• 제목/요약/키워드: surface phase transition

검색결과 250건 처리시간 0.036초

상변화 박막의 두께에 따른 상변화 메모리의 전류 및 열 특성 (Electrical and thermal characteristics of PRAM with thickness of phase change thin film)

  • 최홍규;김홍승;이성환;장낙원
    • Journal of Advanced Marine Engineering and Technology
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    • 제32권1호
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    • pp.162-168
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    • 2008
  • In this paper, we analyzed the heat transfer phenomenon and the reset current variation of PRAM device with thickness of phase change material using the 3-D finite element analysis tool. From the simulation, Joule's heat was generated at the contact surface of phase change material and bottom electrode of PRAM. As the thickness of phase change material was decreased, the reset current was highly increased. In case thickness of phase change material thin film was $200\;{\AA}$, heat increased through top electrode and reset current caused by phase transition highly increased. And as thermal conductivity of top electrode decreased, temperature of unit memory cell was increased.

래티스볼츠만 다상류 모델의 검토 및 응용 (An Investigation of Lattice Boltzmann Multi-phase Model and it Application)

  • 강호근;안수환
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2006년도 전기학술대회논문집
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    • pp.269-270
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    • 2006
  • A finite difference lattice Boltzmann model which allows us to simulate gas-liquid two-phase flows with large density difference, for instance, 800 times for air and water is considered. Two-particle model is used and the density difference is introduced by changing the acceleration according to the fluid density. Numerical measurement of surface tension agrees well with theoretical predictions. Simulations of two-phase phenomenon for phase-transition is carried out, showing applicability of the model for two-phase flows. The two-dimensional cavitating flow around a board set up in the fluid way is also simulated. As a result, it was confirmed that the FDLB method with two-particle model was effective in numerical simulation of cavitating flow and the bubble periodically grew up at the low pressure area behind the board, in which the fluid condition was influenced by the cavitation number.

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PBDG의 자격반응과 물성에 관한 연구 (A Study on Stimulus reaction and Physical Properties of PBDG)

  • 장헌;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.1047-1049
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    • 2001
  • The displacemant current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. With Maxwell-displacement-current-measuring method, the phase transitions of Poly-${\gamma}$ -benzyl D-glutamate(PBDG) on a water surface were detected. Measured surface pressure, displacement current and dipole moment of monolayers of PBDG on the water surface. We measured analyzed displacement current that occur when differed temperature. Could know that displacement current is proportional in increase of temperature and great as experiment result.

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Synthesis and characterization of visible light active photocatalytic $TiO_2$

  • Kim, Duk-Su;Park, Kyu-Sung;Kim, Il-Doo;Kim, Ho-Gi
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.1116-1120
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    • 2002
  • Using thermal hydrolysis and hydrothermal treatment, photocatalytic $TiO_2$ powders were synthesized. During the synthesis, the addition of other transition metals such as iron, copper, etc., affected the photocatalytic capability of synthesized powders, and enabled the activation by visible light. To enhance photocatalytic capacity of gas phase decomposition, the rate-determining adsorption rate of pollutant gases were improved via surface modification of $TiO_2$ powders. The surface modifiers were implanted using mechanochemical synthesis of dopants and photocatalytic powders.

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$BaTiO_3$의 강유전성 분역 (Ferroelectric Domans in $BaTiO_3$)

  • 박봉모;정수진
    • 한국세라믹학회지
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    • 제33권1호
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    • pp.56-64
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    • 1996
  • A large amount of papers about the cubic-to-tetragonal phase transition the ferroelectric domain structures of the BaTiO3 were already reported but there exist still some needs to observe the domain behaviors directly. In this study the domain structures of the tinned plates prepared from ta single crystal grown by the TSSG technique were observed using a polarizing microscope TE and X-ray topography. The spatial relation be-tween the orientation states of domains was investigated and the effects of external stresses and electric fields on the behaviors of ferroelectric and ferroelastic domains were studied. All the 90$^{\circ}$walls cut off in the crystal are the wedge shaped lamellar domains and all the straight boundaries in the observed domain patte군 can be interpreted as the head-to-tail 90$^{\circ}$walls. The irregular overlapped boundaries commonly observed by using a polarizing microscope and X-ray topography are complex combinations of well-known 90$^{\circ}$walls and are domain walls were predominant and were stabilized after surface polishing. In the paraelectric phase region the domain walls vanished but the residual surface strain patterns could be seen at the same positions of the stabilized 90$^{\circ}$a-a walls in the tetragonal phase region, These stabilized walls resulted from the surface strain had a memory effect in domain formation during the repeated phase transitions and could notr be affected by an external electtric field.

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열처리 조건에 따른 TiO2 나노튜브의 결정구조 및 형상 변화 (Crystallization and Phase Transition of TiO2Nanotubes by Heat Treatment.)

  • 이주영;문성모;정용수
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.319-319
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    • 2012
  • 수용액에서 양극산화법을 이용하여 티타늄 표면에 $TiO_2$ 나노튜브를 형성시켰고, XRD 및 전자현미경을 통해 열처리를 한 $TiO_2$ 나노튜브 소재표면, 계면구조를 관찰하였으며, 이는 향후 나노튜브의 결정구조를 제어할 수 있는 자료로 활용 될 것으로 기대된다.

