• Title/Summary/Keyword: surfactants

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Effect of Synthetic Surfactants on the Activity of Mutagens (계면활성제가 돌연변이원성 물질의 활성에 미치는 영향)

  • Choi, Yoon-Ho;Chung, Yong
    • Environmental Analysis Health and Toxicology
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    • v.7 no.3_4
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    • pp.69-79
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    • 1992
  • Recently, concerns of water pollution and health risks caused by synthetic detergents have emerged, as the use of various detergents has increased It has been suggested that some surfactants are cocarcinogens. The surfactants tested were linear alkylbenzene sulfonate, sodium lauryl sulfate, polyoxyethylene sorbitan monooleat (tween 80), and the mutagens were 1-nitropyrene, N -methyl- N'-nitro-N -nitrosoguanidine, benzo (a) pyrene, and aflatoxin B$_1$. This study was undertaken to investigate the effects of surfactants on the activity of mytagens using the Ames mutagenic assay with Salmonella typhimurium TA98, TA100. The results were summarized as follows: 1. The surfactants have no mutagenic activity of themselves. 2. Higher doses of surfactants than 100 $\mu\textrm{g}$/plate reduced the number of revertants. It is assumed that the reduction would inhibited cell growth. 3. When the comutagenic ratio is defined as the ratio between mutagenic activity itself and the activity with mutagen and surfactant (drinking water quality standard), LAS showed the comutagenic ratio 0.86-1.17 and SLS 0.74-1.10 as well. According to the comparisons, it could not be recognised for the comutagenicity of drinking water quality standard of surfactant. 4. As increasing the amount of mutagens, the designated amount of surfactant did not affected the mutagen's activity statistically. From the above result, syunthetic surfactants do not present mutagenicity and comutagenicity in the microbial assay.

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Synthesis and Evaluation of N-(2,3-dihydroxypropyl)-N,N-dimethyldodecane-1-amine chloride (N-(2,3-dihydroxypropyl)-N,N-dimethyldodecane-1-amine chloride의 합성과 평가)

  • Cho, Wan-Goo;Choi, Jeong-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.1
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    • pp.23-31
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    • 2008
  • In general, anionic and cationic surfactants are incompatible because their mixtures form insoluble complexes. There are, however, some complexes that are soluble and behave like regular surfactants, specifically like nonionic surfactants, thus named pseudo-nonionic surfactant complexes. Pseudo-nonionic complexes are more effective and efficient than their ionic surfactant components as shown by their equilibrium and dynamic surface tensions and interfacial tensions. They pack at the interface more than their ionic components. Since, pseudo-nonionic complexes show their own characteristics, they can be treated as separate classes of surfactants distinct from ionic and nonionic surfactants. Novel cationic surfactant was synthesized, having the polyhydroxyl group at the head group. We found that aqueous mixtures of our cationic surfactant and usual anionic surfactant(SDS) could form homogeneous solutions even at high concentration. The properties of mixed surfactant solutions were measured. Foam stability, CMC(critical micelle concentration), water hardness tolerance and thickening effect were tested. The foam stability of mixed surfactants was very good and various synergy effects were observed.

Study on the Absorption Rate of Ascorbic Acid with Span and Tween (Span과 Tween이 Ascorbic Acid의 흡수효율(吸收效率)에 미치는 영향(影響))

  • Kim, Chun-Kyu
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.11 no.4
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    • pp.43-46
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    • 1982
  • The purpose of this paper was to study the effect of surfactants on the absorption and the bioavailability of ascorbic acid in the small intestine of rats and rabbits absorption of ascorbic acid in small intestine of rats was increased with tween 80 and span 80.The blood level of ascorbic acid in rabbits was elevated by combined with low concentration of surfactants but high concentration of surfactants. The bioavailability of ascorbic acid was increased by simultaneous administration of surfactants.

