• Title/Summary/Keyword: surface state

Search Result 3,696, Processing Time 0.026 seconds

Study on the Fuel Decomposition Characteristics and Coke Formation by Type of Endothermic Fuel and Method of Catalyst Molding (흡열연료 종류와 촉매 성형 방법에 따른 분해특성과 코크 생성에 관한 연구)

  • Lee, Tae Ho;Kang, Saetbyeol;Kim, Sung Hyun
    • Korean Chemical Engineering Research
    • /
    • v.57 no.5
    • /
    • pp.611-619
    • /
    • 2019
  • This study was carried out to investigate fuel decomposition characteristics and coke formation according to types of endothermic fuels and methods of catalyst molding. Methylcyclohexane (MCH), n-dodecane, and exo-tetrahydrodipentadiene (exo-THDCP) were used as the endothermic fuels. As a catalyst, USY720 supported with platinum was used. It was manufactured by only using pressure to disk-type, or pelletized with a binder and a silica solution. The characteristics of the catalysts according to the molding method were analyzed by X-ray diffraction analysis, scanning electron microscopy, nitrogen adsorption-desorption isotherm, and ammonia temperature programmed desorption analysis. The reaction was carried out under conditions of high temperature and high pressure ($500^{\circ}C$, 50 bar) in which the fuel could exist in a supercritical state. The product was analyzed by gas chromatograph/mass spectrometer and the coke produced by the catalyst was analyzed by thermogravimetric analyzer. After the reaction, the composition of the products varied greatly depending on the structure of the fuel. In addition, the crystallinity and surface properties of the catalysts were not changed by the method of catalyst molding, but the changes of the acid sites and the pore characteristics were observed, which resulted in changes in the amount and composition of products and coke.

A Material Characteristic Study on the Sword with an Undecorated Ring Pommel of the Ancient Tombs of Jeongchon, Bogam-Ri, Naju (나주 복암리 정촌고분 출토 소환두도의 재료학적 특성)

  • Lee, Hyeyoun
    • Korean Journal of Heritage: History & Science
    • /
    • v.52 no.3
    • /
    • pp.160-171
    • /
    • 2019
  • The sword with a ring pommel, which was excavated from the first stone chamber of the ancient tombs of Jeongchon Village in Naju, is a sword with a pentagon undecorated ring pommel consisting of a mother sword and two child swords. The sword with an undecorated ring pommel of Jeongchon comprises a ring pommel, a hilt, a knife, and a knife end decoration. This sword was coated with lacquer. The ring pommel is an iron frame covered with silver plate; however the silver tarnished into a light purple due to silver chloride corrosion, and iron corrosion originated from the inside is visible on the surface. Silver chloride corrosion is produced when silver objects are exposed to water, dissolved salts, and dissolved chloride ions when in a buried state. It changes objects into powder, making it difficult to preserve original shapes. The other silver artifacts found in the Jeongchon ancient tombs show similar signs of corrosion. The results of X-ray irradiation and a CT analysis showed that the sword had a ring at the end of the handle, a T-shaped hilt, and was probably connected to the handle end of a knife. If the shape of the mother sword can be inferred from the child swords, the mother sword had a ring pommel, decorations of the handle, covered with silver plate, and a gold ring and a silver line wound around the handle. It is assumed that the ring pommel was connected to the knife by welding because no holes were observed. The end decoration of the knife was made by using an iron plate formed into a shape, half covered by silk, and the other half decorated with silver plate and a gold ring. The sword with an undecorated ring pommel excavated from the ancient tombs of Jeongchon Village comprises the metals of gold, silver, and iron, and includes features of Baekje, Silla, and Gaya, which highlights the influence of surrounding historic sites and various cultures.

