• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.20 no.1
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• pp.16-28
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• 2015

In order to elucidate the spatiotemporal variations of marine environmental parameters, we collected seawater samples in the south-western region of the East Sea in May, August, and November 2012 and February 2013. The concentrations of dissolved inorganic nutrients (dissolved inorganic nitrogen, phosphorus, and silicate) in surface seawater during the summer season were lower than those during autumn and winter seasons, which the mixed layer is deeper. The low nutrient concentration in spring and summer seasons seems by consumption of dissolved inorganic nutrients by phytoplankon photosynthesis (high chlorophyll a concentration) and the limited supply of dissolved inorganic nutrients from subsurface layer having high nutrients. The low nutrient concentration during spring season seems to be related to the limited supply of dissolved inorganic nutrients from land and subsurface layer because the concentration of chlorophyll a was low. The DIN:DIP ratio was a wide range of average $15.6{\pm}13.6$ in the surface seawater compared to that of average $14.8{\pm}4.2$ in the bottom seawater during sampling periods. The dissolved inorganic nitrogen might act as a limiting factor of the growth of phytoplankton because the DIN:DIP ratio (on average $8.35{\pm}4.67$) was low during the spring season.

• 한국해양학회지
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• v.29 no.2
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• pp.171-182
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• 1994

Dissolved free amino acid (DFAA) dissolved hydrolyzable amino acid (DHAA) and D/L amino acid racemic ratio in the dissolved organic compounds were studied to investigate the biogeochemical characteristics of dissolved organic compound in the Yellow Sea. Concentration of total DFAA ranged from 0.06 uM to 0.26 uM in the study area. DFAA composition showed that aspiratae, glutamate, serine, glycine and alanine were predominant. According to characteristics of functional group of amino acid, these belonged to hydroponic group. C-18 short column cartridge (Sep-Pak) activated by methanol was used to extract organic macromolecules in the seawater. In operational scheme, macromolecules were divided into two fractions. Geomacromolecule fraction eluted with 50% methanol was used to extract organic macromolecules in the seawater. In operational scheme, macromolecules were divided into two fractions. Geomacromolecule fraction eluted with 50% methanol was moderately hydrophilic and showed characteristics of humic substance in the seawater. Biomacromolecule fraction eluted with 100% methanol was hydrophobic and most abundant in the surface seawater samples. DHAA was much higher than DFAA in this study area. DHAA ranged from 2.05 uM to 6.19 uM in the B-fraction and from 8.13 uM to 24.46 uM in the G-fraction. DHAA was higher in the surface water than in the bottom water where the vertical stratification developed well. The result of HPLC analysis of D/L amino acid showed that low racemic ratio was found in the B-fraction. It implies that the B-fraction is relatively younger than the G-fraction and freshly derived from biosphere.

• Polymer(Korea)
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• v.36 no.6
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• pp.721-726
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• 2012

Thermoplastic polyurethane (TPU) elastomer is used as an encapsulant in undersea sonar devices. A new material for sonar encapsulant exhibiting better mechanical strength than TPU along with a lower swelling ratio for seawater and oil is required to prolong its application. TPU grafted silica nanoparticles (TPU-g-silica) were prepared and then they were melt mixed with TPU to fabricate desirable composites for underwater applications. The composite containing silica nanoparticles exhibited better tensile strength and lower swelling ratios in the seawater and oil than TPU regardless of the surface treatment of the silica particles. At fixed silica content in the composite, the TPU/TPU-g-silica composite exhibited better tensile strength and lower swelling ratio than the TPU composite with the pristine silica particles. Furthermore, the TPU/TPU-g-silica composite exhibited enhanced tensile strength as compared to TPU after being impregnated with oil.

• 한국해양학회지
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• v.21 no.4
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• pp.193-202
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• 1986

Spatio-temporal variabilities of seawater temperature at 0 and 30m in the southeastern Hwanghae were studied by variance and empirical orthogonal function(EOF) analysis of long records of temperature between 1967 and 1982. The spatial distribution of monthly mean sea surface temperature has a pattern similar to the long-term annual mean which decreases from south to north. On the contrary, the total variance computed from the annual mean of sea surface temperature(SST) increases from south to north. The variance of SST is found to be two times greater than that at 30m in the study area except coastal area south of Kyunggi Bay. The important variance of temperature seem s to be closely associated with the seasonal change of temperature because the first and second modes of EOF having a seasonal cycle explain 97.6% and 85.2% of variances at 0 and 30m, respectively. There is a large difference in temperature between the northern and southern parts of the study area during winter, while the difference becomes very small during summer. This might reflect that in summer the heat gain of sea surface from the incoming radiation is much more important than the heat loss or the oceanic heat advection. In summer coastal waters south of the Kyunggi Bay and around Mokpo are observed to be colder than offshore waters due to tidal mixing.

