• Title/Summary/Keyword: surface-modification technology

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A Study on the Lubricational Characteristics of Automotive Piston Motions With $MoS_{2}$ and PTFE Coating Materials ($MoS_{2}$와 PTFE 코팅재료에 의한 자동차 피스톤 운동의 윤활특성 연구)

  • Oh, Seong-Mo;Mun, Sang-Don
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.2
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    • pp.57-62
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    • 2007
  • The lubricational characteristics about friction wear has an effect on the material quality of surface. In this paper, we studied the lubricational characteristics through the surface modification experiment by spray coating the surface with $MoS_{2}$ and PTFE solid lubricants. In the case of $MoS_{2}$ and PTFE coating, the friction coefficient of Journal is lower than that for noncoating so the friction characteristics is excellent. In particular, the beginning characteristics of $MoS_{2}$ coating is excellent, and in the case of PTFE coating, seizure dose not appear seizure. $MoS_{2}$ and PTFE coating are excellent in the extreme pressure at high load. The wear characteristics is excellent in the following order; PTFE < $MoS_{2}$ < Non Coating. For Non coating, seizure appears at the beginning due to the heat, but in the case of $MoS_{2}$ and PTFE coating, it will have the excellent heat stability even at high temperature.

Research of Nitriding Process on Austenite Stainless Steel with Plasma Immersion Ion Beam (플라스마 이온증착 기술을 이용한 스테인리스강의 질화처리에 관한 연구)

  • Kim, Jae-Dol;Park, Il-Soo;Ok, Chul-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.2
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    • pp.262-267
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    • 2008
  • Plasma immersion ion beam (PIIB) nitriding process is an environmentally benign and cost-effective process, and offers the potential of producing high dose of nitrogen ions in a way of simple, fast and economic technique for the high plasma flux treatment of large surface area with nitrogen ion source gas. In this report PIIB nitriding technique was used for nitriding on austenite stainless steel of AISI304 with plasma treatment at $250{\sim}500^{\circ}C$ for 4 hours, and with the working gas pressure of $2.67{\times}10^{-1}$ Pa in vacuum condition. This PIIB process might prove the advantage of the low energy high flux of ion bombardment and enhance the tribological or mechanical properties of austenite stainless steel by nitriding, Furthermore, PIIB showed a useful surface modification technique for the nitriding an irregularly shaped three dimensional workpiece of austenite stainless steel and for the improvement of surface properties of AISI 304, such as hardness and strength

Surface Modification of Polymer Insulator by Plasma Surface Treatment (플라즈마 표면처리에 따른 고분자절연재료의 표면개질)

  • Lim, K.B.;Hwang, M.W.;Lee, B.S.;You, D.H.;Yuk, J.H.;Kim, H.G.;Lim, H.C.;Park, K.S.;Lee, D.C.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.31-35
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    • 2002
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.

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Surface Characterization of Hydrophobically Modified MCC Using Inverse Gas Chromatography (인버스 가스 크로마토 그래피를 이용한 소수화된 MCC의 표면 특성 분석)

  • Lee, Hak-Rae;Lee, Yong-Min;Park, Il;Lee, Jin-Hee;Cho, Joong-Yeon;Han, Sin-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.3
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    • pp.9-16
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    • 2002
  • The adsorption characteristics and surface energetics of hydrophobically modified MCC have been investigated by the inverse gas chromatography technique at infinite dilution. The thermodynamic parameters of adsorption, ΔG, ΔH and ΔS, for n-alkanes were determined at infinite dilution. Heats of adsoption of the n-alkanes increased as the level of hydrophobic modification increased. The hydrophobically modified MCC also showed greater entropy of adsorption indicating restricted mobility of the adsorbed n-alkanes. The acid/base characteristics of the MCC were evaluated using polar probes. As the hydrophobicity of MCC increased, the basisity of the MCC decreased.

