• Title/Summary/Keyword: surface-modification technology

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Etchless Fabrication of Cu Circuits Using Wettability Modification and Electroless Plating (젖음성 차이와 무전해도금을 이용한 연성 구리 회로패턴 형성)

  • Park, Sang-Jin;Ko, Tae-Jun;Yoon, Juil;Moon, Myoung-Woon;Han, Jun Hyun
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.622-629
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    • 2015
  • Cu circuits were successfully fabricated on flexible PET(polyethylene terephthalate) substrates using wettability difference and electroless plating without an etching process. The wettability of Cu plating solution on PET was controlled by oxygen plasma treatment and $SiO_x$-DLC(silicon oxide containing diamond like carbon) coating by HMDSO(hexamethyldisiloxane) plasma. With an increase of the height of the nanostructures on the PET surface with the oxygen plasma treatment time, the wettability difference between the hydrophilicity and hydrophobicity increased, which allowed the etchless formation of a Cu pattern with high peel strength by selective Cu plating. When the height of the nanostructure was more than 1400 nm (60 min oxygen plasma treatment), the reduction of the critical impalement pressure with the decreasing density of the nanostructure caused the precipitation of copper in the hydrophobic region.

DNA Sequencing Analysis Technique by Using Solid-State Nanopore (고체상 나노구멍을 이용한 DNA 염기서열 분석기술)

  • Kim, Tae-Heon;Pak, James Jung-Ho
    • Journal of Sensor Science and Technology
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    • v.21 no.5
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    • pp.359-366
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    • 2012
  • Nanopore DNA sequencing is an emerging and promising technique that can potentially realize the goal of a low-cost and high-throughput method for analyzing human genome. Especially, solid-state nanopores have relatively high mechanical stability, simple surface modification, and facile fabrication process without the need for labeling or amplification of PCR (polymerized chain reaction) in DNA sequencing. For these advantages of solid-sate nanopores, the use of solid-state nanopores has been extensively considered for developing a next generation DNA sequencing technology. Solid-state nanopore sequencing technique can determine and count charged molecules such as single-stranded DNA, double-stranded DNA, or RNA when they are driven to pass through a membrane nanopore between two electrolytes of cis-trans chambers with applied bias voltage by measuring the ionic current which varies due to the existence of the charged particles in the nanopore. Recently, many researchers have suggested that nanopore-based sensors can be competitive with other third-generation DNA sequencing technologies, and may be able to rapidly and reliably sequence the human genome for under $1,000.

Thin Micro-Porous Scaffold Layer on Metallic Substrate (금속기질에 앓은 마이크로 다공질 스케폴드 코팅에 관한 연구)

  • Sin, D.C.;Miao, X.;Kim, W.C.
    • Journal of Power System Engineering
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    • v.14 no.5
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    • pp.41-47
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    • 2010
  • 티타늄과 티타늄 합금은 재료적 특이성 때문에 심장 혈관 임플란트에서 일반적으로 사용되어 왔다. 일찍이 적용된 예로는 인공심장판막, 심박조율기의 보호케이스, 혈액 순환 장치 등이 있다. 하지만 물질유도혈전증(Material-induced thrombosis)은 혈전폐색에 의해 기인한 기능 손실로 심장혈관 임플란트 장치의 주된 합병증으로 존재하고 있으며, 심장혈관 임플란트의 혈전유전자는 심장혈관장치의 발달에 주된 난관 중 하나로 남아있다. 그리고 텍스처 혈액 접합 물질(Textured blood-contacting material)은 1960년대 초반 이후부터 혈액순환 보조 장치의 임상실험에 사용되고 있다. 접합 물질에 내장된 텍스처 섬유조직 표면은 형성, 성장, 안정적 부착, 생물학적 내벽(neointimal layer) 등 유도 혈액(entrapping blood) 성분에 의해 형성된다. 공동(cavity) 형상의 용해 가능한 미립자를 사용하는 SCPL법(Solvent casting/particulate leaching method)은 티타늄 기질 이전에 형성된 폴리우레탄 위에 텍스처(texture)를 생성하기 위해 사용되었다. 또한 콜라겐의 부동화(不動化)에 의한 공동(cavity)은 혈액 접합면에 잔존하기 위한 내피세포를 고정할 수 있는 효과가 있다. cpTi로 층화된 PU 기소공성(microporous)은 구조적 특성과 혈전증 감소를 위한 생물학적 내벽 사용의 잠재성을 평가하기 위한 세포 공동체 실험을 통해서 평가되었다.

