• Title/Summary/Keyword: surface relaxation

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Activated Physical Properties at Air-Polymer Interface

  • Kajiyama, Tisato;Tanaka, Keiji
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.5-6
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    • 2006
  • Molecular motion at the surface of monodisperse polystyrene (PS) films with various chain end groups was studied by scanning probe microscopy. Surface glass transition temperature ($T_{g^s}$) of the PS films was much lower than the corresponding bulk value. And, the magnitude of $T_{g^s}$ was strongly dependent on chain end chemistry. This result can be explained in terms of the chain end concentration at the surface. Time-temperature superposition principle was applied to rheological analysis at the surface. The apparent activation energy of the surface ${\alpha}_{a}$-relaxation process was approximately a half of that for the bulk sample. This result clearly indicates that the cooperativity for the surface segmental motion was reduced in comparison with that in the bulk region.

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Characterization of Ionic-Polymer Metal Composite Actuators Varying Electroless Plating Method of Platinum (백금 무전해 도금 방법의 변화에 따른 이온성 고분자 및 금속 복합체 액추에이터의 특성 분석)

  • 차승은;김병목;조성환;이승기;박정호;김병규
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.12
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    • pp.601-607
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    • 2002
  • IPMC(Ionic Polymer Metal Composite)actuators were optimized for producing improved forces by changing multiple parameters including repetition of number of plating, surface electroding and additive(PVP)-treatment on reduction. The platinum electrode is deposited on the surface of the material where platinum particle stay in a dense form that appears to introduce a significant level of surface electrode resistance. Actuation tests were performed for such IPMC actuators under a low voltage. The test results show that the lower surface-electrode resistance generates higher actuation capability in the IPMC actuators. In order to investigate relaxation behavior of bending and repeatability in dry condition, the IPMC was coated by$rubber(KRATON^{TM})$to minimize the effect of water evaporation from IPMC. This actuator can be used in air with surface coating to avoid membrane drying.

THIN FILM GROWTH AND SURFACE REACTION ON H-TERMINATED SILICON SURFACE

  • Yasuda, Yukio;Zaima, Shigeaki
    • Journal of Surface Science and Engineering
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    • v.29 no.5
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    • pp.407-414
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    • 1996
  • We have investigated the effects of H atoms on thin film growth processes and surface reactions. In the oxidation of Si, Si surfaces are passivated against the $O_2$ adsorption by terminating dangling bonds with H atoms. Moreover, the existence of Si-H bonds on Si(100) surfaces enhances the structural relaxation of Si-O-Si bonds due to a charge transfer from Si-Si back bonds. In the heteroepitaxial growth of a Si/Ge/Si(100) system, H atoms suppress the segregation of Ge atoms into Si overlayers since the exchange of Ge atoms with Si atoms bound with H must be accompanied with breaking of Si-H bonds. However, 3-dimensional island growth is also promoted by atomic H irradiation, which is considered to result from the suppression of surface migration of adsorbed reaction species and from the lowering of step energies by the H termination of dangling bonds.

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Numerical Solutions for the Flow past a Cylinder (원주주위를 지나는 흐름에 관한 수치해석)

  • 조용식;윤태훈
    • Water for future
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    • v.21 no.3
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    • pp.291-291
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    • 1988
  • The two dimensional time dependent flow past a circular cylinder is analyzed numerically. In the analysis, equations of conservation of mass and momentum are transformed to equations of stream function-vorticity and vorticity transport, and nondimensionalized by nondimensional parameters representing flow characteristics, The resulting stream function-vorticity equstion and vorticity transport equation are solved by successive over relaxation scheme and alternating direct implicit scheme. Numerical experments are performed for the flow in the range of Reynolds number 125 to 275. The time dependent streamlines, vorticities, pressure on cylinder surface, separation angle, and drag and lift coefficients are calculated, and the method for estimation of pressure on cylinder surface and the outer boundary limit are developed.