EFFECT OF SOLUBLE ADDITIVES, BORIC ACID (H3BO3) AND SALT (NaCl), IN POOL BOILING HEAT TRANSFER

  • Kwark, Sang-M.;Amaya, Miguel;Moon, Hye-Jin;You, Seung-M.
    • Nuclear Engineering and Technology
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    • v.43 no.3
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    • pp.195-204
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    • 2011
  • The effects on pool boiling heat transfer of aqueous solutions of boric acid ($H_3BO_3$) and sodium chloride (NaCl) as working fluids have been studied. Borated and NaCl water were prepared by dissolving 0.5~5% volume concentration of boric acid and NaCl in distilled-deionized water. The pool boiling tests were conducted using $1{\times}1\;cm^2$ flat heaters at 1 atm. The critical heat flux (CHF) dramatically increased compared to boiling pure water. At the end of boiling tests it was observed that particles of boric acid and NaCl had deposited and formed a coating on the heater surface. The CHF enhancement and surface modification during boiling tests were very similar to those obtained from boiling with nanofluids. Additional experiments were carried out to investigate the reliability of the additives deposition in pure water. The boric acid and NaCl coatings disappeared after repeated boiling tests on the same surface due to the soluble nature of the coatings, thus CHF enhancement no longer existed. These results demonstrate that not only insoluble nanoparticles but also soluble salts can be deposited during boiling process and the deposited layer is solely responsible for significant CHF enhancement.

Phagocytic Uptake of Surface modified PLGA Microspheres Using Dendritic Cell

  • Kim, Ji-Seon;Lee, Young-Sung;Lee, Jung-Gil;Park, Jeong-Sook;Lee, Jong-Kil;Chung, Youn-Bok;Han, Kun
    • Journal of Pharmaceutical Investigation
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    • v.41 no.3
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    • pp.185-190
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    • 2011
  • The purpose of this study was to evaluate the phagocytic uptake of surface modified PLGA microspheres containing ovalbumin (OVA) into dendritic cell. In order to find the most suitable formulation for targeted delivery to antigen presenting cells (APC), OVA was encapsulated by a double emulsion solvent evaporation method with three PLGA microspheres (PLGA 50:50, PLGA 75:25 and PLGA 85:15) and two surface modified microspheres by chitosan and sodium dodecyl sulfate (SDS). Physicochemical properties were evaluated in terms of size, zeta potential, encapsulation efficiency, different scanning calorimeter (DSC), x-ray diffraction, morphology, and OVA release test from microspheres. Phagocytic activity was estimated using dendritic cells and analyzed by fluorescence activated cell sorter (FACS). The result showed that zeta potential of PLGA particles was changed to positive by the chitosan modification. The release profile of chitosan modified PLGA microspheres exhibited sustained release after initial burst. The chitosan modified microspheres had higher phagocytic uptake than the other microspheres. Such physicochemical properties and phagocytic uptake studies lead us to conclude that chitosan modified microspheres is more suitable formulation for the targeted delivery of antigens to APC compared with the other microspheres.

Experimental Study of Removing Surface Corrosion Products from Archaeological Iron Objects and Alternating Iron Corrosion Products by Nd:YAG Laser Cleaning System (Nd:YAG 레이저를 이용한 철제유물의 표면부식물 제거 및 성분 변화 연구)

  • Lee, Hye Youn;Cho, Nam Chul;Lee, Jong Myoung;Yu, Jae Eun
    • Korean Journal of Metals and Materials
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    • v.50 no.5
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    • pp.353-360
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    • 2012
  • The corrosion product of archaeological iron objects is supposed to be removed because it causes re-corrosion. So far it is removed by scapel and sand blaster but they depend on the skill and experience of a conservator and the glass-dust of the sand blaster is harmful to humans. Therefore this study applies a laser cleaning system which is used in various industrial cleaning processes, to remove corrosion product from archaeological iron objects. In addition, this work studies the alternation of corrosion product after laser irradiation, which evaluates the reliability of the laser cleaning system. Optical microscopy, SEM-EDS, XRD, Raman have been used to observe and analyse the surface of the objects. The results show the capacity of laser cleaning some corrosion product, but blackening appears with increasing pulses and laser energy, and some corrosion products, goethite and hematite, are partially altered to magnetite. These problems, blackening and alternation of corrosion product, should be solved by further studies which find the optimal laser irradiation condition and use a wetting agent.

