• Journal of the Society of Cosmetic Scientists of Korea
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• v.21 no.2
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• pp.49-56
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• 1995

Chitosan microcapsules and microbeads were prepared by W/O emulsion method, and their morphologies were observed through SEM. The microcapsules have skin layer of 8 Um and 250 Um of mean diameter, The swelling test showed higher s welling ability in protic solvents than in aphotic solvents. After containing moth-yl violet in the microcapsules, the release patterns were investigated. The results sho wed that the addition of Iysozyme in pH 5.1 acetate buffer accelerated the re-lease rate. In case of the microbeads, the mean diameter was about 70 Um. The surface of the microbeads showed porous structures. The swelling ability of the beads revealed two times higher than the one of the microcapsules.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.09c
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• pp.135-139
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• 2010

A construction technique to install the soil-bentonite (SB) cut-off wall for in-situ geoenvironmental containment by employing the trench cutting and re-mixing deep wall method is first presented in this paper. The laboratory test results on the hydraulic barrier performance of SB in relation to the chemical compatibility are then discussed. Hydraulic conductivity tests using flexible-wall permeameters as well as swell tests were conducted for SB specimens exposed to various types and concentrations of chemicals (calcium chloride, heavy fuel oil, ethanol, and/or seawater) in the permeant and/or in the pore water of original soil. For the SB specimens in which the pore water of original soil did not contain such chemicals and thus the sufficient bentonite hydration occurred, k values were not significantly increased even when permeated with the relatively aggressive chemical solutions such as 1.0 mol/L $CaCl_2$ or 50%-concentration ethanol solution. In contrast, the SB specimens containing $CaCl_2$ in the pore water had the higher k values. The excellent linear correlation between log k and swelling pressure implies that the swelling pressure can be a good indicator for the hydraulic barrier performance of the SB.

• Textile Coloration and Finishing
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• v.31 no.3
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• pp.177-186
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• 2019

In this study, we investigated for synthetic hydrotalcite in chloroprene rubber foam. Experiments were carried out to find the optimum content ratio by controlling the contents of MgO and Hydrotalcite. Swelling test in toluene immersion was made to measure the crosslinking density of CR foams, and the cure properties were investigated with flat die rheometer and Mooney viscosity. The difference of hardness, tensile strength and elongation at break were observed after immersing in 7% NaCl or 21% NaCl solutions for a day and four days. In addition, the volume change and water content remaining in CR foam were measured after immersing NaCl solution. As content of MgO increased, the value of the cure torque tended to increase, but it was almost constant above 2phr of MgO. However, the Mooney viscosity decreased with increasing MgO content. The crosslinking density, determined by the swelling ratio, showed that the CR compound without MgO showed a higher degree of swelling. When the content of hydrotalcite/MgO was 3:2, it was the lowest volume change of CR form. Also, As the content of hydrotalcite decreased, the difference of mechanical properties before and after immersion NaCl solution increased.

• Polymer(Korea)
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• v.30 no.4
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• pp.332-337
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• 2006

Monodisperse polymer particles were prepared via one-step seeded polymerization using PMMA seed particles and HDDA (or EGDMA) as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer or monomer mixture to the seed polymer particles (swelling ratio), 2) the ratio of EGDMA in absorbed monomer mixture, 3) the dosage of initiator, and 4) electro less Ni plating on the variation of mechanical properties of monodisperse polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement, were investigated by using MCT (micro compression test). It was observed that monomer swelling ratio influenced only breaking strength, but EGDMA ratio in monomer mixture, dosage of initiator and electroless Ni plating affected both K-values and breaking strength.

• Journal of the Korean Wood Science and Technology
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• v.29 no.3
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• pp.36-46
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• 2001

This study was to find a way of reusing wood and plastic wastes, which considered as a troublesome problem to be solved in this age of mass production and consumption, in manufacturing wood fiber-polypropylene fiber composite panel. And the feasibility of this composite panel as a substitute for existing headliner base panel of automobile was also discussed, especially based on physical and mechanical performance. Nonwoven web composite panels were made from wood fiber and polypropylene fiber formulations of 50 : 50, 60 : 40, and 70 : 30, based on oven-dry weight, with densities of 0.4, 0.5, 0.6, and 0.7 g/$cm^3$. At the same density levels, control fiberboards were also manufactured for performance comparison with the composite panels. Their physical and mechanical properties were tested according to ASTM D 1037-93. To elucidate thickness swelling mechanism of composite panel through the observation of morphological change of internal structures, the specimens before and after thickness swelling test by 24-hour immersion in water were used in scanning electron microscopy. Test results in this study showed that nonwoven web composite panel from wood fibers and polypropylene fibers had superior physical and mechanical properties to control fiberboard. In the physical properties of composite panel, dimensional stability improved as the content of polypropylene fiber increased, and the formulation of wood fiber and polypropylene fiber was considered to be a significant factor in the physical properties. Water absorption decreased but thickness swelling slightly increased with the increase of panel density. In the mechanical properties of composite panel, the bending modulus of rupture (MOR) and modulus of elasticity (MOE) appeared to improve with the increase of panel density under all the tested conditions of dry, heated, and wet. The formulation of wood fiber and polypropylene fiber was considered not to be a significant factor in the mechanical properties. All the bending MOR values under the dry, heated, and wet conditions met the requirements in the existing headliner base panel of resin felt.