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Micellar Solubilization of Cholesterol, Cholesteryl Myristate and Gallstones by Synthetic Surfactants

  • Han, Suk-Kyu;Kim, Nam-Hong
    • YAKHAK HOEJI
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    • v.21 no.3
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    • pp.135-140
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    • 1977
  • Solubilization of cholesterol, its fatty acid esters and gallstones were undertaken employing nonionic, anionic and cationic surfactants. Cholesterol was effectively solubilized by all of these surfactants. Cationic surfactants were most effective. However, cholesteryl myristate was not solubilized at all. In the dissolution test of gallstones in surfactant solutions, cationic surfactant solutions were exceptionally effective in dissolving gallstones. These results suggest the possible existence of interaction between alkylammonium radical and cholesterol on micellar surface.

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Synergy effect for performance of anionic SDS/ADS mixtures with amphoteric and nonionic surfactants

  • Noh, Hongche;Kang, Taeho;Ryu, Ji Soo;Kim, Si Yeon;Oh, Seong-Geun
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.449-458
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    • 2016
  • Detergency and surface active properties of mixed anionic surfactants with amphoteric and nonionic were investigated. Sodium dodecyl sulfate (SDS) and ammonium dodecyl sulfate (ADS) as anionic surfactants and cocamidopropyl betaine (CAPB) as an amphoteric surfactant were used. Nonionic surfactants, which are butyl glucoside (BG), octyl glucoside (OG), decyl glucoside (DG), lauryl dimethylamine oxide (AO) and saponin were also used. To study the synergy effects of mixed SDS/ADS anionic surfactant systems, amphoteric and nonionic surfactants were added into the mixed anionic surfactants. Investigated properties of surfactant mixtures were critical micelle concentration (CMC), surface tension (${\gamma}$), wettability. In addition, based on these properties, detergency of each sample was examined. Surfactant mixtures are anionics (SDS/ADS), anionic/amphoteric/nonionic (SDS/ADS/CAPB/saponin), and anionic/nonionic (SDS/ADS/BG/saponin, SDS/ADS/OG/saponin, SDS/ADS/DG/saponin, and SDS/ADS/AO/saponin). With the addition of amphoteric and nonionic to mixed anionic surfactants, CMC and ${\gamma}$ were decreased. Addition of CAPB, which is amphoteric, showed the best property at CMC and ${\gamma}$. Furthermore, as the chain length of hydrocarbon in alkyl glucosides was increased, the CMC and ${\gamma}$ were enhanced. However, the wettability did not exactly match up with CMC and ${\gamma}$. The surfactant mixture, which contained DG, showed the best performance at wetting time. Detergency was measured at various temperatures ($15^{\circ}C$, $30^{\circ}C$, $50^{\circ}C$). The cleaning performance was enhanced by increasing washing temperature. Moreover, detergency was influenced by not only CMC and ${\gamma}$ but also wettability. Although CMC and ${\gamma}$ were not minimum at surfactant mixture that included DG, the best cleaning performance showed in that sample.

Inhibitory Activity of Surfactants against Tobacco Mosaic Virus Infection (계면활성제의 TMV 감염저지 효과)

  • 박은경
    • Journal of the Korean Society of Tobacco Science
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    • v.11 no.1
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    • pp.11-17
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    • 1989
  • Inhibition of tobacco mosaic virus (TMV) infection by 4 surfactants, sodium salts of alpha olefin (AOS), linear alkylbenzene (LAS), dioctyl sulfosuccinate (OSS), and dodecyl benzene sulfonic acid (SAS), was examined on tobacco cv. Xanthi-nc and NC 82. Infection of virions or TMV RNA was inhibited over 98% by the surfactants (2500 rpm). However, symptom development and viral concentration in tobacco plants treated with the surfactants into the rhizosphere soil 3 days before inoculation with TMV on leaves were not different from those in untreated tobacco plants. This indicates no significant systemic effects of the surfactants on the inhibition of TMV infection. The surfactants, except LAS, had no effect on the inhibition of viral infection when purified virions mixed with each surfactant and ultracentrifuged were inoculated on the tobacco plants. The virus was almost inactivated by LAS, showing that the viral infection was reduced more than 96%. The virus particles treated with the surfactants were not distinguishable in size and dimension from untreated normal particles, suggesting that the inhibitory action of the surfactants to TMV infection may not involve disintergration or uncoating of the virus at the early stage of infection.

