• Title/Summary/Keyword: surface wettability

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The Behavioral Characteristics of a Droplet on the Line Patterned Surface Including Water Film (수막을 가지는 선형 젖음성 패턴 표면에서의 액적 거동 특성)

  • Lee, Changwoo;Park, Jinyoung;Cho, Handong;Hwang, Woonbong
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.12
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    • pp.1335-1340
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    • 2013
  • Herein the water film was introduced to the hydrophilic area on the line patterned surface to solve the contradiction caused by surface roughness (high different wettability has advantage to control the droplet but high roughness for that high wettability difference causes obstruction of droplet moving). Thus the droplet on the water film could not be hindered to line direction but restricted to orthogonal direction, effectively. In addition, droplet behaviors according to droplet volume and line thickness were studied. Droplet fell off the line with narrowing the interface between the droplet and the water film on the line. When the droplet fell off the line, the plate angle was designated as a critical plate angle and it used as an indicator of surface capability to control the droplet. As a result critical plate angle increases as droplet volume decreases and line thickness increases.

Manufacture and Analysis of Ophthalmic Polymers including Gold Nanoparticles with Surface Modification Method

  • Seon-Young Park;Su-Mi Shin;A-Young Sung
    • Korean Journal of Materials Research
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    • v.34 no.4
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    • pp.194-201
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    • 2024
  • In this study, the surfaces of two gold nanoparticles of different shapes were modified with hexadecyltrimethylammonium bromide (CTAB) and used for contact lenses. The polymer was based on 2-hydroxyethyl methacrylate (HEMA), and spherical and sea urchin-shaped gold nanoparticles were used as additives. CTAB was used to modify the surface of the sea urchin-shaped gold nanoparticles. To analyze the physical properties of the prepared contact lens, optical transmittance, refractive index, water content, contact angle, and atomic force microscope (AFM) were measured and evaluated. The results showed the nanoparticles did not significantly affect optical transmittance, refractive index, or water content of the lens, and tensile strength increased according to the ratio of the additive. The addition of the sea urchin-shaped nanoparticles resulted in lower wettability compared with the spherical nanoparticles, but somewhat superior tensile strength. In addition, it was found that the wettability of the lens was improved when the surface-modified sea urchin-shaped gold nanoparticles were added. The types of gold nanoparticles and surface modification methods used in this study are considered to have great potential for use in ophthalmic materials.

Surface Modification of Polydimethylsiloxane using Nd:YAG Laser (Nd:YAG 레이저를 이용한 PDMS 표면개질)

  • Shin Sung-Kwon;Song Hyun-Seung;Lee Cheon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.2
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    • pp.181-184
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    • 2006
  • Nd:YAG($\lambda$=266 nm, pulse) laser beam was irradiated on the PDMS surface to improve its chemical reaction, wettability, adhesive property. The various surface modification methods of PDMS were already studied using oxygen plasma, ozone and corona discharge. The surface modification using laser has the advantage of the simple experiment that only directly irradiated laser beam on the PDMS surface in the air. After the laser treatment, the PDMS surface was investigated using a contact angle measuring instrument. The contact angle was decreased with a increase of the surface oxygen content. In conclusion, the wettability of PDMS surface was improved by the laser treatment without changing of its bulk characteristics.

Effect of various intraoral repair systems on the shear bond strength of composite resin to zirconia

  • Han, In-Hae;Kang, Dong-Wan;Chung, Chae-Heon;Choe, Han-Cheol;Son, Mee-Kyoung
    • The Journal of Advanced Prosthodontics
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    • v.5 no.3
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    • pp.248-255
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    • 2013
  • PURPOSE. This study compared the effect of three intraoral repair systems on the bond strength between composite resin and zirconia core. MATERIALS AND METHODS. Thirty zirconia specimens were divided into three groups according to the repair method: Group I-CoJet$^{TM}$ Repair System (3M ESPE) [chairside silica coating with $30{\mu}m$ $SiO_2$ + silanization + adhesive]; Group II-Ceramic Repair System (Ivoclar Vivadent) [etching with 37% phosphoric acid + Zirconia primer + adhesive]; Group III-Signum Zirconia Bond (Heraus) [Signum Zirconia Bond I + Signum Zirconia Bond II]. Composite resin was polymerized on each conditioned specimen. The shear bond strength was tested using a universal testing machine, and fracture sites were examined with FE-SEM. Surface morphology and wettability after surface treatments were examined additionally. The data of bond strengths were statistically analyzed with one-way ANOVA and Tamhane post hoc test (${\alpha}$=.05). RESULTS. Increased surface roughness and the highest wettability value were observed in the CoJet sand treated specimens. The specimens treated with 37% phosphoric acid and Signum Zirconia Bond I did not show any improvement of surface irregularity, and the lowest wettability value were found in 37% phosphoric acid treated specimens. There was no significant difference in the bond strengths between Group I ($7.80{\pm}0.76$ MPa) and III ($8.98{\pm}1.39$ MPa). Group II ($3.21{\pm}0.78$ MPa) showed a significant difference from other groups (P<.05). CONCLUSION. The use of Intraoral silica coating system and the application of Signum Zirconia Bond are effective for increasing the bond strength of composite resin to zirconia.

A Study on the Surface Degradation Phenomena and Electrical Properties of Polymer Composite Materials (고분자 복합재료의 표면 열화 현상과 전기적 특성에 관한 연구)

  • Park, Jae-Sae;Lim, Kyung-Bum
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.75-78
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    • 2002
  • In this paper, we investigated the change of wettability, surface potential decay and surface resistivity caused by thermal-treated and plasma-treated FRP respectively for finding out the influence of electrical characteristics on the surface of polymer composites. For the change of wettability, the contact angle of thermal-treated specimen with the high temperature of 200$^{\circ}C$ increased. But that of plasma-treated specimen decreased. The characteristic of surface potential decay shows the tendency of the remarkable decrease on plasma-treated specimens, but no difference on thermal-treated specimen compared with untreated one. Also, for the surface resistivity, it shows the same trend compared with the change of contact angle. We can conclude that the degradation phenomena of epoxy surface are dominated by the induction of hydrophilicity and hydrophobicity.

