• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.136-136
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• 2013

High-resolution photoemission spectroscopy (HRPES) measurements were collected and density functional theory (DFT) calculations were conducted to track the coverage dependent variation of the absorption structure of 2-thiophenecarboxaldehyde (C4H3SCHO: TPCA) on the Ge(100) surface at room temperature. In an effort to identify the most probably adsorption structures on the Ge(100) surface, we deposited TPCA molecules at a low coverage and at a high coverage and compared the differences between the electronic features measured using HRPES. The HRPES data provided three possible adsorption structures of TPCA on the Ge(100) surfaces, and DFT calculations were used to determine the plausibility of the structures. HRPES analysis, corroborated by DFT calculations, indicated that an S-dative bonded structure was the most probable adsorption structure at relatively lower coverage levels, the [4+2] cycloaddition structure was the second most probable structure, and the [2+2]-C=O cycloaddition structure was the last probable structure on the Ge(100) surfaces at relatively higher coverage levels.

• Journal of electromagnetic engineering and science
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• v.9 no.1
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• pp.46-52
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• 2009

This paper conducts a study on the frequency-dependent filtering and blocking effects of a variety of periodic structures, dubbed frequency selective surface(FSS). The periodic structures of interest are 1D and 2D repeated patterns of metal patches or slots sitting on the interface between the two different regions in the layered media which will show the capacitive or inductive behaviors and incorporated with the electromagnetic bandgap(EBG) geometry as another stratified media. Besides the normal substances so called double positive(DPS)-type in the layered media, metamaterials of double negative(DNG) are considered as layering components on the purpose of investigating the unusual electromagnetic phenomena. Frequency responses of transmission(absorption in terms of scattering) and reflection will be calculated by a numerical analysis which can be validated by the comparison with the open literature and demonstrated for the periodic structures embedding metamaterials or not. Most importantly, numerous examples of FSS will present the useful guidelines to have absorption or reflection properties in the frequency domain.

• Journal of Environmental Impact Assessment
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• v.20 no.6
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• pp.797-813
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• 2011

Frequently occurring flood and drought due to abnormal climate and global warming have increased the necessity of an effective water resources control and management of river flows. The various hydraulic structures are constructed in river as part of an effective water resources management. It is very important to analyse characteristics of flow according to installing hydraulic structures in this situations. The objective of this study is to investigate the hydraulic behaviors of flow considering affections of hydraulic structures using 2-D numerical model. To do this, both RMA-2 model and developed RAM2 model are used to analyse flow phenomena before and after installation of hydraulic structures in Nakdong river. As a result of, the water surface elevation at upstream regions increased about 22cm~66cm and the velocity around the structures sharply increased after installation of structures. The measures for the rise of water surface at upstream and local scour due to high velocity around the structures must be established when the structures is constructed.

• Journal of Industrial Technology
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• v.39 no.1
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• pp.33-39
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• 2019

This paper addresses effects of nanoscale structures on structural colors of micropatterned transparent substrate by light diffraction. Structural colors is widely investigated because they present colors without any chemical pigments. Typically structural colors is presented by diffraction of light on a micropatterned surface or by multiple interference of light on a surface containing a periodic or quasi-periodic nano-structures. In this paper, each structural colors induced by quasi-periodic nano-structures, periodic micro-structures, and nano/micro dual structures is measured in order to investigate effects of nanoscale and microscale structures on structural colors in the transparent substrate. Using pre-fabricated pattern mold and hot-embossing process, nanoscale and microscale structures are replicated on the transparent PMMA(Poly methyl methacrylate) substrate. Nanoscale and microscale pattern molds are prepared by anodic oxidation process of aluminum sheet and by reactive ion etching process of silicon wafer, respectively. Structural colors are captured by digital camera, and their optical transmittance spectrum are measured by UV/visible spectrometer. From experimental results, we found that nano-structures provide monotonic colors by multiple interference, and micro-structures induce iridescent colors by diffraction of light. Structural colors is permanent and unchangeable, thus it can be used in various application field such as security, color filter and so on.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.04a
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• pp.272-277
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• 1997

The object of this paper is to analyze the surface temperature of RC structures caused by fire. The experimental analysis is undertaken by using following two methods. 1) Simulation to analyze the relationship between the temperature and the condition change for glass wool caused by fire. 2) Temperature-analysis (TG/DTA tests) of RC structures. From the results of the two experimental analysis, it was possible to estimate the temperature of RC concrete structures caused by fire.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.2
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• pp.655-666
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• 2014

