• Title/Summary/Keyword: surface wettability

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Surface control and durability evaluation of CNT and ITO coated PET transparent electrode with different dry conditions (건조 상태에 따른 CNT 및 ITO로 코팅된 PET 투명전극의 표면 조절 및 내구성 평가)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Gu, Ga-Young;Park, Joung-Man
    • Composites Research
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    • v.24 no.5
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    • pp.17-22
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    • 2011
  • Recently transparent electrodes using carbon nanotube (CNT) have been studied actively to replace conventional ITO. In this work, CNT or ITO coated poly(ethylene terephthalate) (PET) were prepared by controlling the surfaces since the cohesion degree depends upon drying conditions. As transparent electrode application, 3 drying temperatures were set as 20, 80, and $120^{\circ}C$ to produce the change of surface properties. Interfacial durability and electrical properties of prepared transparent electrodes were evaluated by electrical resistance measurement. Surface change with changing drying temperature was observed by FE-SEM, whereas the transparency change was measured by UV-spectroscopy. The electronic properties of nanoparticle coated surface were evaluated using cyclic voltametry method upon the surface change with controlled drying temperature. Durability of CNT coated surfaces was better than ITO coated ease. As drying temperature increased, better coated surface was prepared due to improved cohesion among nanoparticles, which resulted in increased electrical properties.

Research Trends in the Nanoscale Friction and Surface Characteristics of Graphene (그래핀의 나노스케일 마찰 및 표면 특성에 대한 연구동향)

  • Yoon, Min-Ah;Kim, Kwang-Seop;Cho, Dae-Hyun
    • Tribology and Lubricants
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    • v.37 no.5
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    • pp.151-163
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    • 2021
  • Since the discovery of single-layer graphene, exploiting graphene's excellent physical/chemical properties in tribology systems has been a topic of interest in academia over the last few decades. There is no doubt that understanding the underlying friction mechanism of graphite should precede this. Even now, new properties of graphene are being reported in academia, and based on this, studies exploring the origins of graphene's surface properties and friction characteristics in a wide range of scales are also being performed. From the perspective of lubrication engineering, graphene research can be largely divided into studies that 1) reveal its basic friction mechanism at the nanoscale and 2) explore its application in macroscale sliding systems. At the nanoscale, the basic friction mechanism of graphene is mainly due to its atomic thickness. In this paper, the various research on the nanoscale friction and surface characteristics of graphene is reviewed. Graphene surface properties, such as wettability and surface energy and the basic friction mechanisms of graphene attributed to adhesion, electronphonon scattering, bending stiffness, and the underlying substrate, are summarized. Further, we provide the research outcomes on the superlubricity of graphene. Finally, the potential application and challenges of the superlubricity of graphene are highlighted. Through this, we intend to provide summarized information to researchers interested in the tribological properties of graphene and help set the direction of future research.

Study on the Controlled Gel Formation and Photochromic Properties of a New Cholesterol-bridge-naphthopyran Dyad

  • Sun, Lin;Wang, Guang;Liu, Longbo;Wang, Ai Xia
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1343-1348
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    • 2014
  • A cholesterol-bridge-naphthopyran dyad (NP-MCB) was designed and synthesized. NP-MCB can readily self-assemble into gels under ultrasound-radiation in several organic solvents and the formed gels easily transfer to solution by heat. This reversible process can be repeated many times. Scanning Electron Microscopy results showed that the morphologies of all formed xerogels in different solvents have fibrillar microstructure. The gels formation was due to energy and pressure afforded by the ultrasonic process, resulting in formation of molecular hydrogen bonding and molecular aggregation. NP-MCB displayed the normal photochromism both in solution and gel states. The kinetic results confirm that the colored merocyanine in gels show a slower fading speed than that in solution due to the compact aggregation of NP-MCB molecules in gels. The xerogel film formed in polar gelling solvent had large surface wettability than that in nonpolar gelling solvent.

Effectiveness of Enzymatic Hydrolysis on Polyamide Fabric

  • Kim, Hye Rim;Seo, Hye Young;Song, Ah Reum
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.7
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    • pp.962-971
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    • 2013
  • We compared the effectiveness of amidase (amano acylase, AA) and an endopeptidase, (trypsin, TR) in modifying the hydrophobicity of polyamide fabric. We evaluated the number of amino groups released into the reaction mixture in order to optimize the treatment conditions. We found that a large number of amino groups were released into the reaction mixture due to the cleavage of amide bonds by AA hydrolysis; however, the TR hydrolysis exhibited a relatively lower activity compared to AA hydrolysis. In AA and TR hydrolysis, significant differences were observed in the K/S values and moisture regain. Amide bonds in polyamide fabric were hydrolyzed by AA hydrolysis effectively. Compared to TR, AA formed more hydrolysis product (amino groups) on the fabric surface. Thus, the hydrophobicity of polyamide fabric was modified using AA hydrolysis (as verified by the wettability test) without any deterioration of fiber strength.

