• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.33.1-33.1
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• 2009

To date, nanostructured tungsten oxides with a variety of stoichiometries, such as WO3, WO2.9, W18O49, and WO2, have been prepared, because they are promising candidates for applications such as gas sensors, photocatalysts, electrochromic devices, and field emission devices. Among them, W18O49 and WO2 have been widely studied due to their outstanding chemical sensing, catalytic, and electron emissive properties. Here we report, for the first time, a one-pot solution-phase route to synthesizing a novel composite hierarchical hollow structure without adding catalysts, surfactants, or templates. The products, consisting of a WO2 hollow core sphere surrounded by a W18O49 nanorod shell (yielding a sea urchin-like structure), were generated as discrete structures via Ostwald ripening. To our knowledge, this type of composite hierarchical core/shell structure has not been reported previously. The morphological evolution and the detailed growth mechanism were carefully studied. We also demonstrate that the size of the hollow urchins is readily tunable by controlling the reactant concentrations.Interestingly, although bulk tungsten oxides are weakly paramagnetic or diamagnetic, the as-prepared products show unusual ferromagnetic behavior atroom temperature. The urchin structures also show a very high Brunauer-Emmet-Teller (BET) surface area, suggesting that they may potentially be applied to chemical sensor or effective catalyst technologies.

• BMB Reports
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• 제32권2호
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• pp.203-209
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• 1999

Three-week grown Arabidopsis thaliana leaves were wounded by cutting whole leaves with a razor blade into pieces (about$3\;mm\;{\times}\;3\;mm$) submerged in various solutions, and incubated in a growth chamber for 24 h. We measured and compared activities of several enzymes such as phenylalanine ammonia-lyase (PAL), tyrosine ammonia-lyase (TAL), thioredoxin, thioredoxin reductase, thioltransferase, glutathione reductase, and $NADP^+$ -malate dehydrogenase. PAL activity was decreased in $HgCl_2$-, $CdCl_2$-, and glyphosate-treated leaf slices, and could not be detected after treatment with $CdCl_2$. TAL activity was found to be maximal in the $CdCl_2$-treated leaf slices. Activity of thioredoxin, a small protein known as a cofactor of ribonucleotide reductase and a regulator of photosynthesis, was significantly increased in the $CdCl_2$-treated leaf slices, while thioredoxin reductase activity was maximal in the $HgCl_2$-treated leaf slices. Thioltransferase and glutathione reductase activities were significantly decreased in the $HgCl_2$-treated leaf slices. $NADP^+$ -malate dehydrogenase activity remained relatively constant after the chemical treatments. Our results strongly indicate that sulfhydryl-related and phenylpropanoid-synthesizing enzyme activities are affected by chemical treatments such as hydrogen peroxide, heavy metals, and glyphosate.

• 한국결정성장학회지
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• 제5권3호
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• pp.278-283
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• 1995

금속티타늄 분말과 $H_2O_2$와의 반응물에 KOH용액을 첨가하는 습식법에 의해 티탄산칼륨 섬유를 합성하고, 합성된 생성물을 XRD, SEM, FT-IR 등에 의해 검토하였다. 습식 합성법의 경우, $KOH/TiO_2$ 몰비, 합성시간, aging 시간등이 주로 최종 생성물에 영향을 주었다. $KOH/TiO_2 = 1/1$, 합성시간 24시간, aging 시간 24시간 및 하소 온도 $900^{\circ}C$에서의 생성물은 주로 potassium tetratitanate이었으며, 10 ~ 20mm의 가늘고 긴 장섬유이었다. 합성시간이 길어질수록, 그리고 KOH량이 적어질수록, potassium tetratitanate는 potassium hexatitanate로 바뀌면서 섬유의 길이는 짧아졌다.

• 농촌계획
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• 제13권3호
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• pp.73-82
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• 2007

Recently, plans to revitalize rural areas in addition to farming are actively having been groped since given agricultural conditions destituted. One of the plan is the 'Rural Tourism' which to sell to urbanites by merchandising rural and pleasant characteristics possessed by rural areas. As a part of the rural-urban exchange, analyzed the features of the experience programs operated by each village by selecting 152 rural-mountain villages where is supporting and presented results by synthesizing above conclusion. The results acquired through such research are as following. Currently, villages operate mainly with the experience program related to general agricultural life styles by synthesizing special features of experience programs with high frequency in operations as the present status of the rural-mountain villages and showed negative trends dependant to the existing natural resources and easy in operations. Moreover, the operation of the experience which are expected to publicize the village and create large incomes were insufficient, analyzed not to be stimulate purchasing activities by lack of connections among experience programs and only simple staged experiences are mainly operated due to low operation frequency of experience programs which can be operated with special interests or professional characteristics.

