• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.407.1-407.1
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• 2016

Electrochromism is defined as a phenomenon which involves persistently repeated change of optical properties between bleached state and colored state by simultaneous injection of electrons and ions, sufficient to induce an electrochemical redox process. Due to this feature, considerable progress has been made in the synthesis of electrochromic (EC) materials, improvements of EC properties in EC devices such as light shutter, smart window and variable reflectance mirrors etc. Among the variable EC materials, solid-state inorganics in particular, metal oxide semiconducting materials such as nickel oxide (NiO) have been investigated extensively. The NiO that is an anodic EC material is of special interest because of high color contrast ratio, large dynamic range and low material cost. The high performance EC devices should present the use of standard industrial production techniques to produce films with high coloration efficiency, rapid switching speed and robust reversibility. Generally, the color contrast and the optical switching speed increase drastically if high surface area is used. The structure of porous thin film provides a specific surface area and can facilitate a very short response time of the reaction between the surface and ions. The large variety of methods has been used to prepare the porous NiO thin films such as sol-gel process, chemical bath deposition and sputtering. Few studies have been reported on NiO thin films made by using sol-gel method. However, compared with dry process, wet processes that have the questions of the durability and the vestige of bleached state color limit the thin films practical use, especially when prepared by sol-gel method. In this study, we synthesis the porous NiO thin films on the fluorine doped tin oxide (FTO) glass by using sputtering and anodizing method. Also we compared electrical and optical properties of NiO thin films prepared by sol gel. The porous structure is promised to be helpful to the properties enhancement of the EC devices.

• 대한화장품학회:학술대회논문집
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• 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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• pp.218-218
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• 2003

Recently we showed the prototype portable device for the determination of human skin moisture by using near infrared spectroscopy. In order to optimize the acquiring condition of NIR spectrum of skin and control the target information of water depending the site such as epidermis and dermis, skin depth profiling was investigated changing the distance between illuminations and receiving of radiation in the terminal of fiber probe. The colleted light information could be controlled by changing the distance of the fiber optic probes. It was confirmed that the longer distance we used, the deeper site from the skin surface we could get information from in this study. Four kinds of probes with distances such as 0.03 mm, 0.1 mm, 0.5 mm, and 1.0 mm were used. In addition, the gap size from 0.3 mm to 3.0 mm was studied to control the intensity of water absorbance effectively and to avoid saturation of water absorption. We also investigated the reference materials depending the reflectance ratio for water absorption not to be saturated because of the strong absorptivity of water. Furthermore, spectroscopic information regarding free water and bound water around 1850 nm was investigated by using the different distance of fiber optic probes. This study would be great help to control the spectroscopic information of water to be measured depending the site where water exists.

• 한국결정성장학회지
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• 제33권4호
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• pp.132-138
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• 2023

Doped and undoped-BiVO₄ samples with different elements (Li, Mg) and amounts were synthesized with a hydrothermal method. The synthesized samples were characterized using various techniques including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis diffusion reflectance spectroscopy (UV-Vis DRS), and photoluminescence (PL) spectroscopy. Photocatalytic activity of the samples was evaluated by measuring the degradation of methyl blue (MB) under visible light irradiation. The results indicated that the incorporation of Mg and Li into BiVO₄ caused lattice distortion, the presence of surface hydroxyl groups, a narrower band gap, and a reduced recombination ratio of photo-induced electron-hole pairs. Notably, the photocatalytic activity of Mg5%-Li5% co-doped BiVO₄ sample exhibited a significant improvement compared to that of undoped BiVO₄ sample.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2020년도 학술발표회
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• pp.4-4
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• 2020

Three wildfires severely damaged local towns and forests in Gangwon-do, South Korea in 2019 April 4-5. Local hydrological regime could be greatly altered by the wildfires, therefore it is important to assess its damage (e.g. area and severity) and also resultant changes in hydrological fluxes. We retrieved the Normalized-Burned Ratio (NBR) index using remote-sensing data (Moderate Resolution Imaging Spectroradiometer (MODIS) 500-m 8-day surface reflectance data), and delineated the damaged-area based on the difference in the NBR (dNBR) before and after the wildfires. We then estimated changes in the annual evapotranspiration (AET) in 2019 using the MODIS evapotranspiration data (500-m 8-day). It was found that the damaged-area of the three wildfires was 29.50 km^2 in total, which take up 1.00-6.19% area of five catchments. It was estimated that the AET would be decreased as 0.05-1.56% over those five catchments, as compared to the pre-fire AET (2004-2018). The impact of the wildfires on the catchment AET was less severe than expected (i.e. up to 1.56%) mostly because two big wildfires were distributed across two catchments respectively (i.e. four catchments for the two wildfires) and the other wildfire was small and not severe. This study highlights the importance of assessing the area and severity of a wildfire when estimating its impact on the local hydrological cycle.