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전단응력 하에서 에멀젼 상 변이의 측정을 위한 전기 유변학적 연구 (Electro-rheological Measurements of Phase Inversion of Emulsions under Shear Flow)

  • Seung Jae, Baik;Young-Jin, Lee;Yoon Sung, Nam;Chin Han, Kim;Han Kon, Kim;Hak Hee, Kang
    • 대한화장품학회지
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    • 제30권2호
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    • pp.147-151
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    • 2004
  • 본 연구는 다양한 종류의 에멀젼에 전단응력을 가하며 그때 일어나는 에멀젼의 상 변이를 전기, 유변학적 특징을 통해 실시간으로 측정해 보는 것이다. 전기 전도도의 변화는 자체 제작한 JELLI$^{TM}$(Joint Electro-rheometer for Liquid-Liquid Inversion) 칩을 이용하였으며, 동시에 유변물성측정장치(rheometer)를 이용하여 유변물성의 변화를 측정하였다 JELLI$^{TM}$ 칩과 인조 피부를 유변물성측정장치 사이에 장착하고 그 사이에 다양한 종류의 에멀젼을 얇게 발라준 후, 일정한 전단응력을 주며 시간에 따른 저항과 점도 값의 변화를 측정하였다. O/W 제형의 경우 시간에 따라 저항 값이 커지는 경향을 보였으며 저항 값은 내부 상이 많을수록 더 급격한 변화를 나타냈다. 이때의 점도 변화를 보면, 저항 값의 변화가 클수록 점도의 변화도 큼을 볼 수 있었다. 이것은 내부 상의 파괴로 인해 외부의 힘에 저항하는 힘이 약해졌기 때문이라고 예상된다. 이런 결과를 이용하여 전단응력에 의한 에멀젼 상 변이 특성과 정도를 실시간, 정량적 비교할 수 있었다.

Structural Analysis of Simulated Fission-Produced Noble Metal Alloys and Their Superconductivities

  • 박용준;이광용;이종규;허용득;김원호
    • Bulletin of the Korean Chemical Society
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    • 제21권12호
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    • pp.1187-1192
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    • 2000
  • Ternary (Mo-Ru-Pd) and binary (Mo-Ru, Mo-Pd) alloys have been prepared using an Ar arc melting furnace. Mo and the noble metals, Ru and Pd, are the constituents of metallic insoluble residues, which were found in the early days of post-irradiation studies on uranium oxide fuels. In the present study, the structure of the alloys was evaluated using a powder X-ray diffractometer. Unit cell parameters were determined by least squares refinements of powder X-ray diffraction data. Scanning electron microscopic analyses of the surface of the alloys indicated that surface morphology was dependent on the crystallographic structure as well as its composition. Measurements of the magnetic susceptibility of the alloys showed evidence of superconducting transition from 3 to 9.2 K. Among the ternary and binary alloys, the ${\sigma}-phase$ showed the highest superconducting transition temperature,~9.2 K.

Dielectric relaxation properties in the lead scandium niobate

  • Yeon Jung Kim
    • 한국표면공학회지
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    • 제56권4호
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    • pp.227-232
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    • 2023
  • In this study, complex admittance as a function of temperature and frequency was measured to analyze the important relaxation properties of lead scandium niobate, which is physically important, although it is not an environmentally friendly electrical and electronic material, including lead. Lead scandium niobate was synthesized by heat treating the solid oxide, and the conductance, susceptance and capacitance were measured as a function of temperature and frequency from the temperature dependence of the RLC circuit. The relaxation characteristics of lead scandium niobate were found to be affected by contributions such as grain size, grain boundary characteristics, space charge, and dipole arrangement. As the temperature rises, the maximum admittance and susceptance increase in one direction, but the resonance frequency decreases below the transition temperature but increases after the phase transition.

버네사이트 합성 시 에이징 시간에 따른 중간생성물 페이크네타이트 상전이 및 표면 형태학적 특성 (Phase Transition and Surface Morphological Characteristics of Intermediate Product Feitknechtite According to Aging Time during the Synthesis of Birnessite)

  • 민소영;김영규
    • 한국광물학회지
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    • 제32권3호
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    • pp.213-222
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    • 2019
  • 버네사이트(birnessite, $7{\AA}$ manganate, ${\delta}-MnO_2$)는 망간단괴를 구성하는 주요한 광물이다. 버네사이트는 또한 이온교환제와 배터리 재충전 물질로서 사용될 수 있기 때문에 다양한 합성법이 연구되고 있다. 그러나 버네사이트는 화학양론적으로 성립하지 않는 화학조성을 가지기 때문에 합성 시 단일 상을 수득하기에는 어려움이 존재한다. 버네사이트 합성과정 중에서 중간생성물로 페이크네타이트(${\beta}-MnOOH$)가 나타나는데, 본 연구에서는 이 중간생성물이 버네사이트로 상전이 하는 특성 차이를 XRD와 SEM 결과를 통해 비교하였다. 이번 연구에서는 기존에 연구된 합성 방법 중에서 산화-환원(redox)반응을 기작으로 하는 Feng et al. (2004)와 Luo et al. (1998) 두 방법을 이용하였다. Feng et al. (2004) 방법으로는 $27^{\circ}C$에서 60일, Luo et al. (1998) 방법으로는 $60^{\circ}C$에서 3일 에이징 한 시료에서 단일 상의 버네사이트를 수득할 수 있는 것으로 나타났다. 이러한 두 시료의 상전이 특성은 $Mg^{2+}$ 도핑여부에 따라 차이가 나타나는 것으로 판단되며 $Mg^{2+}$ 도핑된 Luo et al. (1998) 방법으로 합성된 버네사이트의 경우 페이크네타이트 상전이 속도가 느리게 나타났고 고온에서 거의 단일 상 버네사이트를 확인할 수 있었으며 결정 표면 및 형태 또한 두 방법 간의 차이를 확인하였다.