• 한국분말재료학회지
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• 제24권3호
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• pp.248-253
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• 2017

In this study, we investigate the effect of the diffusion barrier and substrate temperature on the length of carbon nanotubes. For synthesizing vertically aligned carbon nanotubes, thermal chemical vapor deposition is used and a substrate with a catalytic layer and a buffer layer is prepared using an e-beam evaporator. The length of the carbon nanotubes synthesized on the catalytic layer/diffusion barrier on the silicon substrate is longer than that without a diffusion barrier because the diffusion barrier prevents generation of silicon carbide from the diffusion of carbon atoms into the silicon substrate. The deposition temperature of the catalyst and alumina are varied from room temperature to $150^{\circ}C$, $200^{\circ}C$, and $250^{\circ}C$. On increasing the substrate temperature on depositing the buffer layer on the silicon substrate, shorter carbon nanotubes are obtained owing to the increased bonding force between the buffer layer and silicon substrate. The reason why different lengths of carbon nanotubes are obtained is that the higher bonding force between the buffer layer and the substrate layer prevents uniformity of catalytic islands for synthesizing carbon nanotubes.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1995년도 Proceedings of the Korea Automation Control Conference, 10th (KACC); Seoul, Korea; 23-25 Oct. 1995
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• pp.344-347
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• 1995

The standard estimation and filtering theory are well known and has recently been incorporated with the H$_{\infty}$ optimization techniques where the parametrizations of all estimators and filters are utilized. The issue of reducing its order is always of interest. This paper presents a method for synthesizing low-order stable state estimators. The method presented in this paper is based on the utilization of a free parameter function contained in the parametrization of all state estimators. The results obtained in the paper are compared with standard results on low-order estimators. Both results are shown to be the same in a sense of its orders, but the approaches taken are largely different. It is also shown in the paper that the method can easily and directly be extended to the Kalman filters and the H$_{\infty}$ (sub)optimal filters. Consequently, the orders of all state estimators, Kalman filters, and H$_{\infty}$ filters are shown to be reduced down to the number of states minus the number of outputs, respectively.ly.

• 한국응용과학기술학회지
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• 제24권4호
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• pp.339-346
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• 2007

The influence of adding urea to phenol-formaldehyde (PF) resins as a co-polymer component were investigated aiming at synthesizing useful phenol-urea-formaldehyde resins. Urea was added at 10% by total resin weight. Several methods for the addition of urea to the PF resins during synthesizing resins to see the co-polymerization occurs between urea and PF resins. The urea was added at the beginning, at three different middle stages, and at the end of PF resin synthesis. The copolymerized methylene bridges between phenol and urea molecules were not observed by $^{13}C-NMR;$ no signal around 50ppm. The curing of urea-modified PF resins, evaluated by dynamic mechanical analysis(DMA), showed some differences among the resins. DMA gel times ranged from 2.75 min to 3.25 min and the resins made with earlier urea additions showed slightly shorter gel times. The longest cure time and gelation time was observed for the resin PFU. Catalyst effects on the DMA cure time values of resins were not significant with different amounts of catalyst or different types of catalyst for all resins tested. Gel times of urea-modified PF resins shortened the most by triacetin catalyst.

• 유통과학연구
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• 제13권4호
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• pp.9-19
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• 2015

Purpose - This study focuses on the use of evaluative criteria software for imprecise market information, and product mapping relationships between design parameters and customer requirements. Research design, data, and methodology - This study involved using the product predicted value method, synthesizing design alternatives through a morphological analysis and plan, realizing the synthesis in multi-criteria decision-making (MCDM), and using its searching software capacity to obtain optimal solutions. Results - The establishment of product designs conforms to the customer demand, and promotes the optimization of several designs. In this study, the construction level analytic method and the simple multi attribute comment, or the quantity analytic method are used. Conclusions - This study provides a solution for enterprise products' multi-goals decision-making, because the product design lacks determinism, complexity, risk, conflict, and so on. In addition, the changeable factor renders the entire decision-making process more difficult. It uses Fuzzy deduction and the correlation technology for appraising the feasible method and multi-goals decision-making, to solve situations of the products' multi-goals and limited resources, and assigns resources for the best product design.

• 한국정보처리학회논문지
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• 제7권5호
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• pp.1361-1369
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• 2000

For the implementation of 3D Sound Localization system, the binaural filtering by HRTFs is generally employed. But the HRTF filter is of high order and its coefficients for all directions have to be stored, which imposes a rather large memory requirement. To cope with this, research works have centered on obtaining low dimensional HRTF representations without significant loss of information and synthesizing the original HRTF efficiently, by means of feature extraction methods for multivariate dat including PCA. In these researches, conventional linear PCA was applied to the frequency domain HRTF data and using relatively small number of principal components the original HRTFs could be synthesized in approximation. In this paper we applied neural network based nonlinear PCA model (NLPCA) and the nonlinear PLS repression model (NLPLS) for this low dimensional HRTF modeling and analyze the results in comparison with the PCA. The NLPCA that performs projection of data onto the nonlinear surfaces showed the capability of more efficient HRTF feature extraction than linear PCA and the NLPLS regression model that incorporates the direction information in feature extraction yielded more stable results in synthesizing general HRTFs not included in the model training.

• 로봇학회논문지
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• 제6권2호
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• pp.118-129
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• 2011

In this paper, we suggest a new camera capturing and synthesizing algorithm with the multi-captured left and right images for the better comfortable feeling of 3D depth and also propose 3D image capturing hardware system based on the this new algorithm. We also suggest the simple control algorithm for the calibration of camera capture system with zooming function based on a performance index measure which is used as feedback information for the stabilization of focusing control problem. We also comment on the theoretical mapping theory concerning projection under the assumption that human is sitting 50cm in front of and watching the 3D LCD screen for the captured image based on the modeling of pinhole Camera. We choose 9 segmentations and propose the method to find optimal alignment and focusing based on the measure of alignment and sharpness and propose the synthesizing fusion with the optimized 9 segmentation images for the best 3D depth feeling.