rubber compound type and to investigate the presence of the synthetic rubber due to tearing and grinding and the size of the pulverized product when the pulverized matters rubber was detected. As a result, in the case of tearing degree, the front side of the first contact with the end of the syringe connector was torn more than the back side by about $3.14{\pm}0.04mm$, and the pulverized matters was detected on average 7 to 15 on the 10 contrast mediums. The average particle size was measured to be about $7.89{\pm}0.31{\mu}m$. In addition, it is necessary to develop a micro_filter type automatic injection system for blocking off the pulverized matters as well as additional experiments through various experiments and analysis methods, and it is considered that interest of related organizations will be needed in preparation of fatal accidents when pulverized matters is introduced.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2007.11a
• /
• pp.1145-1148
• /
• 2007

Resilient materials are generally used for the floating floors to reduce the floor impact sound. Dynamic stiffness of resilient material, which has the most to do with the floor impact sound reduction. The resilient materials available in Korea include EPS (Styrofoam), recycled urethane types, EVA (Ethylene Vinylacetate) foam rubber, foam PE (Polyethylene), glass fiber & rock wool, recycled tire, foam polypropylene, compressed polyester, and other synthetic materials. In this study, we tested floor impact sound reduction characteristic to a lot of kinds of resilient material. The result of test showed that the amount of the heavy-weight impact sound reduction appeared by being influenced from this dynamic stiffness of resilient material. The dynamic stiffness looked like between other resilient materials, a similar to the amount of the heavy-weight impact sound reduction was shown.

• Journal of the Korean Society of Safety
• /
• v.30 no.2
• /
• pp.14-20
• /
• 2015

The content of hazardous heavy metal of materials used in playground facility for children was investigated using X-ray fluorescence (XRF) and inductively coupled plasma (ICP) analyses, In order to examine the content of hazardous heavy metals according to the material color, four colors, i.e., green, red, yellow and blue, were categorized on the materials used. The highest lead content is observed in the yellow plastic samples. The yellow samples with relatively high lead content show that the chrome content is also high. This can explained that lead chromate, so-called chromium yellow, is normally used as a main pigment to express the yellow color. Therefore, it is concluded that hazardous heavy metal detected in the materials of playground facility for children is due to the pigments used for coloring. Based on above findings, the relationship between the color of materials used in playground facility for children and the content of hazardous heavy metal is discussed.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2008.04a
• /
• pp.830-834
• /
• 2008

Resilient materials are generally used for the floating floors to reduce the floor impact sound. Dynamic stiffness of resilient material, which has the most to do with the floor impact sound reduction. The resilient materials available in Korea include EPS (Styrofoam), recycled urethane types, EVA (Ethylene Vinylacetate) foam rubber, foam PE (Polyethylene), glass fiber & rock wool, recycled tire, foam polypropylene, compressed polyester, and other synthetic materials. In this study, we tested floor impact sound reduction characteristic to a lot of kinds of resilient material. The result of test showed that the amount of the Light-weight impact sound reduction appeared by being influenced from this dynamic stiffness of resilient material. As the decreasing dynamic stiffness of resilient material, the impact sound reduction amount is increased, especially in the low frequency domain.

• Elastomers and Composites
• /
• v.54 no.3
• /
• pp.232-240
• /
• 2019

A superabsorbent hydrogel (SAH) can absorb and retain water weighing more than a hundred times of their dry weight because of their three-dimensional hydrophilic structure. To fabricate an SAH, itaconic acid (IA) and vinyl sulfonic acid (VSA) were subjected to radical polymerization in an aqueous solution, wherein IA and VSA were neutralized, and then, a crosslinker and a thermal initiator were added in sequence. The structure of poly(IA-co-VSA) was characterized using attenuated total reflectance Fourier-transform infrared spectroscopy. We also studied the changes in the absorption properties of the SAH composites according to the polymerization temperature, degree of neutralization, type and content of the initiator used, and type and content of the crosslinker used. Thus, we could determine the effects of some synthetic factors on the absorption properties of the SAH.

• Elastomers and Composites
• /
• v.25 no.1
• /
• pp.13-19
• /
• 1990

The purpose of this study is to estabilish the synthetic condition of polyurhethane elastomer for excellent properties. Polyurethane elastomer which have different NCO percentage and hard segment contents was synthesized by casting method. And the effects of hard segment contents were investigated by analytical methods such as IR, DSC, etc. [NCO]/[OH] ratio was proper at the range $1.02{\sim}1.05$. By IR absorption peak($1250cm^{-1}$) which indicate interurethane hydrogen bond it was confirmed that hard segment were crystallized. Melting point that was determined by DSC showed the effects of hard segment contents, phase mixing and crystalline size.

• Elastomers and Composites
• /
• v.47 no.1
• /
• pp.9-17
• /
• 2012

Herein, life time prediction based on the deterioration of physical properties of chloroprene rubber (CR)aged by heat and seawater was performed. CR samples were experienced an accelerated test at $80^{\circ}C$, $100^{\circ}C$, $120^{\circ}C$ for heat aging, and $40^{\circ}C$, $60^{\circ}C$, $80^{\circ}C$ for seawater aging for 20,000 hrs. The change in tensile strength, maximum elongation,hardness was measured. As a result, the decrease in elongation was a major factor causing failure. The life time estimated using an Arrhenius model was 125 years at $23^{\circ}C$ for thermal aging and 9 years at $23^{\circ}C$ for seawater aging. SEM and elemental analysis reveal that cracks were generated and the content of oxygen was increased for CR agined by seawater. FT-IR spectrum shows the new C-O and C = O bonds were generated by the chemical reaction with seawater. Also, the glass transtion temperature was increased and the thermal decomposition was decreased by seawater aging.