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POSSIBILITY OF PARTIAL MELTING SOLDERING PROCESS WITH OFF EUTECTIC LEAD FREE SOLDER ALLOYS

  • Kang, Choon-Sik;Ha, Jun-Seok;Park, Jae-Yong;Jung, Jae-Pil
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.791-797
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    • 2002
  • This paper introduces the partial melting process for solder application and characterization of its feasibility using Sn-Ag, and Sn-Cu solder alloys. ill order to show that the liquid phase in the semi-liquid state maintains the similar wettability as single-phase liquid, the wetting balance tests are conducted with varying temperatures and compositions. Also, as a new soldering technology, the microstructural and mechanical test were investigated. The results from this research indicate that the partial melting can yield satisfactory sider joints as long as the liquid phase acquires sufficient chemical activity. At a condition where the partial melting is effective, a direct correlation between the wettability and the surface tension is found to exist.

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The Effect of Micro Nano Multi-Scale Structures on the Surface Wettability (초소수성 표면 개질에 미치는 마이크로 나노 복합구조의 영향)

  • Lee, Sang-Min;Jung, Im-Deok;Ko, Jong-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.5
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    • pp.424-429
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    • 2008
  • Surface wettability in terms of the size of the micro nano structures has been examined. To evaluate the influence of the nano structures on the contact angles, we fabricated two different kinds of structures: squarepillar-type microstructure with nano-protrusions and without nano-protrusions. Microstructure and nanostructure arrays were fabricated by deep reactive ion etching (DRIE) and reactive ion etching (RIE) processes, respectively. And plasma polymerized fluorocarbon (PPFC) was finally deposited onto the fabricated structures. Average value of the measured contact angles from microstructures with nanoprotrusions was $6.37^{\circ}$ higher than that from microstructures without nano-protrusions. This result indicates that the nano-protrusions give a crucial effect to increase the contact angle.

Wettability and Water Repellency of Polyester Fabrics Treated by Low Temperture Plasma (저온플라즈마처리에 의한 폴리에스테르직물의 흡수성 및 발수성 변화)

  • 권영아
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.2
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    • pp.317-328
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    • 1995
  • The objective of this study was to determine the effects of low temperature plasma on the surface properties of polyester fabric with respect to wettability and water repellency. Highly wettable polyester fabric surfaces were obtained by oxygen treatment. The improved wettabililty of oxygen plasma treated fabrics decreased with aging time up to 30 days, and then the wettability remained relatively constant and still exhibited significant improvement compared to that of untreated polyester. Water repellency was significantly improved by tetratfluorocarbon plasma treatment. Such an improvement appears due to introduced fluo\ulcornerrine atoms or a thin fluorocarbon film on the fiber surface. Water repellency remained constant in fact, even after 150 days.

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Control of Wettability Using Regularly Ordered Two-Dimensional Polymeric Wavy Substrates

  • Yi, Dong Kee
    • Nano
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    • v.13 no.10
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    • pp.1850120.1-1850120.9
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    • 2018
  • Two-dimensional poly(dimethylsiloxane) (PDMS) films with wavy patterns were studied in order to investigate reversible and irreversible wetting effects. Pre-strained, surface oxidized layers of PDMS were used to form relieved wavy geometries, on which hydrophobic functionalization was carried out in order to produce irreversible wetting effects. Wavy-patterned PDMS films showed time-dependent reversible wetting effects. The degree of surface wettability could be tuned by the choice of wavy groove geometries. And the groove geometries were controlled via $O_2$ plasma treatment and mechanical pre-straining. The pre-strained, buckled PDMS films were applied to the fabrication of hydrophobic polystyrene nano-patterns using colloidal self-assembly, where the colloids were arrayed in two-dimensional way. The wavy polystyrene films were found to be more hydrophobic relative to flat polystyrene films. The grooving methodology used in this study could be applied to enhancing the hydrophobicity of other types of polymeric thin films, eliminating the need for chemical treatment.

Ion Release and Biocompatibility of Sintered Ni-Cr-Ti Alloy for Dental Prosthodontics (치과보철용 Ni-Cr-Ti소결체합금의 이온용출과 생체적합성)

  • Choe, Han-Cheol;Kim, Seung-Hui
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.360-365
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    • 2017
  • In this study, ion release and biocompatibility of sintered Ni-Cr-Ti alloy for dental prosthodontics have been researched by corrosion and cell culture test. The microstructures of the alloys were observed by optical microscope, and corrosion behavior was investigated using potentiostat (Model PARSTAT 2273, EG&G, USA). Cell culture was carried out using hGf cell in DMEM (Welgene Inc., South Korea) supplemented with 10% fetal bovine serum (FBS) (Welgene Inc., South Korea) and antibiotic antimycotic solution (Welgene Inc., South Korea). After corrosion and cell culture test, surface morphologies were observed by field-emission scanning electron microscopy. For wettability behaviors, contact angles were measured by wettability test. As the content of Ti increased, the number of pit decreased and the corrosion resistance was improved from anodic polarization test, also, polarization resistance of samples containing Ti remarkably improved as compared with the alloy not containing Ti. The sintered alloy showed a low contact angle due to the pores formed on the surface. The addition of Ti element showed that the cell survival rate was better than that of the control group.