• Polymer(Korea)
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• v.31 no.5
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• pp.410-416
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• 2007

Monodisperse polymer particles were prepared via one- step seeded polymerization using PMMA as seed particles, and HDDA, triEGDMA or EGDMA as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer to the seed polymer particles (swelling ratio), 2) the characteristics of crosslinking monomer, 3) electroless Ni plating, and 4) electroless Au Plating on the variation of mechanical properties of polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement were investigated by using MCT (micro compression test). It was observed that swelling ratio of polymer particles influenced only on breaking strength of polymer Particles, while electroless plating did on recovery rate, K-values ($K_{10}\;and\;K_{20}$) and breaking strength of electroless plated polymer particles. However, breaking displacement and K-values ($K_{30}{\sim}K_{50}$) were more or less insensitive to electroless plating.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.552-559
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• 2023

The purpose of this study is to evaluate the crack reduction performance of blast furnace slag concrete mixed with expansive and swelling admixtures. As a basic performance test, various ingredients such as blast furnace slag fine powder (BFS), calcium sulfoaluminate (CSA), bentonite, and hydroxypropyl methyl cellulose (HPMC) were used, and the results showed that bentonite showed superior performance compared to HPMC. Afterwards, a MOCK-UP test was conducted to evaluate cracking and drying shrinkage according to the mixing ratio. As a result, when bentonite and a small amount of calcium phosphate were added, drying shrinkage was reduced and cracking was reduced. In particular, a cement mixture consisting of 30 % BFS, 1 % bentonite, and 1 % calcium phosphate showed optimal crack-free performance. It is believed that BFS concrete will contribute to compensating for shrinkage through continuous expansion activity and can be used for field applications.

• Proceedings of the Korea Environmental Mutagen Society Conference
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• 2002.05a
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• pp.97-97
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• 2002

• Membrane Journal
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• v.12 no.4
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• pp.255-261
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• 2002

Poly(vinyl alcohol) (PVA) membranes crosslinked with poly(acrylic acid-co-maleic anhydride) (PAM) as a polymeric crosslinking agent were prepared to investigate the pervaporation performance for the dehydration separation of aqueous ethanol solution. The characteristics of the resulting membranes crosslinked(x) were analysed by FT-IR and water swelling test. The water swelling decreased with increasing crosslinking agent content. The crosslinked PVA membranes with PAM showed lower water swelling than those of PVA membrane crosslinked with glutaraldehyde and modified PVA membrane. The swelling of water molecules in the crosslinked PVA membranes is more restricted by both chemical crosslinking between PVA and polymeric crosslinking agent chains and physical crosslinking by the entanglement between the PVA and polymeric crosslinking agent chains. For the pervaporation of aqueous ethanol solution through the crosslinked membrane, as the contents of crosslinking agent increased, the separation factor increased while the permeation flux decreased. The separation factor slightly decreased and permeation flux increased with increasing feed water content. As a result it could be considered that PVA-PAM membranes suppressed the plasticization effect even in the range of high water concentration in fled.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.833-836
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• 2008

In this study, we would like to study on the apply properties to salt water environment of pre-hydrated bentonite for complement problem that water leakage to permit salt water that existing bentonite does not initial swelling. Accordingly, execute viscosity properties, swelling properties, permeability and confirmed apply properties to salt water environment. Did not permit initial permeable in test result salt water environment, and permeable did not happen until 72 hours by maximum $3kgf/cm^2$ water pressure. Fresh water environment enough progress of gelation confirm that viscosity and swelling properties confirmation result and as delamination phenomenon of platy formation looked in salt water environment but this as bentonite hydrates crystallization layer swelling that is done consider. Synthetic study results, if compaction condition such as press layer is formed to bentonite upper, applied to the salt water environment of the underground structures of expectations.