• Title/Summary/Keyword: surface-modification technology

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Surface Transformation Hardening for Rod-shaped Carbon Steels by High Power Diode Laser (고출력 다이오드 레이저(HPDL)를 이용한 탄소강 환봉의 표면변태경화)

  • Kim, Jong-Do;Kil, Byung-Lea;Kang, Woon-Ju
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.8
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    • pp.961-969
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    • 2007
  • The laser material processing has replaced a conventional material processing such as a welding, cutting, drilling and surface modification and so on. LTH(Laser Transformation Hardening) is one branch of the laser surface modification process. A lot of energy is needed for the LTH process to elevate workpiece surface to temperature of the austenite transformation($A_3$), which results from utilizing a beam with a larger size and lower power intensity comparatively. The absorptivity of the laser energy with respect to material depends on the wave length of a beam. This study is related to the surface hardening for the rod-shaped carbon steel by the high power diode laser(HPDL) whose beam absorptivity is better than conventional types of lasers such as $CO_2$ or Nd:YAG laser. Because a beam proceeds on the rotating specimen the pretreated hardened-phase can be tempered and softened by the overlapping between hardened tracks. Accordingly, the longitudinal hardness measurement and observation of the micro structure was carried out for an assessment of the hardening characteristics. In addition, a hardening characteristics as a hardenability of materials was compared in the point of view of the hardness distribution and hardening depth and width.

Surface Modification and Medical Formulation Technology Using Adhesion of Plant Tannic Acid (식물 유래 탄닌산의 접착능을 이용한 표면 개질 및 의료용 제형 기술 동향)

  • Park, Eunsook;Shin, Mikyung;Lee, Haeshin
    • Journal of Adhesion and Interface
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    • v.20 no.2
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    • pp.71-75
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    • 2019
  • Tannic acid is one of the most commonly found polyphenols in the vegetable field. Initially, research on tannins concentrated on physiological functions such as antioxidants. Recently, however, tannic acid has attracted much interest as a molecular glue as it has been found to interact virtually all bio-macromolecules such as proteins and DNA. The various properties of tannic acid are expected to control the wettability of the surface, contribute to energy storage and generation, and show potential as a medical agent. Here, tannic acid will be discussed about the interaction of with bio-macromolecules as a molecular glue, surface modification, and utilization of itself as biomaterials.

Surface Treatment with CO2 to Improve Electrochemical Characteristics of Carbon Felt Electrode for VRFB

  • Yechan Park;Sunhoe Kim
    • Journal of Electrochemical Science and Technology
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    • v.14 no.2
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    • pp.131-138
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    • 2023
  • The carbon felt is usually hired as electrodes for vanadium redox flow battery (VRFB). In the study, surface modification of carbon felt under CO2 atmosphere with variables of operating various temperature ranges between 700℃ and 900℃. The qualitative and quantitative analysis were carried out such as scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) to observe degree of surface modification. Result of XPS analysis confirmed increase of carbon and oxidation functional group on the surface with increase of temperature. SEM image was discovered similar phenomena. Electrochemical characteristics such as cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) revealed the improved electrode performance with increase of temperature. However, the electrochemical performance under treatments temperature of 900℃ was less than that of under treatment temperature of 850℃ due to weight loss at the treatment temperature of 900℃. From the CV and EIS results, the best electrochemical characteristics was at the temperature of 850℃. That of at the temperature of 900℃ was decreased due to weight loss. The energy efficiencies (EE) obtained from full cell test were 69.37, 80.76, 82.45, and 75.47%, at the temperature of 700, 800, 850, and 900℃, respectively.

A Study on the Analysis of Surface Heat Flux Using the Transient Heat Flux Method (비정상열유속 기법을 이용한 표면 열유속 해석에 관한 연구)

  • Yi, Jong-Ju
    • Journal of the Korea Institute of Military Science and Technology
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    • v.13 no.3
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    • pp.503-510
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    • 2010
  • The quick variation of the canister wall temperature causes the modification of the shape of canister wall. This paper is the possibility of adoption and the error analysis about the transient heat flux method. The commercial code(Fluent Ver6.2.16) was employed for the calculation of surface temperature in the case of steady and unsteady heat flux condition. Based the surface temperature variation and surface material property, transient heat flux method can calculate the surface heat flux. In the case of steady heat flux condition, the error is about 2%, and in the case of unsteady heat flux condition, the error is about 3.6%. With the unsteady heat flux condition, the time which reach the maximum surface heat flux is almost same between the numerical analysis and transient heat flux method.