• 한국정밀공학회지
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• 제28권7호
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• pp.777-782
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• 2011

Micro features on the surface are well-known to have significant effects on optical or mechanical properties such as the optical interference, reflectance at the surface, contact angle, interfacial friction, etc. These surface micro features are increasingly employed to enhance the functionality of the applications in various application areas such as optical components for LCD or solar panel. Diverse surface features have been proposed and some of them are showing excellent efficiency or functionality, especially in optical applications. Most applications employing the micro features need manufacturing process for mass production and the injection molding and roll-to-roll forming, which are typical processes for mass production adopting polymeric materials, may be also preferred for micro patterned plastic product. Since the functionality or efficiency of the surface structures generally depends on the shape and the size of the structure itself or the array of the structures on the surface, it would be very important to replicate the features very precisely as being designed during the molding the micro pattern applications. In this paper, a series of research activities is introduced for roll-to-roll forming of micro patterned film including filling of patterns with UV curable resin, demolding of surface structures from the roll tool, control of surface energy and cure shrinkage of resin and dispose time and intensity of the UV light for curing of UV curable resin.

• 폴리머
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• 제28권1호
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• pp.77-85
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• 2004

초고분자량 폴리에틸렌은 우수한 기계적 특성과 생체 적합성으로 인해 생체 재료 분야에서 널리 이용되어 왔다. 그러나, 다른 생체 고분자 재료와의 접착 시, 초고분자량 폴리에틸렌 분말의 표면 불활성으로 인해 접착력이 현저히 감소한다. 본 연구에서는 초고분자량 폴리에틸렌 분말을 첨가함으로써 상온 경화형 폴리(메틸 메타크릴레이트) 뼈 시멘트의 기계적 특성 및 열적 특성을 향상시키기 위해 메틸 메타크릴레이트와 자일렌의 혼합 용액으로 초고분자량 폴리에틸렌 분말의 표면 개질을 시도하였다. 개질 후, 표면 처리된 초고분자량 폴리에틸렌 분말은 적외선 분광기, 주사전자 현미경, 인장압축 시험기, 및 디지털 온도계로 특성을 결정하였다. 메틸 메타크릴레이트와 자일렌의 함량을 달리하여 표면 개질된 초고분자량 폴리에틸렌 분말을 함유한 폴리(메틸 메타크릴레이트) 뼈 시멘트의 기계적 특성을 측정해 본 결과, 메틸 메타크릴레이트/자일렌을 1 : 1 (부피 비율)로 표면 개질한 초고분자량 폴리에틸렌 분말을 첨가시킨 새로운 폴리(메틸 메타크릴레이트) 뼈 시멘트의 기계적 강도가 최대였으며, 중합 열은 103 $^{\circ}C$에서 58∼73 $^{\circ}C$로 감소함을 확인하였다. 또한, 초고분자량 폴리에틸렌 분말의 표면 개질방법의 메카니즘을 제안하였다.

• 한국지형학회지
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• 제28권1호
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• pp.83-99
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• 2021

Burn severity analysis using satellite imagery has high capabilities for research and management in inaccessible areas. We extracted the forest fire area of the DMZ (Demilitarized Zone) in the western Imjin Estuary which is restricted to access due to the confrontation between South and North Korea. Then we analyzed the forest fire severity and recoverability using atmospheric corrected Surface Reflectance Level-2 data collected from Landsat-8 OLI (Operational Land Imagery) / TIRS (Thermal Infrared Sensor). Normalized Burn Ratio (NBR), differenced NBR (dNBR), and Relative dNBR (RdNBR) were analyzed based on changes in the spectral pattern of satellite images to estimate burn severity area and intensity. Also, we evaluated the recoverability after a forest fire using a land cover map which is constructed from the NBR, dNBR, and RdNBR analyzed results. The results of dNBR and RdNBR analysis for the six years (during May 30, 2014 - May 30, 2020) showed that the intensity of monthly burn severity was affected by seasonal changes after the outbreak and the intensity of annual burn severity gradually decreased after the fire events. The regrowth of vegetation was detected in most of the affected areas for three years (until May 2020) after the forest fire reoccurred in May 2017. The monthly recoverability (from April 2014 to December 2015) of forests and grass fields was increased and decreased per month depending on the vegetation growth rate of each season. In the case of annual recoverability, the growth of forest and grass field was reset caused by the recurrence of a forest fire in 2017, then gradually recovered with grass fields from 2017 to 2020. We confirmed that remote sensing was effectively applied to research of the burn severity and recoverability in the DMZ. This study would also provide implications for the management and construction statistics database of the forest fire in the DMZ.

