• Title/Summary/Keyword: synthetic rubber

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A Study on Examination of Application in Waste Filled Land and Performance Evaluation as Waterproofing Material by the Spray Water-Soluble Rubber Asphalt (뿜칠형 수용성 고무화 아스팔트 차수재의 성능평가 및 폐기물 매립지 적용성 검토에 관한 연구)

  • 오상근;김형무;정문정;최은수
    • Journal of the Korea Institute of Building Construction
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    • v.1 no.2
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    • pp.165-173
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    • 2001
  • This study examinated the application in construction field and the development of waterproofing material system by the spray water-soluble rubber asphalt to solve the problems of synthetic polymer sheet and gio membrane(A mat sheet of Bentonite) that had been used domestic waterproofing material in advance. As the result of study, characters of study water-soluble rudder asphalt are the follows: 1) The amount of water absorption was '0.06'g and the seepage quality was '0'g in result. 2) The tensile strength was about 30.7kgf/$\textrm{cm}^2 and the elongation was about 72.4% in result. 3) After reliance of temperature test had been ended, the tensile strength was about 72.4kgf/$\textrm{cm}^2 in low temperature and about 30.7kgf/$\textrm{cm}^2 in normal temperature. 4) After acid and alkaline treatment had been ended, the tensile strength was about 19.7kgf/$\textrm{cm}^2$ and about 21.9kgf/$\textrm{cm}^2 in result. 5) After chlorine ion treatment had been ended, the tensile strength was 28.5kgf/$\textrm{cm}^2$ and the elongation was 250% in result. 6) The impact performance was subsided at 1.5m height. 7) After promotion weathering had been ended, the tensile and elongation was about 26.0kgf/$\textrm{cm}^2, 214% in result. So, this study can propose the spray water-soluble rubber asphalt to satisfy the and durability of waste filled land.

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Effect of Vinyltriethoxysilane Content on Mechanical and Physical Properties of Precipitated Silica Reinforced Silicone Rubber (비닐트리에톡시실란 함량에 따른 습식실리카로 충전된 실리콘 고무의 기계적 및 물리적 물성)

  • Jin, Sung-Hoon;Hong, Jin-Ho;Kim, Il;Yun, Ju-Ho;Shim, Sang-Eun
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.342-349
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    • 2011
  • The effect of the amount of vinyltriethoxysilane (VTEOS) in precipitated silica filled silicone rubbers was extensively investigated in terms of the change of mechanical properties, heat resistance, oil resistance, compression set, resilience, and curing characteristics. As the content of VTEOS increased from 0 to 2.0 phr, the hardness of the silicone rubber increased, however, tensile strength, elongation at break, and tear strength decreased. From heat resistance test, the change of mechanical properties was pronounced for silicone rubber treated with more VTOES. The best heat resistance was achieved at 2.0 phr VTOES. In addition, oil resistance was proportionally improved with VTEOS content. From oil resistance test. it was found that the decrease in hardness and maximum elongation was reduced for VTEOS-added systems. Finally, resilience, compression set, degree of cure and crosslink density were significantly enhanced with the amount of VTEOS.

Comparative Study on Compressive Strength of Concrete with New Sand-Cap and Neoprene Pad

  • Park, Young-Shik;Suh, Jin-Kook
    • International Journal of Concrete Structures and Materials
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    • v.2 no.1
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    • pp.15-19
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    • 2008
  • The most typical capping method for concrete structures is a sulfur-mortar compound capping, provided it satisfied the standard criterion set forth by ASTM C 617, but this conventional bonded-type method has many problems. It exhibits relatively the smaller unreliable value of the strength of high-strength concrete due to the differences of elasticity and strength between the cylinder and the cap, and manifests poor serviceability such as dangerous working tasks or a waste of the working time. To prevent these problems, unbonded-type capping methods have taken the place of the conventional methods in recent years. One of the popular methods is the use of synthetic rubber like a neoprene pad. Serious problems still remain in this method, which include the consideration of its chemical characteristics in consideration of the selection, the safekeeping and the economy of the pads. Moreover, the synthetic rubber pads cannot be used in concrete cylinder with strength greater than 80 MPa according to ASTM C 1231-00. New 'sand-capping method' presented in this study, can be applicable to the compressive strength evaluation of the high strength concrete in the range of $70{\sim}100\;MPa$. This new method has better simplicity and reliability than those of existing 'sand-box', because usual materials such as standard sand and simply-devised apparatus are used for the capping system. The statistical analysis of the test results revealed that the new sand-capping method exhibited the smallest deviation and dispersion, attesting for its much better reliability than other methods specified in ASTM C 1231/1231M.