Interfacial Shear Strength and Thermal Properties of Electron Beam-Treated Henequen Fibers Reinforced Unsaturated Polyester Composites

  • Pang Yansong;Cho Donghwan;Han Seong Ok;Park Won Ho
    • Macromolecular Research
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    • v.13 no.5
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    • pp.453-459
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    • 2005
  • Natural fiber henequen/unsaturated polyester (UPE) composites were fabricated by means of a compression molding technique using chopped henequen fibers treated at various electron beam (EB) dosages. The interfacial shear strength (IFSS), dynamic mechanical properties, and thermal expansion behavior were investigated through a single fiber microbonding test, fractographic observation, dynamic mechanical analysis, and thermomechanical analysis, respectively. The results indicated that the interfacial and dynamic mechanical properties significantly depended on the level of the EB treatment irradiated onto the henequen fiber surfaces. The effect of EB treatment on the IFSS, storage modulus and fracture surface of the henequen/UPE composites agreed with each other. The results of this study also suggested that the modification of henequen fiber surfaces at 10 kGy EB is the most effective for improving the interfacial properties of the henequen/UPE composites.

Biological Synthesis of Alkyne-terminated Telechelic Recombinant Protein

  • Ayyadurai, Niraikulam;Kim, So-Yeon;Lee, Sun-Gu;Nagasundarapandian, Soundrarajan;Hasneen, Aleya;Paik, Hyun-Jong;An, Seong-Soo;Oh, Eu-Gene
    • Macromolecular Research
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    • v.17 no.6
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    • pp.424-429
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    • 2009
  • In this study, we demonstrate that the biological unnatural amino acid incorporation method can be utilized in vivo to synthesize an alkyne-terminated telechelic protein, Synthesis of terminally-functionalized polymers such as telechelic polymers is recognized to be important, since they can be employed usefully in many areas of biology and material science, such as drug delivery, colloidal dispersion, surface modification, and formation of polymer network. The introduction of alkyne groups into polymeric material is particularly interesting since the alkyne group can be a linker to combine other materials using click chemistry. To synthesize the telechelic recombinant protein, we attempted to incorporate the L-homopropargylglycine into the recombinant GroES fragment by expressing the recombinant gene encoding Met at the codons for both N- and C-terminals of the protein in the Met auxotrophic E. coli via Hpg supplementation. The Hpg incorporation rate was investigated and the incorporation was confirmed by MALDI-TOF analysis of the telcchelic recombinant protein.

Development and Application of High-Cr Ferritic Stainless Steels as Building Exterior Materials

  • Kim, Yeong H.;Lee, Yong H.;Lee, Yong D.
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.324-327
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    • 2008
  • Stainless steels have been widely used as a building exterior materials in Asian countries for the last decade. It is required for the materials in this field to have an aesthetic appearance, a relatively high strength, and an excellent corrosion resistance. Other metallic materials such as copper, aluminum, and carbon steels have been also used as the exterior materials. Considering the cost of maintenance, stainless steel, having the outstanding corrosion resistance, is replacing other materials in the several parts in the building exteriors. Ferritic stainless steel has been applied as the roofing materials because its thermal expansion is much smaller than that of austenitic stainless steel. Therefore, it is suitable for the large-scale construction such as airport terminal, convention center, and football stadium. To improve the corrosion resistance of the ferritic stainless steels, the modification of alloy composition has been studied to develop new grade materials and the progress in the surface technology has been introduced. Corrosion properties of these materials were evaluated in the laboratory and in the field for longer than two years. High-Cr ferritic stainless steel showed excellent corrosion resistance to the atmospheric environments. In the region close to the sea, the corrosion resistance of high-Cr ferritic stainless steel was much superior to that of other materials, which may prove this steel to be the appropriate materials for the construction around seashore. In some of the large constructions around seashore in South Korea, high-Cr ferritic stainless steels have been used as the building exterior materials for six years.