• JSTS:Journal of Semiconductor Technology and Science
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• 제17권4호
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• pp.483-491
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• 2017

The interdigitated germanium (Ge) meta-lsemiconductor-metal (MSM) photodetectors (PDs) with and without an $SiO_2$ anti-reflection (AR) layer was fabricated, and the effect of $SiO_2$ AR layer on their optoelectronic response properties were investigated in detail. The lowest reflectance of 15.6% at the wavelength of 1550 nm was obtained with a $SiO_2$ AR layer with a thickness of 260 nm, which was in a good agreement with theoretically calculated film thickness for minimizing the reflection of Ge surface. The Ge MSM PD with 260 nm-thick $SiO_2$ AR layer exhibited enhanced device performance with the maximum values of responsivity of 0.65 A/W, the quantum efficiency of 52.2%, and the detectivity of $2.49{\times}10^9cm\;Hz^{0.5}W^{-1}$ under the light illumination with a wavelength of 1550 nm. Moreover, time-dependent switching analysis of Ge MSM PD with 260 nm- thick $SiO_2$ AR layer showed highest on/off ratio with excellent stability and reproducibility. All this investigation implies that 260 nm-thick $SiO_2$ AR layer, which is effective in the reduction in the reflection of Ge surface, has a great potential for Ge based optoelectronic devices.

• 대기
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• 제16권4호
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• pp.333-342
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• 2006

The long-term trends of global solar irradiance, air temperature, specific humidity and cloudiness measured at King Sejong station, Antarctica, during the period of 1988-2004, have been investigated. A statistically insignificant decrease, -0.21 $Wm^{-2}yr^{-1}$ (-0.26 %$yr^{-1}$, P<0.5) in global solar irradiance was found in an analysis from the time series of the monthly mean values, except for the increasing trends only in two months of January and June. The trends in irradiance are directly and inversely associated with the cloudiness trends in annual and monthly means. The trends in surface air temperature show a slight warming, $0.03^{\circ}Cyr^{-1}$ (1.88 %$yr^{-1}$, P<0.5) on the annual average, with cooling trend in the summer months and the warming in the winter. The exact relationship, if any, between the irradiance and temperature trends is not known. No significant tendency was found in specific humidity for the same periods. Recent (1996-2004) erythermal ultraviolet irradiance shows decreasing trend in annual mean, -0.15 $mWm^{-2}yr^{-1}$ (-1.18 %$yr^{-1}$, P<0.1) which is about five times the trends of global solar irradiance. The ratio of erythermal ultraviolet to global solar irradiance shows remarkable seasonal variations with annual mean value of 0.01 % and a peak in October and November, showing the increase of ultraviolet irradiance resulting from the Antarctic ozone hole. The sensitivity of global solar irradiance to the change in cloudiness is roughly $13%oktas^{-1}$ which is about twice of the value at the South Pole due to the difference in the average surface reflectance between the two stations. Much more sensitive values of $59%oktas^{-1}$ was found for erythermal UV irradiance than for the global solar irradiance.

• Nuclear Engineering and Technology
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• 제52권10호
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• pp.2320-2327
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• 2020

The extreme hydrophobicity of expanded polytetrafluoroethylene (ePTFE) hinders bone-tissue integration, thus limiting the use of ePTFE in medical implant applications. To improve the potential of ePTFE as a biomaterial, 2-hydroxyethyl methacrylate (HEMA) was grafted onto the ePTFE surface using the gamma irradiation technique. The characteristics of the grafted ePTFE were successfully evaluated using attenuated total reflectance Fourier transform infrared (ATR-FTIR), field-emission scanning electron microscopy (FESEM)/energy dispersive X-ray (EDX), and X-ray photoelectron spectroscopy (XPS). Under the tensile test, the modified ePTFE was found to be more brittle and rigid than the untreated sample. In addition, the grafted ePTFE was less hydrophobic with a higher percentage of water uptake compared to the untreated ePTFE. The protein adsorption test showed that grafted ePTFE could adsorb protein, which was denoted by the presence of N peaks in the XPS analysis. Moreover, the formation of the globular mineral on the grafted ePTFE surface was successfully visualized using the FESEM analysis, with a ratio of 1.94 for Ca:P minerals by the EDX. To summarize, the capability of the modified ePTFE to show protein adsorption and mineralization indicates the improvement of the polymer properties, and it can potentially be used as a biomaterial for implant application.