- Numerical Solutions for the Flow past a Cylinder- (원주주위를 지나는 흐름에 관한 수치해석)

  • 조용식;윤태훈
    • Water for future
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    • v.31 no.4
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    • pp.291-297
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    • 1998
  • The two dimensional time dependent flow past a circular cylinder is analyzed numerically. In the analysis, equations of conservation of mass and momentum are transformed to equations of stream function-vorticity and vorticity transport, and nondimensionalized by nondimensional parameters representing flow characteristics, The resulting stream function-vorticity equation and vorticity transport equation are solved by successive over relaxation scheme and alternating direct implicit scheme. Numerical experiments are performed for the flow in the range of Reynolds number 125 to 275. The time dependent streamlines, vorticities, pressure on cylinder surface, separation angle, and drag and lift coefficients are calculated, and the method for estimation of pressure on cylinder surface and the outer boundary limit are developed.

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An Experimental Study of Nonlinear Viscoelastic Bushing Model for Axial Mode

  • Lee, Seong-Beom;Shin, Jung-Woog;Alan S. Wineman
    • Journal of Mechanical Science and Technology
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    • v.17 no.9
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    • pp.1324-1331
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    • 2003
  • A bushing is a device used in automotive suspension systems to cushion the force transmitted from the wheel to the frame of the vehicle. A bushing is essentially a hollow cylinder which is bonded to a solid metal shaft at its inner surface and a metal sleeve at its outer surface. The shaft is connected to the suspension and the sleeve is connected to the frame. The cylinder provides the cushion when it deforms due to relative motion between the shaft and sleeve. The relation between the force applied to the shaft or sleeve and its deformation is nonlinear and exhibits features of viscoelasticity. An explicit force-displacement relation has been introduced for multi-body dynamics simulations. The relation is expressed in terms of a force relaxation function and a method of determination by experiments on bushings has been developed. Solutions allow for comparison between the force-displacement behavior by experiments and that predicted by the proposed method. It is shown that the predictions by the proposed force-displacement relation are in very good agreement with the experimental results.

An Experimental Study of Pipkin-Rogers Model for Automotive Bushing (자동차 부싱에 대한 Pipkin-Rogers 모델의 실험적 연구)

  • Kim, Sung-Jin;Lee, Su-Young;Lee, Seong-Beom
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.11 s.176
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    • pp.118-124
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    • 2005
  • An automotive bushing is a device used in automotive suspension systems to reduce the load transmitted from the wheel to the frame of the vehicle. A bushing is a hollow cylinder, which is bonded to a solid steel shaft at its inner surface and a steel sleeve at its outer surface. The relation between the force applied to the shaft and the relative deformation of a bushing is nonlinear and exhibits features of viscoelasticity. In this paper, an automotive bushing is regarded as nonlinear viscoelastic incompressible material. Instron 8801 equipment was used for experimental res earch and ramp-to-constant displacement control test was used for data acquisition. Displacement dependent force relaxation function was obtained from the force extrapolation method and expressed as the explicit combination of time and displacement. Pipkin-Rogers model, which is the direct relation of force and displacement, was obtained and comparison studies between the experimental results and the Pipkin-Rogers results were carried out.

Microstructures and Dielectric Properties of SrTiO$_3$-Based BL Capacitor with Content of Ca

  • 김충혁;최운식;이준웅
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.12 no.1
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    • pp.35-43
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    • 1999
  • Microstructures and dielectric properties of (Sr$\_$1-x/Ca$\_$x/) TiO$_3$-0.006Nb$_2$O$\_$5/ (0.05$\leq$x$\leq$0.2) boundary layer ceramics were investigated. The samples fired in a reducing atmosphere(N$_2$) were painted on the surface with CuO paste for the subsequent grain boundary diffusion, and then annealed at 1100$^{\circ}C$ for 2 hrs. The metal oxide of CuO infiltrated by thermal diffusion from surface of sample presents continuously in not grain but only grain boundary, and makes up thin boundary phase. The SEM photo, and EDAX revealed that CuO was penetrated rapidly into the bulk along the grain boundaries during the annealing. The average grain sizes is continuously increased as the content of substitutional Ca is increased from 5[mol%] to 15[mol%], but the average grain size of the sample with content of 20[mol%] Ca is slightly decreased. In the samples with content of 10∼15[mol%] Ca, excellent dielectric properties were obtained as follows; dielectric constant <25000, dielectric loss <0.3[%], and capacitance change rate as a function of temperature <${\pm}$10[%], respectively. All samples in this study exhibited dielectric relaxation with frequency as a functior of the temperature.

