• Title/Summary/Keyword: surface states

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Surface States and Field Emission Properties of Oxygen Plasma Treated Carbon Nanotubes (산소 플라즈마 처리한 탄소나노튜브의 표면상태와 전계방출 특성)

  • Lee, Sunwoo;Lee, Boong-Joo;Park, Gu-Bum;Shin, Paik-Kyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.3
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    • pp.376-379
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    • 2013
  • Multi-walled carbon nanotubes (MWCNTs) were synthesized using catalytic chemical vapor deposition (CVD) method. Oxygen plasma treatment was applied to modify surface state of the CNTs synthesized for improvement of field emission performance. Surface state of the plasma treated CNTs was studied by X-ray photoelectron spectroscopy (XPS). The surface states of the CNTs were changed as a function of plasma treatment time. The oxygen related carbon shift was moved toward higher binding energy with the plasma treatment time. This result implies that the oxygen plasma treatment changes the surface state effectively. While any shift in carbon 1s peak was not detected for the as grown CNTs, oxygen related carbon shift was detected for the plasma treated CNTs. Carbon shift implies that closed CNT tips were opened by the oxygen plasma and reacted with oxygen species. Since the field emission occurs at pentagons or dangling bonds of the CNT tips, the increase of carbon-oxygen bonds plays an important role in field emission behavior by increasing the number of electron emission sites resulting in improvement of the field emission performance.

Evaluation of the Horizontal and Vertical Dispersion Coefficients for the Urban Area (都市地域의 垂直, 水平 擴散係數 算定)

  • 羅振均;金良均;權寧洙
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.1
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    • pp.23-31
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    • 1986
  • Meteorological Measurement was performed for evaluation of the horizontal vertical standard deviation $(\sigma_y, \sigma_z)$, surface roughness length and stmospheric stability during the period of March to October 1985 The major results are as follows; 1) The average value of surface roughness length was 144cm at NEPI. 2) In frequency distribution of atmospheric stability, neutral state (D class) was dominent in Seoul (29%) and Pusan (30%). Unstable states (A. B. C. class) were 26% in Seoul and 24% in Pusan. Also, stable states (D. E. F class) were 74% in Seoul and 76% in Pusan. 3) Standard deviations of horizontal ad vertical direction were evaluated as a function of downwind distance and atmospheric stability at NEPI, Jamsil and Pujeondong (Pusan). Standard deviation of horizontal direction was largest at NEPI among 3 areas because of mechanical turbulence resulting from difference of surface roughness length.

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Methodological Consideration on the Prediction of Electrochemical Mechanical Polishing Process Parameters by Monitoring of Electrochemical Characteristics of Copper Surface

  • Seo, Yong-Jin
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.346-351
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    • 2020
  • The removal characteristics of copper (Cu) from electrochemical surface by voltage-activated reaction were reviewed to assess the applicability of electrochemical-mechanical polishing (ECMP) process in three types of electrolytes, such as HNO3, KNO3 and NaNO3. Electrochemical surface conditions such as active, passive, transient and trans-passive states were monitored from its current-voltage (I-V) characteristic curves obtained by linear sweep voltammetry (LSV) method. In addition, the oxidation and reduction process of the Cu surface by repetitive input of positive and negative voltages were evaluated from the I-V curve obtained using the cyclic voltammetry (CV) method. Finally, the X-ray diffraction (XRD) patterns and energy dispersive spectroscopy (EDS) analyses were used to observe the structural surface states of a Cu electrode. The electrochemical analyses proposed in this study will help to accurately control the material removal rate (MRR) from the actual ECMP process because they are a good methodology for predicting optimal electrochemical process parameters such as current density, operating voltage, and operating time before performing the ECMP process.