Genotoxicity of Heavy Metals among the Particulates in the Working Environment as Assessed by Tradescantia-Micronucleus (Trad-MCN) Assay (자주달개비 미세핵 분석법을 이용한 작업환경내 총 먼지 중 수용성 추출물의 유전독성 평가)

  • Shin, Hae-Shik;Kim, Jin-Kyu;Lee, Jae-Hwan;Hwang, Kap-Sung;Kim, Kyun;Lee, Jeong-Joo;Lee, Jin-Hong
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.639-646
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    • 2003
  • In this study, we evaluated genotoxicity of heavy metals among particulates with Tradescantia-micronucleus (Trad-MCN) assay in the various working environment. In a synthetic fiber factory and a rubber factory, chromium concentration was higher than any other heavy metals. On the other hand, nickel concentration was the highest in a semi-conductor factory. The difference in genotoxicity among the working environment was statistically significant as Trad-MCN frequencies were 4.07 $\pm$0.35 MCN/100 tetrads (p< 0.01) for the synthetic fiber factory,5.73 $\pm$0.81 MCN/100 tetrads (p< 0.01) for the rubber factory, and 15.60$\pm$2.58 (p< 0.01) (p< 0.001) for the semi -conductor factory. As a result, heavy metals among particulates in the working environment can be considered to have hazardous potential to human health, although they cannot directly induce DNA damage to the workers in the working environments.

High power lithium ion polymer batteries (IV): Nano-sized cathode materials manufactured in a single synthetic step using united eutectic self-mixing method

  • An, Uk;Ra, Dong-Il;Lee, Beom-Jae;Han, Gyu-Seung
    • Rubber Technology
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    • v.6 no.2
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    • pp.91-98
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    • 2005
  • Nano-sized cathode materials for high power lithium ion polymer battery are easily and economically prepared using united eutectic self-mixing method without any artificial mixing procedures of reactants and ultra-miniaturization of products. While the micro-sized $LiNi_{0.7}Co_{0.3}O_2$ exhibits the discharge capacities of 167.8 mAh/g at 0.1C and 142.5 mAh/g at 3.0C, those of the nano-sized $LiNi_{0.7}Co_{0.3}O_2$ are 170.8 mAh/g at 0.1C and 159.3 mAh/g at 3.0C. In the case of $LiCoO_2$, the micro-sized $LiCoO_2$ exhibits the discharge capacities of 134.8 mAh/g at 0.1C and 118.6 mAh/g at 5.0C. Differently, the nano-sized $LiCoO_2$ exhibits the discharge capacities of 137.2 mAh/g at 0.1C and 131.7 mAh/g at 5.0C.

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Studies on the Chemical Treatment of Silica for Synthetic Rubber Reinforcement(I) - Silica Treatment by MDI- (합성(合成)고무 보강제(補强劑) Silica의 화학처리(化學處理)에 관(關)한 연구(硏究)(I) -Silica의 MDI 처리(處理)-)

  • Jin, Je-Yong;Kim, Hong-Seon;Choi, Sei-Young
    • Elastomers and Composites
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    • v.30 no.1
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    • pp.20-31
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    • 1995
  • The purpose of this study is to investigate the reinforcement of inorganic filler silica, treated by MDI about SBR vulcanizate. The characteristics of vulcanization, physical properties, surface properties and dynamic properties were investigated after mixing those silica with SBR and unmodified silica with SBR. In this experiment only the quantity of silica was variable. In the vulcanization characteristics tested by rheometer, S-series showed the fastest scorch $time(t_{10})$ and optimum cure $time(t_{90})$. And in test or tensile characteristics hardness, tensile strength, 100%, 300% modulus and elongation were all appeared in the order of M>S-series. The characteristic bonding of urea between unmodified silica and MDI could be confirmed in IR spectrum. The shapes of silicas treated chemically were observed by SEM. And the dispersion of the filler in the SBR composite was uniform. In the dynamic characteristics by the RDS, the order of elastic modulus G' values was as follows : M>S-series, and also the order of damping values was as follows : M>S-series.

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A Study on the Properties of Flame Retardant and Fire Safety of Silicone Rubbers Added Reinforcing Fillers (보강성 충진제를 첨가한 실리콘 고무의 난연 및 화재안전 특성에 관한 연구)

  • Park, Seung Ho;Lee, Sung Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.4
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    • pp.349-355
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    • 2019
  • A fire, be it caused intentionally or unintentionally, leads to economic loss and physical damage, and requires digestion. The number of fires is increasing yearly, and electrical fires account for more than 30% among the main causes of fires. Electric wires that catch fire typically employ silicone coatings; silicone has organic as well as inorganic properties. Silicon is a natural, nonexistent, synthetic product with numerous applications. In this study, a silicon rubber for application in wires was prepared by high-temperature vulcanization (HTV) with a Shore A hardness of 70. We report results for the flame retardancy test and the fire safety characteristics via inorganic analysis. For this, a quartz inorganic material was added to the wire specimen, and 18% powdered extinguishing agent ammonium phosphate and expanded vermiculite respectively. Thus, expanded vermiculite showed the best flame retardancy and fire safety characteristics.

