• 대한화학회지
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• 제55권5호
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• pp.824-829
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• 2011

In Fischer-Tropsch Synthesis, because of few reactants ($H_2$, CO), scarce operating parameters affected on efficiency especially the selectivity of products. In this research, effect of operating parameters on the selectivity of Co-Mn-$TiO_2$ Fischer-Tropsch synthesis catalyst were studied by design of experimental procedure and Taguchi method. According to this research, interactions between operating factors have a crucial effect on light products selectivity. Among these interactions, (temperature${\times}$feed ratio) has the main influence on light hydrocarbons selectivity. It was concluded that temperature and feed ratio ($H_2$/CO) were the most integral operating parameters for much greater selectivity of light hydrocarbons.

• 약학회지
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• 제38권1호
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• pp.1-5
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• 1994

We have synthesized some 2-(2-benzyloxybenzoyloxy)-and 2-(2,6-dibenzyloxybenzoyloxy)-acetophenones as intermediates for flavone synthesis. The reaction of polyoxygenated 2-hydroxyacetophenones with 2-benzyloxybenzoic acid or 2,6-dibenzyloxybenzoic acid in the presence of dicyclohexylcarbodiimide and p-dimethylaminopyridine resulted in a good yield$(70{\sim}89%)$ of 2-(2-benzyloxybenzoyloxy)-acetophenones or 2-(2,6-dibenzyloxybenzoyloxy) acetophenones under milder conditions and in shorter time than the previous methods. This new methods using benzoic acids instead of benzoyl chlorides saves one reaction step of acid chlorination in comparision of the previous methods.

• 한국분말재료학회지
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• 제19권6호
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• pp.442-445
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• 2012

The quantum dots (QD) have unique electrical and optical properties due to quantum dot confinement effect. The optical properties of QDs are decided by various synthesis conditions. In a prior QDs study, a study on the QDs size with synthesis condition such as synthesis time and temperature is being extensively researched. However, the research on QDs size with composition ratio has hitherto received scant attention. In order to evaluate the ratio dependence of CdSe crystal, synthesis ratio of Se precursor is changed from 16.7 mol%Se to 44 mol%Se. As the increasing Se ratio, the band gap was increased. This is caused by red shift of emission. We confirmed optical property of CdSe QDs with composition ratio.

• Journal of Multimedia Information System
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• 제2권3호
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• pp.263-274
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• 2015

The subject of this work is the complex discrete systems simulation special features with the aid of dynamic graph models. The proposed simulation technique allows to determine the ways for tasks solutions in terms of discrete systems analysis and synthesis of various complication: one-dimensional and multidimensional, steady and unstable, with the pulse elements abnormal operating mode and others. Often complex control systems analysis and synthesis task solutions, via classical approach comes out to be insolvent, because of the computational problems. The application of graph models allows to perform clear and strict characterization and computer procedures automation. The optimal controls synthesis algorithm presented in this paper, transferring the discrete system from target initial state to target final state within the minimum time, allows to consider the zero initial conditions systems, with the initial potential energy, with the control actions limitations and complex pulse elements operating mode.

• 한국세라믹학회지
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• 제32권6호
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• pp.735-747
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• 1995

The synthesis of clay mineral through the hydrothermal reaction of the anorthite, which is distributed in San Chung-District of Korea and called as the ground rock for halloysite-kaolin, has been investigated. It was observed that this anorthite sample was easily converted into clay mineral with 0.5 wt% HCl solution at a temperature below 20$0^{\circ}C$ under a pressure about 15 atm. The conversion reaction was promoted by adding aluminum chloride under the condition concerned. Aluminum chloride was considered to supply the insufficient aluminum ion during the conversion reaction and to reprepare the acid solution-condition by adding the HCl-component as a by-product. According to the electron micrographs, it was confirmed that fine tubular or needle-shaped halloysite-kaolin minerals with the crystal length shorter than about 1.1${\mu}{\textrm}{m}$ could be obtained by the hydrothermal reaction for 5 days under those conditions.