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An Interactive Process Capability-Based Approach to Multi-Response Surface Optimization (대화식 절차를 활용한 공정능력지수 기반 다중반응표면 최적화)

  • Jeong, In-Jun
    • Journal of Korean Society for Quality Management
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    • v.45 no.2
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    • pp.191-207
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    • 2017
  • Purpose: To develop an interactive version of the conventional process capability-based approach, called 'Interactive Process Capability-Based Approach (IPCA)' in multi-response surface optimization to obtain a satisfactory compromise which incorporates a decision maker(DM)'s preference information precisely. Methods: The proposed IPCA consists of 4 steps. Step 1 is to obtain the estimated process capability indices and initialize the parameters. Step 2 is to maximize the overall process capability index. Step 3 is to evaluate the optimization results. If all the responses are satisfactory, the procedure stops with the most preferred compromise solution. Otherwise, it moves to Step 4. Step 4 is to adjust the preference parameters. The adjustment can be made in two modes: relaxation and tightening. The relaxation is to make the importance of one of the satisfactory responses lower, which is implemented by decreasing its weight. The tightening is to make the importance of one of the unsatisfactory responses higher, which is implemented by increasing its weight. Then, the procedure goes back to Step 2. If there is no response to be adjusted, it stops with the unsatisfactory compromise solution. Results: The proposed IPCA was illustrated through a multi-response surface problem, colloidal gas aphrons problem. The illustration shows that it can generate a satisfactory compromise through an interactive procedure which enables the DM to provide his or her preference information conveniently. Conclusion: The proposed IPCA has two major advantages. One is to obtain a satisfactory compromise which is faithful to the DM preference structure. The other is to make the DM's participation in the interactive procedure easier by using the process capability index in judging satisfaction/unsatisfaction. The process capability index is very familiar with quality practitioners as well as indicates the process performance levels numerically.

Evaluation of slip coefficient of slip critical joints with high strength bolts

  • Nah, Hwan-Seon;Lee, Hyeon-Ju;Kim, Kang-Seok;Kim, Woo-Bum
    • Structural Engineering and Mechanics
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    • v.32 no.4
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    • pp.477-488
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    • 2009
  • A slip critical joint has various values to adopt the proper slip coefficient in various conditions of faying surfaces in the following codes: AISC, AIJ and Eurocode 3. However, the Korean Building Code still regulates the unique slip coefficient, 0.45, regardless of the diverse faying conditions. In this study, the slip resistance test, including five kinds of surface treatments were conducted to obtain the proper slip coefficients available to steel plate KS SM490A. The faying surfaces were comprised of a clean mill, rust, red lead paint, zinc primer, and shot blast treatment. The candidates for high strength bolts were torque-shear bolts, torque-shear bolts with zinc coating, and ASTM A490 bolts. Based on the test results, the specimens with a shot blasted surface and rusted surface exhibited $k_s$, 0.61, and 0.5, respectively. It is recommended that the specimens with zinc primer exhibit $k_s{\geq}0.40$. The clean mill treated surface had prominently lower values, 0.27. For red lead painted treatment, the thickness of the coating affects the determinant of slip coefficient, so it is necessary to establish a minimum $k_s$ of 0.2, with a coating thickness of 65 ${\mu}m$. During 1,000 hours of relaxation, the uncoated surfaces exhibited the loss of clamping force behind 3%, while the coated surfaces within a certain limited thickness exhibited the loss of clamping within a range of 4.71% and 8.37%.