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Effects of the Presence of Nonionic surfactants on Diesel Biodegradation (비이온계 계면활성제가 미생물의 디이젤 분해에 미치는 영향)

  • Lee, Hyo-Sang;Jeong, Gi-Hyeong;Kim, Jeong-Rak;Lee, Gi-Se
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.424-425
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    • 2000
  • The effects of the presence of commercial non-ionic surfactants on the cell growth and diesel degradation by Pseudomonas sp. OSD were studied. Most surfactants inhibited the diesel biodegradation at high concentration(1000mg/1). However, some surfactants showed no inhibition at lower concentrations. Tween 20, Brij 58, Brij 78 were not inhibitory to the diesel biodegradation even at high concentration. These chosen surfactants has relatively high HLB values. There exists complicated relationship for diesel bioremediation between cell hydrophobicity, surfactant HLB, contaminants, an soil.

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Removal of Aoueous Pentachlorophenol by Horseradish Peroxidase in the Presence of Surfactants

  • Kim, E.Y.;Choi, Y.J.;Chae, H.J.;Chu, K.H.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.5
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    • pp.462-465
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    • 2006
  • An important issue in the oxidation of pentachlorophenol (PCP) by the enzyme horseradish peroxidase (HRP) is enzyme inactivation during the reaction. This study was initiated to investigate the ability of two nonionic surfactants (Tween 20 and Tween 80) to mitigate HRP inactivation. The surfactants were tested at concentrations below and above their critical micelle concentrations (CMCs). Enhancement of PCP oxidation was observed at sub-CMCs, indicating effective protection of HRP by the two surfactants. Maximum levels of PCP removal were observed when the concentrations of Tween 20 and Tween 80 were 40 and 50% of the CMCs, respectively At supra-CMCs, both surfactants caused a noticeable reduction in the extent of PCP removal.

Removing of Phosphate, Nitrogen and Anion surfactants in the Wastewater using ALC (경량기포콘크리트를 이용한 인과 질소 및 음이온계면활성제 제거)

  • 홍영호
    • Journal of environmental and Sanitary engineering
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    • v.16 no.1
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    • pp.102-107
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    • 2001
  • This research was carried out investigate the removed T-P, T-N and anion surfactants using Autoclaved Lightweight Concrete(ALC) in wastewater treatment system. Effects of pH, TDS on aqueous solution was measured. Specific area which measured by BET was $27.66m^2/g$. The phosphorous, nitrogen and anion surfactants removal efficiencies were examined by using artificial waste water(T-P : 66~73mg/L, T-N : 56~136mg/L and anion surfactants : 10~31mg/L). The results showed that the ALC was effective material as a adsorbent due to the structure and porosity. It was found that anion surfactants removed was 85~95%, phosphate removed was 92% and nitrogen removed was 90% in artificial wastewater. Agitation process was more effective than aeration process in that case of nitrogen removal system using ALC.

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Properties of Low Density Foamed Concrete for Building Construction Using Anionic Surfactants of Synthetic and Natural Materials

  • Jeong, Ji-Yong;Kim, Jin-Man
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.6
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    • pp.557-566
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    • 2011
  • The surfactants facilitate the formation of foam bubbles under a proper condition and provide stability of foam bubbles by decreasing the surface tension of solutions and increasing the viscosity of foam surface. However, there have been almost no practical data of foam concrete in this regard so far. This study aims to understand the effects of foaming agents such as anionic synthetic surfactant and anionic natural material surfactant on the low density foamed concrete. From the experiment, the vegetable soap of anionic natural material surfactants showed a higher foaming rate, more open pores, slightly lower compressive strength, and a higher permeability coefficient compared to the vegetable soap of anionic synthetic surfactants. It is believed that the natural material surfactants make not only the surface tension of the solution low but also the viscosity of slurry high.