A Study on the Confined Effects of Highly Moistured Soils Reinforced with Geosynthetics (토목섬유가 보강된 고함수비 흙의 구속효과에 관한 연구)

  • Yoo, Jae-Won;Im, Jong-Chul;Kang, Sang-Kyun;Lee, Hyung-Jun;Choi, Moon-Bong
    • Journal of the Korean Geosynthetics Society
    • /
    • v.18 no.1
    • /
    • pp.25-37
    • /
    • 2019
  • This study confirms reinforcing effect of geosynthetics in the use of soil at higher water contents as a compaction material on compaction tests, field compaction tests, and numerical analysis. To verify a confined effect, a large mold(area ratio of rammer / mold = 0.19) larger than D compaction mold(area ratio of rammer / mold = 0.33) was performed for compaction. It showed that in the D compaction test, dry density were 0.5~0.6% increases and in the compaction test using the large mold, it were 2.4~3.7% increases at high water contents. It shows that when the area of compacted area is large enough, a confined effect could be arising from the reinforcement of geosynthetics even at high water contents. As a result of analyzing of compaction effects according to 'depth(z/B) from compacted surface' in the field, when not reinforced, the compaction state deteriorated due to the over-compaction and the compaction did not work well. However, when reinforcement of geosynthetics, restraint effect by geosynthetics occurs, it is confirmed that the compaction energy is effectively transferred to the compaction layer and the dry density is increased. Also, through the conceptual model of the behavior of geosynthetic and soil layer, the mechanism in the ground due to reinforcement of geosynthetics is presented and it is verified through finite element analysis.

Weight Loss Prediction by Operating Conditions of CA Storage (CA저장고의 작동 환경에 따른 감모율 예측)

  • Park, Chun Wan;Park, Seok Ho;Kim, Jin Se;Choi, Dong Soo;Kim, Yong Hun;Lee, Su Jang
    • Food Engineering Progress
    • /
    • v.21 no.4
    • /
    • pp.312-317
    • /
    • 2017
  • Weight loss that influences quality and farmer incomes is affected by the storage environment of agricultural products. The interior of storage should be maintained at high humidity to prevent the weight loss of products which contain a lot of moisture. The research had constantly proceeded with change in the heat exchanger surface areas, humidity systems, and weight loss forecast to maintain high humidity within storage. Relative humidity that exerts an effect weight loss of crop is influenced by storage temperature, leak state, and volume of product. When weight loss is predicted, different conditions of these factors are derived. In case of CA storage, ways of forecasting the weight loss become easier compared to cold storage due to sealed storage with external environment during storage period. In this study, apples were stored in purge-type CA storage and weight loss has been predicted by using operating characteristics and environmental conditions. As a result, humidity variation in the storage fluctuates with the operation of the unit-cooler. Furthermore, unit-cooler operation factor is influenced by outside temperature and respiration heat. Prediction value of weight loss according to temperature and humidity has been most accurately predicted. Prediction value through defrosting water measured shows unit-cooler work quality. K-value needs verification to calculate the VPD method.

Planting Patterns and Landscape Redevelopement of Pilam Seowon in Jangseong-Gun (장성 필암서원(筆巖書院)의 식재현황과 정비방안)

  • Lee, Won-Ho
    • Journal of the Korean Institute of Traditional Landscape Architecture
    • /
    • v.29 no.1
    • /
    • pp.131-141
    • /
    • 2011
  • This study, as a purpose of base study for landscape redevelopement of Seowon, pointed out problems of planting patterns in each sector and suggested an alternative through analyzing old literature, complete enumeration survey in each sector and taking aerial images. the conclusions drawn from this study are as follows. A Pilam Seowon(historic site no 242) is located in a Pyungya-Sanrok(plain and mountain) district in Jangsung-gun and has Junhak-Humyo(Study room in the front and Shirne in the back) type. 23 taxonomic group of arbor, 6 taxonomic group of shrub and 5 taxonomic group of flowers are planted high-densitily in limited flat surface. It can be classified into being planted by family and being planted through landscape redevelopement in 1980s. Korean traditional trees are planted in this area like Pinus densiflora, Juniperus chinensis L., Thuja orientalis L., Zelkova serrato Makino, Sophora japonica L., Lagerstroemia indica, Prunus mume include Ginkgo biloba which is old big tree and is registered in Jangsung-gun as protected trees. The tea tree in this area was introduced from wild tea plantation in Yonhwa moutain and was planted. From now on, we have to pay consideration a form management of planted trees in the historical area, rearrangement of plant density due to over planting, removal of alien trees like Pinus bungeana and Canna generalisa, prevention a dwarfishness of main area due to over planting in outside facilities, recovery a alienation among each planting area, and planting concept from plants drawings on wall of buildings can be suggested. The implications of this case study is that introduction of over planting can make more problems like losing sense of place. Therefore, we must do a actual state survey on traditional landscape area like Seowon from preservation point of view.

