• 제목/요약/키워드: synthetic polymers

검색결과 169건 처리시간 0.035초

Chiral Mesophase Derived from Achiral Polymers with Banana-Shaped Mesogens and Their Model Compounds

  • Choi, E-Joon;Kim, Eun-Chul;Kwon, Myung-Hun;Zin, Wang-Cheol;Kim, Young-Chul;Paek, Sang-Hyon
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.242-243
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    • 2006
  • In this work, we report the synthesis and characterization of azomethineester polymers that consist of banana-shaped mesogen in their backbone. Two parts of the key structure of five-ring bent-core mesogen were modified by connecting different angle of central unit (Ar), and introducing lateral substituent into the outer ring (X). The synthetic details includes (1) placing the dioxydodecamethylene unit as a flexible spacer, (2) possessing 2,3- or 2,7-naphthylene, or 1,2-phenylene connection on the central unit, and (3) introducing fluorine or chlorine substituent (X = F or Cl) into the outer phenylene unit.

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Silk Protein as a Fascinating Biomedical Polymer: Structural Fundamentals and Applications

  • Ki, Chang-Seok;Park, Young-Hwan;Jin, Hyoung-Joon
    • Macromolecular Research
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    • 제17권12호
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    • pp.935-942
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    • 2009
  • Silk is a textile material, as well as one of the oldest biomaterials. However, the recent progress of biomedical science and technology has led to the replacement of silk by various biomaterials based on synthetic polymers. Despite the wide variety of biomaterials available, these materials suffer certain limitations that prevent them from meeting the various demands of the medical field. Therefore, silk continues to attract considerable interest as a promising biomaterial. This paper explains the fundamentals of silk protein, and reviews the many applications of silk biomedical polymers.

Synthesis and Mesomorphism of Polymers with Banana-Shaped Mesogens in the Main Chain

  • Choi, E-Joon;Zin, Wang-Cheol;Kim, Young-Chul;Paek, Sang-Hyon;Chien, Liang-Chy;Samulski, Edward T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.171-174
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    • 2006
  • In this work, we report the synthesis and characterization of azomethine-ester polymers that consist of banana-shaped mesogen in their backbone. Two parts of the key structure of five-ring bent-core mesogen were modified by connecting different angle of central unit (Ar), and introducing lateral substituent into the outer ring (X). The synthetic details includes (1) placing the dioxydodecamethylene unit as a flexible spacer, (2) possessing 2,3- or 2,7-naphthylene, or 1,2-phenylene connection on the central unit, and (3) introducing fluorine or chlorine substituent (X = F or Cl) into the outer phenylene unit.

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LIGHT EMITTING POLYMER MATERIALS: THE WORKING BASE FOR FLEXIBLE FULL COLOR DISPLAYS

  • Falcou, Aurelie;Becker, Heinrich;Breuning, Esther;Buesing, Arne;Heun, Susanne;Parham, Amir;Spreitzer, Hubert;Steiger, Juergen;Stoessel, Philipp
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.1053-1056
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    • 2003
  • Progress in light emitting materials is presented. New polymers based on the Spiro concept show encouraging properties in electroluminescence performance and lifetime. The spiro-polymers can be tailor made to fit the RGB color requirements of a full color display. This class of materials showed recently very promising performance for white emission as well. They are readily soluble, show excellent thermal stability and can be processed by printing or through simple synthetic modification by photolithography technology.

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Poly-${\varepsilon}$-caprolactone(PCL) / Polyvinyl chloride(PVC) 블렌드의 기계적 성질 및 생분해성

  • 서해정;하기룡;강선철
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2002년도 생물공학의 동향 (X)
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    • pp.379-380
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    • 2002
  • 기계적 성질이 우수한 PVC와 생분해성이 우수한 고분자로 알려져 있는 폴리카프로락톤 (PCL)과 블렌드하여 새로운 소재의 생분해성 필름을 제조하여 생분해성 효과에 대해 조사하였으며, 그 결과 PCL/PVC 필름의 표면은 8주 후에 다수의 작은 구멍이 형성되었으며, 이러한 결과는 PCL의 함량이 9%로 낮아도 생분해성을 지닌다는 것을 의미한다.