• Journal of the Korean institute of surface engineering
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• v.39 no.1
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• pp.25-34
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• 2006

Al-Mg alloy, an open rack vaporizer(ORV) material was reported to be corroded in seawater environments though the ORV material was coupled to thermally sprayed Al-Zn alloy functioning a sacrificial anode. In addition, the corrosion behavior based on the calculated corrosion potential did not match the observed corrosion behavior. Hence, the goal of this study is to get better understanding on Al or Al-Mg alloy coupled to Al-Zn alloy and to provide the calculated corrosion potential representing the corrosion behavior of the ORV material by immersion test, electrochemical tests, and calculation of corrosion and galvanic potential. The corrosion potentials of Al and Al alloys also depended on alloying element as well as surface defects. The corrosion potentials of Al and Al-Mg alloy were changed with time. In the meantime, the corrosion potentials of Al-Zn alloys were not. The corrosion rates of Al-Zn alloys were exponentially increased with zinc contents. The phenomena were explained with the stability of passive film proved by passive current density depending on pH and confirmed by the model proposed by McCafferty. Dissimilar material crevice corrosion (DMCC) test shows that higher content of zinc caused Al-Mg alloy corroded more rapidly, which was due to the fact that higher corrosion rate of Al-Zn makes [$H^+$] and [$Cl^-$] more concentrated within pit solution to corrode Al-Mg alloy. Considering electrochemical reactions within pit as well as bulk in the calculation gives better prediction on the corrosion behavior of Al and Al-Mg alloy as well as the capability of Al-Zn alloy for corrosion protection.

• Journal of Korea Water Resources Association
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• v.50 no.6
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• pp.387-395
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• 2017

Sea level rise, accompanied by climate change, is expected to exacerbate seawater intrusion in the coastal groundwater system. As the salinity of saturated groundwater increases, salinity can increase even in the unsaturated soil above the groundwater surface, which may cause crop damage in the agricultural land. The other adverse impact of sea level rise is reduced unsaturated soil thicknesses. In this study, a composite model to assess impacts of sea level rise in coastal agricultural land is proposed. The composite model is based on the combined applications of a three dimensional model for simulating saltwater intrusion into the groundwater and a vertical one dimensional model for simulating unsaturated zone flow and transport. The water level and salinity distribution of groundwater are calculated using the three dimensional seawater intrusion model. At some uppermost nodes, where salinity are higher than the reference value, of the 3D mesh one dimensional unsaturated zone modeling is conducted along the soil layer between the ground water surface and the ground surface. A particular location is judged salinized when the concentration at the root-zone depth exceeds the tolerable salinity for ordinary crops. The developed model is applied to a hypothetical agricultural reclamation land. IPCC RCP 4.5 and 8.5 scenarios were used as sea level rise data. Results are presented for 2050 and 2100. As a result of the study, it is predicted that by 2100 in the climate change scenario RCP 8.5, there will be 7.8% increase in groundwater saltwater-intruded area, 6.0% increase of salinized soil area, and 1.6% in increase in water-logging area.

• Journal of the Korean institute of surface engineering
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• v.57 no.3
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• pp.221-224
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• 2024

The 304 stainless steel has good corrosion resistance, so it is used in various industries. However, in an environment like seawater, stainless steel can be damaged by chloride ions, resulting in surface corrosion such as pitting and crevice corrosion. Electropolishing is a technique that smooths the surface and creates a passivation layer that can resist corrosion. In this study, electropolishing was applied as a surface finish to increase the smoothness of the metal surface and its corrosion resistance. We confirmed the topology of the electropolished surface of stainless steel by optical microscope and evaluated the corrosion resistance characteristics of electropolished stainless steel through a potentiodynamic experiment.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.815-820
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• 2001

This study is to set a new standard for using of the colorimetric method through grasping the character of the colorimetric method, and measuring the chloride concentration at the place of the change of color. Also, to predict chloride concentration around rebar and time reaching limit chloride concentration through measuring the chloride concentration of concrete surface by the colorimetric method and this study presents the new program of concrete degradation and diagnosis of the durability by salt damage. First the use of the colorimetric method was examinated, second the chloride concentration through slicing concrete submerged in artificial seawater for 6 months was measured. And the chloride concentration at the place of the change of color was calculated by using colorimetric method. Finally, the cloride concentration of the concrete surface was calculated.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2014.10a
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• pp.87-88
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• 2014

The Coastal sediment is highly contaminated due to ship transportation, industries discharges and urban sources. Various contaminants release into seawater and settle in marine sediment and it significantly affect marine eco system. In the present study evaluated the optimization of slow release biostimulant ball (BSB) in coastal sediment in busan. The effective variables like BSB size, distance and month variables on VS reduction was determined by using Response surface methodology(RSM). The analysis of variance (ANOVA) and coefficient determination (R2) of VS was 0.9369 and maximum reduction of VS was obtained in 3cm ball size and 5.5cm distance and 4 month interval time. This result revealed that the BSB in effective VS reduction in coastal sediment.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.9
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• pp.57-62
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• 2021

CNC machining is used to fabricate various components. This has led to the development of processing-based industries for the production of automobile, appliances, semiconductors, and rockets. Additionally, this machining has enabled economical mass production of high-quality products in industries. Magnesium alloy with a hexagonal closed packed configuration is prone to difficulties during plastic machining, has a high oxygen affinity, and exhibits poor corrosion resistance to seawater and the atmosphere. In this research, Al alloy A5083 was used to investigate and analyze the surface roughness with a certain depth of cut fixed by the machining center (DVM-500II) and various feed rates, speeds, and processing methods after modeling and simulated machining with Gibbs CAM.