Influence of Plasma Treatment on The Soil Release Properties of Polyester Fabrics (플라즈마처리가 폴리에스테르 직물의 오염제거성에 미치는 연구)

  • Kwon, Young-Ah
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.434-435
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    • 2003
  • Physicochemical properties of a polymer surface significantly affect adhesion, wetting, and dyeing properties. In recent years, low temperature plasma technology has been widely used for surface modification of polymers. Surface fluorination by low temperature plasma treatment has been employed to improve the water and oily repellency of textile fabrics. However, very few results have been reported on soil release properties of the oxygen plasma treated textile fabrics. (omitted)

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The Study for Estimation of the Surface Temperature Rise in Spur Gear Tooth (Spur Gear 치면의 표면상승온도 예측에 관한 연구)

  • 김희진;구영필;조용주
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.2
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    • pp.331-337
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    • 2001
  • A numerical simulation of the temperature rise for sliding surface in dry contact is based on Jaegers formula combined with a calculated heat input. A gear tooth temperature analysis was performed. The pressure distribution has the Hertzian pressure distribution on the heat source. The heat partition factor is calculated along ling of action. A Temperature distribution of tooth surface is calculated about before and after profile modification. A Temperature of addendum and deddendum in modified gear have reduced.

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Investigation of chemical modification on tosyl-activated polystyrene microsphere magnetic particle surface by infrared microscopy (토실 활성화된 폴리스티렌 마이크로구체 자성 입자 표면의 화학적 변형에 대한 적외선 연구)

  • Byun, Chang Kyu
    • Analytical Science and Technology
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    • v.29 no.5
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    • pp.225-233
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    • 2016
  • The chemical engrafting of polymers on particle surface, plays an important role on selective partitioning of micro/nano-particles in the separated layers of liquid media, such as aqueous two phase systems (ATPSs). Three polymers, dextran, poly (ethylene glycol) and albumin were chosen and chemically conjugated to the polystyrene (PS) magnetic microparticle surface. The attachment of long-chained polymer chains which may switch the partition behavior, can be simply performed by SN2 substitution of various polymers having primary amine functional groups, with p-toluenesulfonyl (tosyl)-activated polystyrene magnetic micro-particles. The surface modification of microparticle was probed by infrared microscopy. The distinctive peak represents N-H stretching vibration mode for microparticles after the reaction and it is common for all three polymers examined. The locations of main peaks are similar for all micro-particles but different and distinguishable in fingerprint region.

Surface-modified Nanoparticle Additives for Wear Resistant Water-based Coatings for Galvanized Steel Plates