Exposure Characteristics of 1,3-Butadiene Exposed Workers (1,3-부타디엔 제조 및 취급 근로자의 노출특성에 관한 연구)

  • Choi, Ho Chun;An, Sun Hee;Lee, Hyun Seok;Park, Young Wook;Kim, Kyung Soon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.4
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    • pp.321-327
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    • 2009
  • 1,3-butadiene is classified as suspected human carcinogen, group A2(American Conference of Governmental Industrial Hygienists, ACGIH). In Korea, 1,3-butadiene has been used as a raw material; monomer, homopolymer, polybutadiene latex, acrylonitrile-butadiene-styrene(ABS) and styrene-butadiene rubber(SBR), in the petrochemistry and precision chemistry industry. As petrochemistry industry in Korea has been developed, the potential exposure possibility of 1,3-butadiene to workers can be increased. Therefore the purpose of this study is to evaluate airborne 1,3-butadiene concentration and workers' exposure levels in the workplace using 1,3-butadiene. Air samples were collected with 4-tert-butyl catechol(TBC) charcoal tube(100 mg/50 mg) and were analyzed by gas chromatograph/flame ionization detector(GC/FID) according to the Choi's method(2002). Geometric mean (GM) and arithmetic mean (AM) of total 59 workers' exposure concentrations to airborne 1.3-butadiene were 0.042 ppm and 1.51 ppm, respectively. Although most samples were lower than 1ppm, 2 samples(21.5ppm and 33.1ppm as 8hr-TWA) were exceeded the Korean standard(2ppm) over 10 times at the repair process in synthetic rubber and resin manufacture industry. 14 samples(41%) of total 34 short-term air samples were exceeded the Korean standard(10ppm as STEL) of Ministry Labor. 1,3-butadiene concentration(GM) in the synthetic rubber and resin manufacture industry(7.87ppm) was significantly higher than that in the monomer manufacure industry (0.35ppm)(p<0.05). Also in the sampling and repair process, each GM(range) was 1.39ppm(N.D.-469.6ppm) and 7.85ppm(N.D.-410.2ppm). In conclusion, it depends on the industry and process, 1,3-butadiene can be exposed to workers as high concentration for short-term.

A Study on the Performance Evaluation of Water(wash out) Resistance of 5-Type Repair Materials in Water Leakage of Underground Concrete Structures (지하 콘크리트 구조물 누수부위에 시공되는 5계열 보수재료의 유실 저항 성능 평가 연구)

  • Kim, Soo-Yeon;Yoo, Jae-Yong;Oh, Sang-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.61-68
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    • 2020
  • In this study, the international standard ISO TS 16774 Part 3 Test Method for Water (wash out) Resistance and KS F 4935 「Sealant Injection type for water leakage maintenance of adhesive flexible rubber asphalt series」, which are standardized as a quality control method of injection type repair materials used for water leakage cracks in underground concrete structures, are currently used in Korea. As a result, considering the performance criteria of "mass change rate -0.1%" stipulated in KS F 4935, the remaining 13 types repair materials, excluding RG-2 of synthetic rubber and UG-1 of urethane, need to be reviewed for stabilization of the loss resistance due to the flow of ground water. The results of this study are determined to be available as a basic indicator for the selection of repair materials used for cracks in concrete structures. In addition, it is expected that the results of this study can be utilized as reference data that can be reflected in the improvement of the quality of repair materials that will be researched and developed later.

The Development of Concepts on Sound Propagation of Children (소리의 전달에 대한 아동의 개념 발달 연구)

  • Shin, Eunsoo;Kim, Eunjung
    • Korean Journal of Child Studies
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    • v.34 no.4
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    • pp.19-36
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    • 2013
  • This study examined concept development in children in terms of sound propagation. The subjects consisted of 240 five-, seven-, and ten-year-old children from three kindergartens and two primary schools respectively. The instrument used for the purposes of this study was the examination instrument on sound as developed by the SPACE Project in the UK. The concepts related to sound were classified into five stages including : no recognition, egocentric concept, initial mental models, synthetic mental models, and scientific mental models. The results revealed the existence of significant differences in terms of the types of concept that children were aware of, according to age and context. Most five-, seven-, and ten-year-old children revealed egocentric concepts related to every sounds, drum, rubber band context, however, most five-, seven-, and ten-year-old children revealed their recognition of the synthetic models of sound propagation when using the string telephone context. These results have implications for the contents of science education for children when it comes to the development of concepts related to sound propagation.