Development of Washable Wool Using Environmental-friendly Spray UV-cure Finishing Technique - Using Photocrosslinkable Polymerr Dextran-methacrylate- (환경친화적 Spray UV-Cure 가공 기술을 이용한 물세탁 모직물(washable wool)의 개발 -광가교 고분자인 dextran-methacrylate를 이용하여-)

  • 김신희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.11
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    • pp.1507-1515
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    • 2004
  • Washable wool was developed using environmental-friendly spray UV-cure technique. Photocrosslinkable polymer, dextran-methacrylate, was synthesized starting from natural biopolymer, dextran. The aqueous solution of dextran-methacrylate was applied to wool fabric with various concentrations to find out the optimum condition in minimizing felting shrinkage. The wool fabric subsequently cured by 365 nm UV, The effects of UV-cure time and photoinitiator concentration on felting behavior of wool were examined. As the concentration of dextran-methacrylate increased, the felting shrinkage decreased gradually. At concentration 0.5g/ml, the felting shrinkage of wool was negligible. Other properties such as air permeability, moisture content, wrinkle recovery, thickness and wettability were also evaluated. The surface coating of dextran polymer onto wool fiber was identified by SEM.

Improvement of Printing Properties of PET Micro Filament Fabrics Using Low Temperature Plasma Technology(I) (저온 plasma 기술에 의한 PET 극세사직물의 날염성 개선(I))

  • 조규민;이종훈
    • Textile Coloration and Finishing
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    • v.7 no.1
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    • pp.1-9
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    • 1995
  • In order to improve dyeability of poly(ethylene terephthalate)(PET) micro filament fabrics, the effect of the prior oxygen low temperature plasma on the subsequent dyeing(deep dyeing, printing) was examined in various conditions. The apparent concentration of dyed PET micro filament fabrics was increased by $O_{2}$plasma treatment. Higher discharge power levels and higher reactor pressure values created more significant effect. The wettability was significantly increased by $O_{2}$ plasma treatment. Therefore, it is predicted that introducing hydrophilic group on the surface of material can improve the apparent concentration of PET micro filament fabrics.

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Influence of Spring on The Absorption Performance of a Vertical Absorber Tube (수직 흡수전열관의 흡수성능에 미치는 스프링의 영향)

  • 김정국;조금남
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.10
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    • pp.825-832
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    • 2002
  • The present study investigated the enhancement of the absorption performance by the spring wrapped around the outer surface of the vertical falling film absorber tube. Heat and mass transfer enhancements were experimentally investigated, and flow visualization was performed to observe the wettability and flow pattern of the solution. The key experimental parameters were spring diameter (0.5, 1.0 mm) and spring pitch (1, 3, 10 mm), film Reynolds number (50~150), and concentration of LiBr-$H_2O$ solution (55, 60, 65 wt%). As the spring diameter was increased, the absorption mass flux, Sherwood number, Nusselt number, heat flux, and heat transfer coefficient were increased The Nusselt and Sherwood numbers showed the maximum at the spring pitch of 3mm, and the ratio of pitch to diameter of approximately 3 and 6 for the spring diamter of 0.5 mm, respectively.

A sturdy on the sintering characteristics for Cu-Cr contact material (Cu-Cr 계 접점재료의 소결특성에 관한 연구)

  • Yeon, Young-Myoung;Oh, Il-Sung;Park, Hong-Tae;Lee, Sang-Yeup;Seo, Jung-Min
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1643-1645
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    • 2000
  • The effects of pre-sintering and infiltration conditions on the electrical and physical properties of Cu-Cr contact material have been studied. Specimens were prepared by infiltration technique, aiming at the final composition of Cu50w%Cr, with varying pre-sintering and infiltration conditions. It showed that increased pre-sintering temperature had a little influence on the final microstructure of Cu-Cr contact material, but improved the surface morphology of Cr-skeleton resulting in better wettability in the followed infiltration process. It also showed that Cr grain growth and gram shape change became prominent with increasing infiltration temperature and time.

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Effect of Fe Magnetic Nanoparticles in Rubber Matrix

  • Uhm, Young-Rang;Kim, Jae-Woo;Jun, Ji-Heon;Lee, Sol;Rhee, Chang-Kyu;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.173-178
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    • 2010
  • A new kind of magnetic rubber, Fe dispersed ethylene propylene monomer (EPM), was prepared by a conventional technique using a two roll mill. The magnetic fillers of Fe-nanoparicles were coated by low density polyethylene (LDPE). The purpose of surface treatment of nanoparticles by LDPE is to enhance wettability and lubricancy of the fillers in a polymer matrix. The mechanical strength and microstructure of the magnetic rubber were characterized by tensile strength test and scanning electron microscopy (SEM). Results revealed that the Fe nanoparticles were relatively well dispersed in an EPM matrix. It was found that the nano- Fe dispersed magnetic rubber showed higher coercivity and tensile strength than those of micron- Fe dispersed one.

A Study on the Improvement of Interfacial Properties of Epoxy Composites (에폭시 복합재료의 계면특성 향상에 관한 연구)

  • Lim, K.B.;Lee, S.H.;You, D.H.;Yuk, J.H.;Hwang, M.H.;Kim, Y.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.124-126
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    • 2002
  • In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate, dielectric property and tensile strength were improved.

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