• 한국광물학회:학술대회논문집
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• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
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• pp.40-40
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• 2001

The sorption behavior of Cs(I), Sr(II), and U(VI) on representative single minerals(oxide and clay) and rocks were comparatively studied by using batch type sorption experiment. The effects of pH, ionic strength and the sorption mechanism were also discussed. It was found that mineral structure played as a main factor governing the sorption characteristics of Cs(I), Sr(II). The sorption of Cs(I) and Sr(II) on minerals showed ionic strength-dependency, which is a indirect sign of weak binding between metal cation and mineral surfaces. However, the sorption behavior of U(VI) was quite different compared with that of Cs(I), and Sr(II). Fe-oxide minerals showed strong tendency for U(VI) sorption, dominating the sorption in the composite/mixture systems. The surface characteristics which arise from mineral structure, and the affinity of metal ions to the sorption sites of minerals are the key to understand the role of minerals in the radionuclide sorption.

• 자원환경지질
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• 제45권2호
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• pp.205-215
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• 2012

금속이온은 토양이나 퇴적물 내의 광물에 수착되어 고착화될 수 있다. 여기서는 광물 표면의 화학적 특성과 금속이온의 수착에 관련된 이론 및 수착 연구를 위한 X-선 흡수 미세구조(extended X-ray absorption fine structure, EXAFS) 분석방법에 대해 알아보고 금속이온의 광물표면 수착에 관한 원자 단위 연구 결과를 정리하였다. 광물표면의 특성과 금속이온의 수착에 관한 원자 단위 이론의 이해는 원자 단위 분광법의 분석을 수행하는데 있어서 기초가 된다. 여기에 정리된 원자 단위 수착상 연구 결과는 외부권 착물, 내부권 착물, 표면침전뿐 아니라 공침전, 삼성분 착물, 수착반응 시간의 효과, 탈착가능성을 포함한다.

• Nuclear Engineering and Technology
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• 제27권1호
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• pp.25-32
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• 1995

저준위 방사성 폐기물의 대표핵종인 Cs의 국내 대표 암반구성 물질인 화강암과 응회암에의 흡착특성을 조사하기 위해 회분식 흡착실험을 수행하였다. 반응표면분석법을 이용하여 ［Cs］, ［Vol/Wt］, ［pH］의 독립변수가 흡착에 미치는 영향을 정량적으로 평가하였다. 결과, 초기 세슘이온의 농도가 가장 중요한 변수로 나타났다. Cs의 흡착능의 pH 의존성은 미약한 것으로 나타났다. 핵종의 응회암에의 흡착량이 화강암보다 더 많았다. 이들 핵종흡착의 낮은 pH 비의존성을 매질의 전기적 표면특성과 핵종의 수용액상 특성으로 설명하였다. 핵종간과 매질간의 흡착능 비교는 물구조 변환론으로 설명하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.219-222
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• 2004

Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

• 한국광물학회:학술대회논문집
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• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
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• pp.52-52
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• 2001

Clays coated with cationic surfactants (organoclays) have been investigated due to their effectiveness in sorbing organic compounds from water The objectives of this study were to (1) study the sorption characteristics or a cationic surfactant (HDTMA) to clay minerals; (2) examine the partitioning of HOC (naphthalene) to the adsorbed surfactants within the context of the first objective, and (3) develop overall HOC distribution coefficients that consider sorbed surfactant amounts. The sorption of hydrophobic organic contaminant was due to partitioning of the organics into the organic pseudophase created by the surfactant tail groups. Sorption of naphthalene by HDTMA-clays at different surfactant surface coverages revealed that the naphthalene K$\_$d/ values were affected by the surface concentration of surfactant. In our study the kaolinite was modified with a cationic surfactant to achieve different fractional organic carbon contents and different surfactant molecule configurations on the surface. All of the sorption isotherms were nearly linear and could be described by a distribution coefficient (K$\_$d/). The sorption of naphthalene by the surfactant-modified kaolinite was found to be dependent on the bound surfactant molecule configuration as well as on the fractional organic carbon content but halloysite was not affected by the increase of surfactant amounts. Results from this investigation provide additional insight into the role that sorbed surfactant structure plays in HOC partitioning.