Recently, as the appearance and exterior design of the construction structure are highlighted, the irregularly shaped structures are increasing in a construction facility. Many softwares provide a quantity take-off function of 3D object under BIM environment, however, they are focused on the limited function based on the solid modeling method. Because the vast geometric information of the curved surface is difficult to extract in the 3D objects that consist of major changes in vertical section shape as the irregularly shaped structures, it is difficult to express a 3D object as a solid model. On the other hand, the irregularly shaped structures can be expressed in relatively free in the surface model because the surface model consists of points, lines and surfaces. Accordingly, the surface modeling method is suitable for the modeling of large irregularly shaped structures. This study suggests a quantity take-off algorithm for the irregularly shaped structures using the surface modeling approach that is beneficial in the design work of structures. Some case projects are used for verifying the accuracy of the proposed method.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.253-256
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• 2006

For nuclear concrete structures on the coast, the prevention and management against salt damage is needed because they are being under the influence of the sea water at all times. In general, the deterioration of the concrete is generated in concrete surface firstly and then extended into concrete gradually as its service life increases. Therefore, the protective layer on the concrete surface is needed to establish and manage the durability of concrete. To enhance the durability performance of the existing and new concrete, the development and application of a high-performance penetration sealer is needed. The sealer has to have the functions that are able to prevent the attack of the moisture, carbon dioxide, and harmful substance from the outside. Therefore, the aim of this project is to guarantee the long service-life and waterproof performance of a nuclear concrete structures by increasing the density of the existing and new concrete surface layer, and to enhance the dust-proof performance of the uncoating part of the nuclear safety-relative structures.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.337-337
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• 2011

The elecronic absorption and surface morphology evolution of two types of molecular double layer thin films, copper phthalocyanine(CuPc) layer deposited on top of chloro[subphtalocyaninato]boron(III) (SubPc) layer, denoted as SubPc/CuPc, and vice versa, at various thicknesses were invertigated using ultraviolet(UV)-visible spectroscopy and atomic force microscopy (AFM). Both types of double layer structures showed similar broadened absorption patterns in UV-visible region which were well consistent with fitted spectra by a simple linear combination of single layer absorption spectra of two materials. In contrast, the surface morphology of double layer structures was dependent on the order of deposition. For CuPc/SubPc structures, the surface morphology was characterized by elongated grains, characteristic of SubPc thin films, indicating the morphological influence of underlying CuPc layer on subsequent SubPc layer was not large. For SubPc/CuPc structures, however, the underlying SubPc layer acted as a morphological template for the subsequently deposited CuPc layer. It was also observed that the grain size of CuPc layer varied by the thickness of underlying SubPc layer.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.581-586
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• 2014

The most stable adsorption structures and their corresponding energies of 4-pyridone, 4-hydroxypyridine, 2-pyridone and 2-hydroxypyridine have been investigated by Density Functional Theory (DFT) calculation and high-resolution photoemission spectroscopy (HRPES). We confirmed that between the two reaction centers of 4- and 2-pyridone, only O atom of carbonyl functional group can act as a Lewis base while both the two reaction centers of 4- and 2-hydroxypyridine (tautomers of 4- and 2-pyridone) can successfully function as a Lewis base. On the other hand, owing to their molecular structures, there is a remarkable difference between the adsorption structures of 4- and 2-hydroxypyridine. Through the analysis of the N 1s and O 1s core level spectra obtained using HRPES, we also could corroborate that two different adducts coexist on the surface at room temperature due to their activation energy investigating the coverage dependent variation of bonding configurations when these molecules are adsorbed on the Ge(100) surface.

• Korean Journal of Optics and Photonics
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• v.20 no.6
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• pp.339-345
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• 2009

The high power and single mode vertical cavity surface emitting laser(VCSEL)s with photonic crystal structures have been proposed and fabricated by reducing substantially the hole numbers used in the photonic crystal structures. It is found that only six holes enable VCSELs to operate a single mode and the reliability can be enhanced by filling the holes with polyimide. The single mode lasing characteristics were analyzed by varying the oxide aperture and the hole diameter in photonic crystal structures. As a result, the single mode lasing can be stably obtained in the photonic crystal vertical cavity surface emitting lasers.