Estimation of Contact Fatigue Life of a Girth Gear Based on Pinwheel (핀 휠 기반 거스 기어의 접촉 피로수명 평가)

  • Kwon, Soon-man;Shin, Heung Chul
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.4
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    • pp.245-252
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    • 2016
  • Girth gears are applied in the mining, cement, and mineral processing industries and used in various types of horizontal mills, rotary dryers and kilns, and other heavy-gear ring applications. The large ring gears are normally fitted outside mills or kilns to provide the primary rotational drive. Recently, an external pinwheel gear set (e-PGS) was introduced to overcome manufacturing problems associated with girth gears. e-PGS is also suitable for low-speed, heavy-duty mechanical transmission and dusty and poor-lubrication conditions. This paper first presents a new profile modification of root relief for the e-PGS cam pinion. We then investigate load-stress factors to estimate the surface fatigue life by varying the shape design parameters. The results show that the contact fatigue life of an e-PGS can be extended significantly by increasing the profile shift coefficient. However, support bearing life of the pinwheel depends more on the contact force distribution than the profile shift coefficient.

Recent progress in supported liquid membrane technology: stabilization and feasible applications

  • Molinari, Raffaele;Argurio, Pietro
    • Membrane and Water Treatment
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    • v.2 no.4
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    • pp.207-223
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    • 2011
  • Supported Liquid Membranes (SLMs) have been widely studied as feasible alternative to traditional processes for separation and purification of various chemicals both from aqueous and organic matrices. This technique offers various advantages like active transport, possibility to use expensive extractants, high selectivity, low energy requirements and minimization of chemical additives. SLMs are not yet used at large scale in industrial applications, because of the low stability. In the present paper, after a brief overview of the state of the art of SLM technology the facilitated transport mechanisms of SLM based separation is described, also introducing the small and the big carrousel models, which are employed for transport modeling. The main operating parameters (selectivity, flux and permeability) are introduced. The problems related to system stabilization are also discussed, giving particular attention to the influence of membrane materials (solid membrane support and organic liquid membrane (LM) phase). Various approaches proposed in literature to enhance SLM stability are also reviewed. Modification of the solid membrane support, creating an additional layer on membrane surface, which acts as a barrier to LM phase loss, increases system stability, but the membrane permeability, and then the flux, decrease. Stagnant Sandwich Liquid Membrane (SSwLM), an implementation of the SLM system, results in both high flux and stability compared to SLM. Finally, possible large scale applications of SLMs are also reviewed, evidencing that if the LM separation process is opportunely carried out (no production of byproducts), it can be considered as a green process.

Preferential face coating of knitted PET fabrics via UV curing for water- and oil-repellent finish (자외선 경화에 의한 PET 니트직물의 편면 발수발유 가공)

  • Jeong, Yong-Kyun;Jeong, Yongjin;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.17 no.6 s.85
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    • pp.27-35
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    • 2005
  • Conventional pad- dry-cure(thermo-fixation) process usually produces functional performance on both sides of a fabric. UV curing technique was applied to impart water- and oil-repellent finish effective only on the face of a PET knitted fabric. The preferential one-side coating, by virtue of the limited penetration of UV light, was achieved by W curing after padding of a fluorocarbon agent without special coating or printing equipments. The difference in the functional property of face and back sides was examined by measuring water and oil repellency at each side of the treated fabric. The influence of pre/post-irradiation dose and agent concentration on the performance of the finished fabrics were investigated. While increase in both resin concentration and post-irradiation did not have significant effect on the finish, UV pre-irradiation of PET fabrics caused remarkable influence presumably due to appropriate surface modification of PET fabrics required for facile wetting of the resin. The dimensional stability and color change of the UV cured fabrics measured by FAST and reflectance spectrophotometry showed significantly decreased color difference and increased percent extension compared with the samples pre-irradiated without agent application.

A Study on Effect of Heat Treatment on Electrochemical Characteristics of Silicon-coated Graphite (실리콘이 코팅된 흑연의 열처리 효과에 따른 전기화학적 특성에 대한 연구)

  • Lee Myungro;Byun Dongjin;Jeon Bub Ju;Lee Joong Kee
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.66-72
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    • 2005
  • Surface modification of the silicon-coated graphite was carried out at $200^{\circ}C\~800^{\circ}C$ under hydrogen atmosphere. The silicon-coated graphites were prepared by fluidized-bed spray coating method. The components of silicon films prepared on the graphite consist of SiO, $SiO_x\;(1. The components of silicon films at $200^{\circ}C$ of heat treatment brought on the higher fraction of SiO and $SiO_x$ than that of $SiO_2$. However, inactive $SiO_2$ fraction increases with increase of the heat treatment temperature. The high content of SiO and $SiO_x$ in the silicon film on graphite leads to the higher discharge capacity in our experimental range.