  • Becker-Willinger, Carsten;Heppe, Gisela;Opsoelder, Michael;Veith, H.C. Michael;Cho, Jae-Dong;Lee, Jae-Ryung
    • Corrosion Science and Technology
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    • v.9 no.4
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    • pp.147-152
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    • 2010
  • Conventional paints for conversion coating applications in steel production derived mainly from water-based polymer dispersions containing several additives actually show good general performance, but suffer from poor scratch and abrasion resistance during use. The reason for this is because the relatively soft organic binder matrix dominates the mechanical surface properties. In order to maintain the high quality and decorative function of coated steel sheets, the mechanical performance of the surface needs to be improved significantly. In fact the wear resistance should be enhanced without affecting the optical appearance of the coatings by using appropriate nanoparticulate additives. In this direction, nanocomposite coating compositions (Nanomer$^{(R)}$) have been derived from water-based polymer dispersions with an increasing amount of surface-modified nanoparticles in aqueous dispersion in order to monitor the effect of degree of filling with rigid nanoparticles. The surface of nanoparticles has been modified for optimum compatibility with the polymer matrix in order to achieve homogeneous nanoparticle dispersion over the matrix. This approach has been extended in such a way that a more expanded hybrid network has been condensed on the nanoparticle surface by a hydrolytic condensation reaction in addition to the quasi-monolayer type small molecular surface modification. It was expected that this additional modification will lead to more intensive cross-linking in coating systems resulting in further improved scratch-resistance compared to simple addition of nanoparticles with quasi-monolayer surface modification. The resulting compositions have been coated on zinc-galvanized steel and cured. The wear resistance and the corrosion protection of the modified coating systems have been tested in dependence on the compositional change, the type of surface modification as well as the mixing conditions with different shear forces. It has been found out that for loading levels up to 50 wt.-% nanoparticles, the mechanical wear resistance remains almost unaffected compared to the unmodified resin. In addition, the corrosion resistance remained unaffected even after $180^{\circ}$ bending test showing that the flexibility of coating was not decreased by nanoparticle addition. Electron microscopy showed that the inorganic nanoparticles do not penetrate into the organic resin droplets during the mixing process but rather formed agglomerates outside the polymer droplet phase resulting in quite moderate cross linking while curing, because of viscosity. The proposed mechanisms of composite formation and cross linking could explain the poor effect regarding improvement of mechanical wear resistance and help to set up new synthesis strategies for improved nanocomposite morphologies, which should provide increased wear resistance.

Low-impedance Tetrodes using Carbon Nanotube-Polypyrrole Composite Deposition

  • Kim, Minseo;Shin, Jung Hwal;Lim, Geunbae
    • Journal of Sensor Science and Technology
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    • v.26 no.2
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    • pp.73-78
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    • 2017
  • A tetrode is one of the neural electrodes, and it is widely used to record neural signals in the brain of a freely moving animal. The impedance of a neural electrode is an important parameter because it determines the signal-to-noise ratio of the recorded neural signals. Here, we developed a modification technique using carbon nanotube-polypyrrole composite nanostructures to decrease the impedances of tetrodes. The synthesis of the carbon nanotube and polypyrrole nanostructures was performed in two steps. In the first step, randomly dispersed carbon nanotubes and pyrrole monomers were gathered and aligned on the tetrode electrode. Next, they were electro-polymerized on the electrode surface. As the applied time (step-1 and step-2) and the offset voltage increased, the impedances of the tetrodes decreased. The modification technique is, therefore, an important and useful of lowering the impedances of tetrodes.

Enhancement of Wear and Corrosion Resistances of Monocrystalline Silicon Wafer (단결정 실리콘 웨이퍼의 내마모성 및 내식성 향상을 관한 연구)

  • Urmanov, B.;Ro, J.S.;Pyun, Y.S.;Amanov, A.
    • Tribology and Lubricants
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    • v.35 no.3
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    • pp.176-182
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    • 2019
  • The primary objective of this study is to treat a monocrystalline silicon (Si) wafer having a thickness of $279{\mu}m$ by employing the ultrasonic nanocrystal surface modification (UNSM) technology for improving the efficiency and service life of nano-electromechanical systems (NEMSs) and micro-electromechanical systems (MEMSs) by enhancing of wear and corrosion resistances. The wear and corrosion resistances of the Si wafer were systematically investigated before and after UNSM treatment, wherein abrasive, oxidative and spalling wear mechanisms were applied to the as-received and subsequently UNSM-treated Si wafer. Compared to the asreceived state, the wear and corrosion resistances of the UNSM-treated Si wafer are found to be enhanced by about 23% and 14%, respectively. The enhancement in wear and corrosion resistances after UNSM treatment may be attributed to grain size refinement (confirmed by Raman spectroscopy) and modified surface integrity. Furthermore, it is observed that the Raman intensity reduced significantly after UNSM treatment, whereas neither the Raman shift nor new phases were found on the surface of the UNSM-treated Si wafer. In addition, the friction coefficient values of the as-received and UNSM-treated Si wafers are found to be about 0.54 and 0.39, respectively. Hence, UNSM technology can be effectively incorporated as an alternative mechanical surface treatment for NEMSs and MEMSs comprising Si wafers.