• 대한기계학회논문집
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• 제13권4호
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• pp.799-806
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• 1989

본 논문에서는 일반적으로 축방향 변위에 대한 모우드만을 가지고 있는 경우의 합성을 위해 축방향 변위 모우드의 커브-피팅을 이용하여 기울기 정보를 얻고 모델링된 요소의 연결부에 부여함으로써, 변위 정보만을 사용하는 방법보다 좀 더 정확한 고유값을 얻을 수 있음을 보이고자 한다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2000년도 추계학술대회논문집
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• pp.201-206
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• 2000

In this work transfer function synthesis method based on FRF data of each substructure is investigated for a complex structure composed of many substructures. Though the transfer function synthesis method has superiority to analyze the characteristics of interfaces among substructures effectively, many problems arise in the computation process, especially matrix inversion process. Due to computational problems, the error between the data obtained by test and the predictions through computations is inevitable. So in this paper, computational aspects in the transfer function synthesis method are examined through a steering system problem of passenger car. For the FBS method, frequency response functions of 3 substructures are measured experimentally. Effects of several parameters such as matrix inversion method, connection conditions between substructures and off-diagonal terms on system response are studied numerically.

• Bulletin of the Korean Chemical Society
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• 제4권2호
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• pp.72-76
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• 1983

Cephaloglycin was synthesized directly from D-${\alpha}$ -phenylglycine methyl ester and 7-aminocephalosporanic acid using whole cell enzyme of Xanthomonas citri (IFO 3835). Some optimal conditions for cephaloglycin synthesis were investigated, and yield improvements for its production by several methods were attempted. Using the whole cell enzyme system, the reaction kinetic model for cephaloglycin synthesis is proposed, and the kinetic constants for D-${\alpha}$ -phenylglycine methyl ester hydrolysis, cephaloglycin synthesis, and cephaloglycin hydrolysis were determined. The $K_m$ values of D-${\alpha}$-phenylglycine methyl ester, 7-aminocephalosporanic acid, and cephaloglycin were 11 mM, 24 mM, and 167 mM, and $K_i$ value of D-${\alpha}$-phenylglycine was 15 mM, respectively. The pattern of product inhibition was found to be competitive one.

• Archives of Pharmacal Research
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• 제18권2호
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• pp.69-74
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• 1995

In order to improve physico-chemical properties and to enhance stability of drugs, amino acid salt has been widely adoptd in pharmaceutical synthesis. Acetylsalicylic acid lysinate is one of the widely used analgesics and it is a good example of t5his synthesis. In the case of bacetylsalicylic acid lysinate synthesis, racemization of natrually occurred lysine is esential because the racemic lysine salt of the drug shows better yield, crystallinity and dryness than that of the L-lysine salt. To esatablish a simple, practical and economical process for L-lysine racemization, L-lysine treatments with phosphoric acid and with acetic acid were compared and the optimum conditions for its process and derivatization were investigated by chiral separation methods using GC_MS spectroscopy.

• 한국군사과학기술학회지
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• 제4권1호
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• pp.93-103
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• 2001

고주파를 주로 사용하는 능동소나에서 반사신호는 물체표면의 거울면 반사와 내부의 여러 등가적인 산란자로 형성되며, 이는 물체에 공간적으로 분포된 하이라이트에 의해 특징 된다. 본 연구에서는 기존의 모의표적에 대한 반사신호 합성모델 즉, 랜덤분포 모델, 등간격분포 모델 및 MUTAHID 모델에 대하여 분석하고, 합성된 반사신호 결과특성을 여러 조건에서 비교하였다. 이러한 하이라이트 분포 모델들은 수중표적의 반사신호 합성을 필요로 하는 각종 실시스템의 모의표적 신호 합성에 유용하게 적용될 수 있으리라 생각된다.