Synthesis and Electrochemical Properties of Zn and Al added LiNi0.85Co0.15O2 Cathode Materials (Zn와 Al을 첨가한 LiNi0.85Co0.15O2 양극활물질의 제조 및 전기화학적 특성평가)

  • Kim, Su-Jin;Seo, Jin-Seong;Na, Byung-Ki
    • Korean Chemical Engineering Research
    • /
    • v.59 no.1
    • /
    • pp.42-48
    • /
    • 2021
  • Zn and Al added LiNi0.85Co0.15O2 cathode materials were synthesized to improve electrochemical properties and thermal stability using a solid-state route. Crystal structure, particle size and surface shape of the synthesized cathode materials was measured using XRD (X-ray diffraction) and SEM (scanning electron microscopy). CV (cyclic voltammetry), first charge-discharge profiles, rate capability, and cycle life were measured using battery cycler (Maccor, series 4000). Strong binding energy of Al-O bond enhanced structure stability of cathode material. Electrochemical properties were improved by preventing cation mixing between Li+ and Ni2+. Large ion radius of Zn+ increased lattice parameter of NC cathode material, which meant unit-cell volume was expanded. NCZA25 showed 80% of capacity retention at 0.5 C-rate during 100 cycles, which was 12% higher than that of NC cathode. The discharge capacity of NCZA25 showed 104 mAh/g at 5 C-rate. NCZA25 achieved 36 mAh/g more capacity than that of NC cathod. NCZA25 cathode material showed excellent rate capability and cycling performance.

The Effect of Applying Various Tools to the Stiffness and Muscle Tone of Hamstring Muscles (다양한 도구의 적용이 뒤넙다리근의 뻣뻣함과 근 긴장도에 미치는 영향)

  • Hwang, Sunghyun;Kim, Taeho
    • Journal of The Korean Society of Integrative Medicine
    • /
    • v.8 no.4
    • /
    • pp.223-230
    • /
    • 2020
  • Purpose : The purpose of this study was to examine the effects of tools (i., extracorporeal shock wave therapy, massage gun, and foam roller) on range of motion, muscle tone and pain threshold among patients with hamstring stiffness. Methods : Fourteen participants with hamstrings stiffness were recruited. Interventions were performed 6 times, and each session was for 30 seconds using the three tools. The range of motion, muscle tone, and pain threshold were measured. The order of the use of the three tools was randomly determined. The foam roller was made to move from the bottom of the hip crease to the upper part of the back of the hamstring. Additionally, velocity 5 vibration stimulation was performed on the hamstring using a massage gun. Moreover, vibration stimulation was performed on the hamstring with extracorporeal shock wave therapy 5 minutes, 5 Hz, and 1,500 strokes. The flexibility of the posterior thigh muscle was based on maintaining the knee and hip joints in a 90 ° bend in the supine position. The joint angle of the knee was measured, when the knee was actively extended, at the maximum point where the posterior thigh muscle was stretched. The elasticity of the posterior thigh muscle was measured while the subject was prone and in a relaxed state without any force. Measurements were made at the muscle abdominal area of the semitendinosus muscle of the posterior femur, and the area to be measured was marked with a pen. The measurement of the tenderness threshold of the posterior femur was measured using a tenderness meter(Commander Algometer, J-Tech, USA). The force value at the point at which the pressure sensation change to pain was measured after applying vertical pressure to the posterior femur muscle, which was the halfway point between the ischial tuberosity and the popliteal surface of the subject lying on their stomach. Results : The extracorporeal shock wave therapy increased stiffness and, muscle tone, and caused changes in the pain threshold, whereas the other two tools had no effect on these indices. Conclusion : Extracorporeal shock wave therapy has important effects on range of motion and muscle stiffness and can be used in warmup protocols.