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생체분해성 고분자의 합성 및 물성에 관한 연구 -Poly (glycine-co-lactic acid) 와 Poly (glycine-co-glycolic acid)- (Synthesis and Physical Properties of Biodegradable Polymers -Poly (glycine-co-lactic acid) and Poly (glycine-co-glycolic acid)-)

  • 성용길;김정엽
    • 대한의용생체공학회:의공학회지
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    • 제9권1호
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    • pp.37-46
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    • 1988
  • Synthetic biodegradable polymers are of great interest for biomedical applications such as surgical sutures and drug delivery systems. The copolymers of ${alpha}-amino$ acids and ${alpha}-hydroxy$ matrices having the required permeability for drugs. Poly (glycine.co-lactic acid) and poly (glycine-co-glycolic acid) have been synthesized by ring-opening polymerization. Morpholine-2, 5-diane, lactide, and glycolid have been used as starting materials for polydepsipeptides. The synthesized monomers and copoylmers have been identified by NMR and FT-lR spectrophotometer. The thermal properties and glass transition temperatures ($T_g$) of the copolymers have been measured by differential scanning calorimetry. The $T_g$ values of poly (glycine-co-lactic acid) and poly (glycine co.glycolic acid) are increased with increasing mole fraction of morpholine-2, 5-dione in the copolymers.

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Synthesis of Red, Green, Blue Light Emitting Polymers and Their Electroluminescence Properties

  • Park, Lee-Soon;Han, Yoon-Soo;Kim, Sang-Dae;Kim, Dong-Uk
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.123-124
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    • 2000
  • Three types of conjugated polymer, poly(DFPZ-AV), poly(MEHPV-PV) and poly(BFMP12-BPV), were obtained by Honer-Emmons condensation using potassium tert-butoxide from the synthesized monomers in anhydrous tetrahydrofurane. The Honer-Emmons reaction was found to be a useful synthetic method for the preparing a wide range of EL polymers. The EL devices using poly(DFPZ-AV), poly(MEHPV-PV) and poly(BFMP12-BPV) as light emitting layer gave red, green and blue emission, respectively, which were in close chromaticity with the CIE 1931 NTSC standard.

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Synthesis of Hollow Silica by Stöber Method with Double Polymers as Templates

  • Nguyen, Anh-Thu;Park, Chang Woo;Kim, Sang Hern
    • Bulletin of the Korean Chemical Society
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    • 제35권1호
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    • pp.173-176
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    • 2014
  • The hollow $SiO_2$ spheres with uniform size were synthesized by a modified Stober method under the control of polyelectrolytes (PSS and PAA) as templates. This synthetic route includes the formation of spherical colloid micelle in ethanol solution, hydrolysis of TEOS under control of ammonia, and the removal of polyelectrolyte by washing or calcination. Hollow silica spheres with controllable core diameters between 100 and 270 nm and wall thickness between 15 and 50 nm have been synthesized. The influence of template solution concentration and solvent and dispersant on the formation of silica hollow spheres is studied and reported in detail.

Myocardial tissue engineering using electrospun nanofiber composites

  • Kim, Pyung-Hwan;Cho, Je-Yoel
    • BMB Reports
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    • 제49권1호
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    • pp.26-36
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    • 2016
  • Emerging trends for cardiac tissue engineering are focused on increasing the biocompatibility and tissue regeneration ability of artificial heart tissue by incorporating various cell sources and bioactive molecules. Although primary cardiomyocytes can be successfully implanted, clinical applications are restricted due to their low survival rates and poor proliferation. To develop successful cardiovascular tissue regeneration systems, new technologies must be introduced to improve myocardial regeneration. Electrospinning is a simple, versatile technique for fabricating nanofibers. Here, we discuss various biodegradable polymers (natural, synthetic, and combinatorial polymers) that can be used for fiber fabrication. We also describe a series of fiber modification methods that can increase cell survival, proliferation, and migration and provide supporting mechanical properties by mimicking micro-environment structures, such as the extracellular matrix (ECM). In addition, the applications and types of nanofiber-based scaffolds for myocardial regeneration are described. Finally, fusion research methods combined with stem cells and scaffolds to improve biocompatibility are discussed. [BMB Reports 2016; 49(1): 26-36]

환형 폴리옥시에틸렌 존재하의 피롤의 화학적 중합에 관한 연구 (Study on the Chemical Polymerization of Pyrrole in the Presence of Cyclic Poly(oxyethylene)s)

  • 차국찬;김진환;배진영
    • 폴리머
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    • 제26권5호
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    • pp.568-574
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    • 2002
  • 호스트 분자로서 환형 폴리옥시에틸렌을 사용한 inclusion 화합물을 이용하여 수용액상에서 피롤의 화학적 중합을 수행하였다. 이와 같은 합성 전략은 수용액상에서 화학적 산화방법에 의해 견고한 방향족 고분자의 사슬을 성장시킬 수 있는 가능성을 나타내며, 수용성 올리고 또는 폴리피롤을 손쉽게 얻을 수 있는 방법을 제시하고 있다. 본 연구에서는 부분적으로 고분자 주사슬에 환형 폴리옥시에틸렌을 함유한 수용성 폴리피롤을 얻었으며, NMR, IR, UV 및 MALDI-TOF MS 분석 등을 통하여 그 구조를 확인하였다.