• Nuclear Engineering and Technology
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• 제31권2호
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• pp.182-191
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• 1999

The sorption of UO$_{2}$$^{2+}$ onto goethite and kaolinite under various experimental conditions was successfully interpreted using surface complexation modeling (SCM). The SCM approach used in this work is the triple-layer model (TLM) in which weakly bonded ions are modeled as outer-sphere (ion-pair) complexes and strongly bonded ions as inner-sphere (surface coordination) complexes. The change of ionic strength did not affect the U(VI) sorption onto goethite, thus the formation of inner-sphere surface complexes, (FeO)$_2$UO$_2$ and (FeO)$_2$(UO$_2$)$_3$OH$_{5}$ was assumed to simulate the effects of ionic strength and goethite concentration. On the other hand, the U(VI) sorption onto kaolinite showed ionic strength dependence, thus the formation of AlO-UO$_{2}$$^{2+}$(outer-sphere complex) and SiO(UO$_2$)$_3$OH$_{5}$ (inner-sphere complex) was assumed to simulate the experimental data. In the presence of carbonates, the sorption of U(VI) onto kaolinite decreased in the weakly alkaline pH range. This was well simulated assuming the formation of a outer-sphere surface complex, A1OH$^{2+}$- (UO$_2$)$_2$CO$_3$OH$_3$. Since SCM approach uses thermodynamic data such as surface complexation constants, it is more predictive than empirical modeling approach in which conditional values such as partition coefficient are used. used.

• 한국연초학회지
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• 제3권1호
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• pp.30-40
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• 1981

The moisture sorption and desorption isotherms of various tobaccos were obtained over a relative humidity range from 0 to 90% at $20^{\circ}C$ and $30^{\circ}C$. The hysteresis effect, constant and rate of moisture sorption and desorption, monomolecular-layer moisture content, and specific surface area were analyzed from the obtained data. The moisture sorption and desorption isotherms showed a different characteristics for different tobacco varieties. At a lower humidity range below 50% RH, Burley tobacco had higher moisture sorption and desorption figures than Hicks and Basma, while, at a higher humidity range above 50% RH, Hicks had higher values than the others. The hysteresis effect of tobacco were greater in an intermediate humidity range (40-70% RN), and Basma showed a greater effect than the others. The sorption and desorption constant (K) increased with temperature, but decreased with RH, and Burley tobacco had larger K values, while Hicks had smaller K values than others. The sorption and desorption rate of Burley tobacco were greater than the other tobaccos. The monomolecular-layer moisture was 27.8 and 51.4mg/g, and the specific surface was 101 and $186m^2/g$, for Basma and Burley, respectively.

• 방사성폐기물학회지
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• 제20권2호
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• pp.151-160
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• 2022

The sorption of Eu on MX-80 bentonite in Na-Ca-Cl solutions is investigated at a molal proton concentration (pH_m) range of 3 to 10 and an ionic strength (I) range of 0.1 to 6 m (mol·kgw^-1). The sorption equilibrium of Eu on MX-80 is achieved within 14 to 21 d at I = 0.1 and 6 m. The sorption distribution coefficient (K_d) values of Eu for MX-80 increase as pH_m increases from 3 to 6 for all I values, and they are independent of pH_m between 8 and 10 at I ≥ 0.5 m. Meanwhile, at I = 0.1 m, the K_d value at pH_m = 10 is slightly lower than those at pH_m = 8 and 9. The K_d values are not affected by the I values between 0.5 m and 6 m, whereas the K_d value at I = 0.1 m is greater than those at I ≥ 0.5 m, except at pH_m = 10. A two-site protolysis nonelectrostatic surface complexation and cation exchange sorption model is applied to the Eu sorption data for I ≤ 4 m, and the equilibrium constants of the sorption reactions are estimated.

• Journal of Microbiology and Biotechnology
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• 제12권6호
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• pp.878-881
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• 2002

The goal of the current research was to assess the influence of the growth rate of Nocardia amarae on its overall metal binding capacity. Batch sorption isotherms for cadmium (Cd), copper (Cu), and nickel (Ni) showed that Nocardia cells harvested from chemostat cultures at a dilution rate of $0.33d^-1$ had a significantly higher metal sorption capacity than cells grown at 0.5 and $1d^-1$. The cell surface area estimated using a dye technique indicated that pure N. amarae cells grown at a lower growth rate had a significantly more specific surface area than cells harvested from a higher growth rate operation. Accordingly, this difference in the specific surface area seemed to indicate that the higher metal sorption capacity of the slowly growing Nocardia cells was due to their higher specific surface area.

• Nuclear Engineering and Technology
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• 제44권8호
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• pp.945-952
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• 2012

The sorption of selenium ions onto iron and iron compounds as a disposal container material and its corrosion products, and onto bentonite as a buffer material, was studied to understand the behaviors of selenium in a waste repository. Selenite was sorbed onto commercial magnetite very well in solutions at around pH 9, but silicate hindered their sorption onto both magnetite and ferrite. Unlike commercial magnetite and ferrite, flesh synthesized magnetite, green rust and iron greatly decreased selenium concentration even in a silicate solution. These results might be due to the formation of precipitates, or the sorption of selenide or selenite onto an iron surface at below Eh= -0.2 V. Red-colored Se(cr) was observed on the surface of a reaction bottle containing iron powder added into a selenite solution. Silicate influences on the sorption onto magnetite and iron for selenide are the same as those for selenite. Even though bentonite adsorbed a slight amount of selenite, the sorption cannot be ignored in the waste repository since a very large quantity of bentonite is used.