Development of a reference framework to assess stylized human intrusion scenarios using GENII Version 2 considering design features of planned near-surface disposal facility in Korea

  • Kwon, Ki Nam;Cheong, Jae Hak
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1561-1574
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    • 2019
  • A standard form of six stylized human intrusion scenarios for a near-surface disposal facility (e.g. the planned Korean repository, Gyeongju Phase II) is proposed through re-categorization of totally thirty-one past cases reported in public literature. A reference assessment framework for inadvertent human intrusion is newly developed using GENII Version 2 conforming to the ICRP Publication 60 and thereafter. Calculated dose from the assessment framework is verified by comparing with hand calculation results for simplified model equations independently derived. Results from GENII Version 2 and 1.485 show inevitable differences, which is mainly attributed to the difference in the external dose assessment model. If intake dose coefficients in GENII Version 1.485 are modified, the difference can be reduced but still exist to an extent. Through deterministic and probabilistic sensitivity analysis, most affecting four parameters are derived and uncertainties of the parameters are quantified. It is expected that the reference assessment framework together with representative stylized scenarios can be used to do a human intrusion impact assessment for a specific repository using site-specific information. Especially, the past practice of human intrusion impact assessment using GENII Version 1.485 with or without modification may be replaced with the new assessment framework developed in this study.

Enhanced Photocatalytic Disinfection Efficiency through TiO2/WO3 Composite Synthesis and Heat Treatment Optimization

  • Sang-Hee Kim;Seo-Hee Kim;Jun Kang;Myeong-Hoon Lee;Yong-Sup Yun
    • Journal of Surface Science and Engineering
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    • v.57 no.3
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    • pp.179-191
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    • 2024
  • This study focuses on improving the photocatalytic degradation efficiency by synthesizing a TiO2/WO3 composite. Given the environmental significance of photocatalysis and the limitations posed by TiO2's large bandgap and high electron recombination rate, we explored doping, surface modification, and synthesis strategies. The composite was created using a ball mill process and heat treatment, analyzed with field emission scanning electron microscope, high resolution X-ray diffraction, Raman microscope, and UV-Vis/NIR spectrometer to examine its morphology, composition and absorbance. We found that incorporating WO3 into the TiO2 lattice forms a Wx-Ti1-x-O2 solution, with optimal WO3 content reducing the band gap and enhancing sterilization efficiency by inhibiting the anatasese to rutile transition. This contributes to the field by offering a way to overcome TiO2's limitations and improve photocatalytic performance.

Adhesion Behavior of Chondrocyte and Osteoblast on Surface-Modified Biodegradable PLLA Films and Scaffolds (표면개질된 생분해성 PLLA 필름 및 지지체의 연골세포와 조골세포 점착거동)

  • Choi, Ji-Yeon;Jung, Hyun-Jung;Park, Bang-Ju;Joung, Yoon-Ki;Park, Kwi-Deok;Han, Dong-Keun
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.357-363
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    • 2012
  • Surface-modified poly(L-lactic acid) (PLLA) films and scaffolds were treated with plasma discharge in oxygen gas and subsequently subjected to $in$ $situ$ grafting of acrylic acid (AA) in order to increase the cell compatibility. The surface of AA-grafted PLLA was converted to hydroxyapatite (HA)-deposited PLLA in stimulated body fluid (SBF). After the samples were immersed in phosphate-buffered saline (PBS), fetal bovine serum (FBS), normal saline, or cell medium, the water contact angles were significantly reduced on the surface of HA-deposited PLLA. Chondrocyte and osteoblast showed a higher attachment and cell proliferation on HA-deposited surfaces and in particular, it was confirmed that chondrocyte was considerably influenced by HA. However, osteoblast showed better cell proliferation on the surfaces immersed in FBS, cell medium or HA-deposited surface. In addition, the cell proliferation in 3D scaffolds was much higher than that on film type, irrespective of chondrocyte and osteoblast. Therefore, such surface-modified PLLAs are expected to be useful as organic-inorganic hybrid scaffolds in the regeneration of cartilage and bone.