Research Trend of Topological Insulator Materials and Devices (위상절연체 소재 및 소자 기술 개발 동향)

  • W.J. Lee;T.H. Hwang;D.H. Cho;Y.D. Chung
    • Electronics and Telecommunications Trends
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    • v.38 no.1
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    • pp.17-25
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    • 2023
  • Topological insulators (TIs) emerge as one of the most fascinating and amazing material in physics and electronics. TIs intrinsically possess both gapless conducting surface and insulating internal properties, instead of being only one property such as conducting, semiconducting, and insulating. The conducting surface state of TIs is the consequence of band inversion induced by strong spin-orbit coupling. Combined with broken inversion symmetry, the surface electronic band structure consists of spin helical Dirac cone, which allows spin of carriers governed by the direction of its momentum, and prohibits backscattering of the carriers. It is called by topological surface states (TSS). In this paper, we investigated the TIs materials and their unique properties and denoted the fabrication method of TIs such as deposition and exfoliation techniques. Since it is hard to observe the TSS, we introduced several specialized analysis tools such as angle-resolved photoemission spectroscopy, spin-momentum locking, and weak antilocalization. Finally, we reviewed the various fields to utilize the unique properties of TIs and summarized research trends of their applications.

Fiber Orientation in Injection-Molded Short Fiber Composites with a Confocal Laser Scanning Microscope and Numerical Simulation (공초점 레이저 주사 현미경을 이용한 단섬유 복합재료 사출 성형물 내의 섬유 배열 측정 및 수치모사)

  • Lee, Kwang-Seok;Le, Seok-Won;Youn, Jae-Ryoun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.201-204
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    • 2001
  • A Confocal Laser Scanning Microscope (CLSM) is applied to determine three-dimensional fiber orientation states in injection-molded short fiber composites. Since the CLSM optically sections the composites, more than two planes either on or below the surface of composites can be obtained. Therefore, three dimensional fiber orientation states are determined without destruction. To predict the orientation states, velocity and temperature fields are calculated by using a hybrid FEM/FDM method. The change of orientation state during packing stage is also considered by employing a compressible Hele-Shaw model. The predicted orientation states show good agreement with measured ones. However, some differences are found at the end of cavity. They may result from other effects, which are not considered in the numerical analysis.

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Surface Electronic Structures and Magnetism of a Full-Heusler Alloy Co2CrGa(001): A First-principles Study

  • Jin, Ying-Jiu;Lee, Jae-Il
    • Journal of Magnetics
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    • v.12 no.3
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    • pp.97-102
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    • 2007
  • We have investigated the electronic structures and magnetism of a full Heusler alloy $Co_2CrGa(001)$ surface by using the all-electron full-potential linearized augmented plane wave (FLAPW) method within the generalized gradient approximation (GGA). We considered two types of different terminations: the Co-terminated (Co-Term) and the CrGa-terminated (CrGa-Term) surfaces. From the calculated layer-projected density of states (LDOS), we found that the surface of the CrGa-Term shows nearly half-metallic character while that of the Co-Term is far from the half-metallic. For the Co-Term, the surface Co atom moves down to the bulk region by $0.05{\AA}A$, while the subsurface Cr and Ga atoms move up to the surface layer by 0.05 and $0.01{\AA}$, respectively. For the CrGa-Term, there is a large inward relaxation of the surface Ga atom $(0.07{\AA})$, but the relaxation of the surface Cr atom is very small $(0.01{\AA})$. The relaxations affect not much to the overall shapes of DOS for both terminations, but make the surface states of the surface Cr and Ga atoms for the CrGa-Term shift to higher energy that enhances the nearly half-metallic character of the CrGa-Term. The magnetic moments of the surface $Cr(2.98{\mu}_B)$ in the CrGa-Term and the surface $Co(1.17{\mu}_B)$ in the Co-Term were much increased compared to those of the inner-layers $(1.79\;and\;0.77{\mu}_B)$, respectively, while that of the subsurface Cr atom in the Co-Term was decreased to $1.19{\mu}_B$.

Density Functional Theory Calculations on Ag Adatom in the Bi2Se3 (111) Surface

  • Sin, Eun-Ha
    • Proceeding of EDISON Challenge
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    • 2013.04a
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    • pp.243-245
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    • 2013
  • Topological insulator (TI) has non-trivial metallic surface states and has provoked many studies of property of this metarial. One of TI, $Bi_2Se_3$ is the promising metarial due to application of quantum devices. We investigate the effect of Ag adatom in the $Bi_2Se_3$ (111) surface. The silver atom prefers to locate within the vdW gap between the QLs rather than on the top surface. The effect of Ag adsorption is the rise of the Fermi level implying that the adsorbed Ag atoms behave like electron donors.

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