Analysis of the microstructure of melting-pool in aluminum specimens fabricated by SLM technique (SLM 기법으로 제작한 알루미늄 시편 내부 멜팅풀 미세조직 분석)

  • Kim, Moo-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.21 no.12
    • /
    • pp.115-119
    • /
    • 2020
  • Selective Laser Melting (SLM) technology is state-of-the-art additive manufacturing process technology that produces a three-dimensional structure by irradiating a laser on a fine metal powder to perform the fusion of a specific area and repeat this process. Owing to the characteristics of the additive manufacturing process, the melting phenomenon of the metal material by the laser has directionality depending on the process conditions, such as the irradiation direction of the laser and the build-up direction. For this reason, the composition of the metal material in the structure exhibits non-uniform characteristics. In this study, aluminum (AlSi10Mg) specimens were manufactured by applying SLM technology, and the material composition characteristics of the specimen were analyzed. The specimens were manufactured as cylinders by the build-up orientation of 0°, 45°, and 90°. The surface morphology of the specimen plane was analyzed optically. TEM analysis was performed on the core and the interface of the melting-pool inside the specimen generated by laser irradiation. The analysis results confirmed that there was a difference between the nano cell structure of the core and the interface of the melting-pool, and that the composition ratio of Si appeared higher at the interface than at the core of the cell.

Georeferencing of GPR image data using HD map construction method (정밀 도로 지도 구축 방법을 이용한 GPR 영상 데이터 지오레퍼런싱)

  • Shin, Jinsoo;Won, Jonghyun;Lee, Seeyoung
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
    • /
    • v.39 no.6
    • /
    • pp.507-513
    • /
    • 2021
  • GPR (Ground Penetrating RADAR) is a sensor that inspects the pavement state of roads, sinkholes, and underground pipes. It is widely used in road management. MMS (Mobile Mapping System) creates a detailed and accurate road map of the road surface and its surroundings. If both types of data are built in the same area, it is efficient to construct both ground and underground spatial information at the same time. In addition, since it is possible to grasp the road and important facilities around the road, the location of underground pipelines, etc. without special technology, an intuitive understanding of the site is also possible, which is a useful tool in managing the road or facilities. However, overseas equipment to which this latest technology is applied is expensive and does not fit the domestic situation. LiDAR (Light Detection And Raging) and GNSS/INS (Global Navigation Satellite System / Inertial Navigation System) were synchronized in order to replace overseas developed equipment and to secure original technology to develop domestic equipment in the future, and GPR data was also synchronized to the same GNSS/INS. We developed software that performs georeferencing using the location and attitude information from GNSS/INS at the time of acquiring synchronized GPR data. The experiments were conducted on the road site by dividing the open sky and the non-open sky. The road and surrounding facilities on the ground could be easily checked through the 3D point cloud data acquired through LiDAR. Georeferenced GPR data could also be viewed with a 3D viewer along with point cloud data, and the location of underground facilities could be easily and quickly confirmed through GPR data.

Exothermic Oil Absorbent Sheet for Low-sulfur Fuel Oil (LSFO) Spilled into Seawater in the Winter Season (동절기 해상으로 유출된 저유황 중질유 제거를 위한 발열 흡착포)

  • Park, Han-gyu;Oh, Gyung-geun;Bae, Byung-Uk;Song, Young-Chae
    • Journal of Navigation and Port Research
    • /
    • v.46 no.4
    • /
    • pp.297-302
    • /
    • 2022
  • An exothermic oil absorbent sheet with calcium chloride crystals can be fabricated, by dipping a clean polypropylene fabric in calcium carbonate and hydrochloric acid solution and drying it. The exothermic oil absorbent sheet applied to the seawater surface, releases heat by the dissociation of calcium chloride. The dissociation heat liquefies the solidified low-sulfur fuel oil at a low temperature, and converts it to a state at which it can be absorbed. The optimum mole concentrations of calcium carbonate and hydrochloric acid required for the exothermic oil absorbent sheet, are 0.25 M and 0.5 M, respectively. The oil absorption capacity of the exothermic oil absorbent sheet for low sulfur fuel oil depends on the seawater temperature. But, it is highly excellent at 4.5-7.08 g/g at 10℃, the average seawater temperature during the winter in Korea. The exothermic oil absorbent sheet is an excellent alternative in absorbing low-sulfur fuel oil in winter and removing it from seawater.